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\(n_{H_2SO_4}=\dfrac{200.19,6}{100.98}=0,4mol\\ CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ n_{CuSO_4\left(A\right)}=n_{CuO}=n_{H_2SO_4}=0,4mol\\ n_{Cu\left(OH\right)_2}=\dfrac{29,4}{98}=0,3mol\\ CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\\\Rightarrow\dfrac{0,4}{1}>\dfrac{0,3}{1}\Rightarrow CuSO_4.pư.không.hết\)
\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
0,3mol 0,6mol 0,3mol
\(m_{ddB}=0,4.80+200+0,6.40-29,4=226,6g\\ C_{\%Na_2SO_4\left(B\right)}=\dfrac{0,3.142}{226,6}\cdot100=18,8\%\)
Ta có: \(n_{H_2SO_4}=\dfrac{200.19,6\%}{98}=0,4\left(mol\right)\)
\(n_{Cu\left(OH\right)_2}=\dfrac{29,4}{98}=0,3\left(mol\right)\)
PT: \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
Dung dịch A gồm: CuSO4 và H2SO4 dư
\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)
\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
Đề có cho dữ kiện gì liên quan đến dd NaOH không bạn nhỉ?
\(n_{HCl}=\dfrac{300.7,3\%}{36,5}=0,6\left(mol\right)\\ n_{NaOH}=\dfrac{200.4\%}{40}=0,2\left(mol\right)\\ a.NaOH+HCl\rightarrow NaCl+H_2O\\ Vì:\dfrac{0,6}{1}>\dfrac{0,2}{1}\\ \Rightarrow HCldư\\ b.n_{HCl\left(p.ứ\right)}=n_{NaCl}=n_{NaOH}=0,2\left(mol\right)\\ n_{HCl\left(dư\right)}=0,6-0,2=0,4\left(mol\right)\\ m_{ddsau}=300+200=500\left(g\right)\\ C\%_{ddHCl\left(dư\right)}=\dfrac{0,4.36,5}{500}.100=2,92\%\\ C\%_{ddNaOH}=\dfrac{0,2.58,5}{500}.100=2,34\%\)
c. Vì dư HCl => Qùy tím sẽ hóa đỏ.
\(a,PTHH:H_2SO_4+BaCl_2\rightarrow BaSO_4\downarrow+2HCl\\ \left\{{}\begin{matrix}m_{H_2SO_4}=\dfrac{300\cdot9,8\%}{100\%}=29,4\left(g\right)\\m_{BaCl_2}=\dfrac{200\cdot26\%}{100\%}=52\left(g\right)\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\left(mol\right)\\n_{BaCl_2}=\dfrac{52}{208}=0,25\left(mol\right)\end{matrix}\right.\)
Vì \(\dfrac{n_{H_2SO_4}}{1}>\dfrac{n_{BaCl_2}}{1}\) nên H2SO4 dư
\(\Rightarrow n_{BaSO_4}=n_{BaCl_2}=0,25\left(mol\right)\\ \Rightarrow a=m_{BaSO_4}=0,25\cdot233=58,25\left(g\right)\\ b,n_{HCl}=n_{BaCl_2}=0,25\left(mol\right)\\ \Rightarrow m_{CT_{HCl}}=0,25\cdot36,5=9,125\left(g\right)\\ m_{dd_{HCl}}=300+200-58,25=441,75\left(g\right)\\ \Rightarrow C\%_{HCl}=\dfrac{9,125}{441,75}\cdot100\%\approx2,07\%\)
Bài 1:
PTHH: \(Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)
Ta có: \(\left\{{}\begin{matrix}m_{Ba\left(OH\right)_2}=150\cdot17,1\%=25,65\left(g\right)\\m_{HCl}=300\cdot7,3\%=21,9\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{Ba\left(OH\right)_2}=\frac{25,65}{171}=0,15\left(mol\right)\\n_{HCl}=\frac{21,9}{36,5}=0,6\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\frac{0,15}{1}< \frac{0,6}{2}\) \(\Rightarrow\) Ba(OH)2 phản ứng hết, HCl còn dư
\(\Rightarrow\) Dung dịch A làm quỳ tím hóa đỏ
Bài 3:
PTHH: \(BaCl_2+H_2SO_4\rightarrow2HCl+BaSO_4\downarrow\) (1)
a) Ta có: \(\left\{{}\begin{matrix}n_{BaCl_2}=\frac{150\cdot5,2\%}{208}=0,0375\left(mol\right)\\n_{H_2SO_4}=\frac{250\cdot19,6\%}{98}=0,5\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\frac{0,0375}{1}< \frac{0,5}{1}\) \(\Rightarrow\) BaCl2 phản ứng hết, H2SO4 còn dư
\(\Rightarrow n_{BaSO_4}=0,0375mol\) \(\Rightarrow m_{BaSO_4}=0,0375\cdot233=8,7375\left(g\right)\)
b) Dung dịch A chứa \(HCl\) và \(H_2SO_{4\left(dư\right)}\)
PTHH: \(HCl+NaOH\rightarrow NaCl+H_2O\) (2)
\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\) (3)
Theo PTHH (1): \(\left\{{}\begin{matrix}n_{HCl}=2n_{BaCl_2}=0,075mol\\n_{H_2SO_4\left(dư\right)}=0,4625mol\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{NaOH\left(2\right)}=0,075mol\\n_{NaOH\left(3\right)}=0,925mol\end{matrix}\right.\)
\(\Rightarrow n_{NaOH}=1mol\) \(\Rightarrow V_{NaOH}=\frac{1}{1,5}\approx0,67\left(l\right)=670\left(ml\right)\)
\(a,\left\{{}\begin{matrix}m_{H_2SO_4}=\dfrac{300\cdot9,8\%}{100\%}=29,4\left(g\right)\\m_{BaCl_2}=\dfrac{200\cdot26\%}{100\%}=52\left(g\right)\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\left(mol\right)\\n_{BaCl_2}=\dfrac{52}{208}=0,25\left(mol\right)\end{matrix}\right.\\ PTHH:H_2SO_4+BaCl_2\rightarrow2HCl+BaSO_4\downarrow\)
Vì \(\dfrac{n_{H_2SO_4}}{1}>\dfrac{n_{BaCl_2}}{1}\) nên sau phản ứng \(H_2SO_4\) dư
\(\Rightarrow n_{BaSO_4}=0,25\left(mol\right)\\ \Rightarrow a=m_{BaSO_4}=0,25\cdot233=58,25\left(g\right)\)
\(b,n_{HCl}=2n_{BaCl_2}=0,5\left(mol\right)\\ \Rightarrow m_{CT_{HCl}}=0,5\cdot36,5=18,25\left(g\right)\\ m_{dd_{HCl}}=300+200-58,25=441,75\left(g\right)\\ \Rightarrow C\%_{HCl}=\dfrac{18,25}{441,75}\cdot100\%\approx4,13\%\)
\(a.m_{HCl}=100.10\%+150.20\%=40\left(g\right)\\ C\%_{ddHCl}=\dfrac{40}{100+150}.100=16\%\\ b.n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\\ n_{HCl}=\dfrac{10,95\%.100}{36,5}=0,3\left(mol\right)\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ Vì:\dfrac{0,1}{1}< \dfrac{0,3}{1}\Rightarrow HCldư\\ n_{HCl\left(dư\right)}=0,3-2.0,1=0,1\left(mol\right)\\ m_{HCl\left(dư\right)}=0,1.36,5=3,65\left(g\right)\\ n_{MgCl_2}=n_{Mg}=0,1\left(mol\right)\\ m_{MgCl_2}=0,1.95=9,5\left(g\right)\\ m_{ddsau}=2,4+100-0,1.2=102,2\left(g\right)\\ C\%_{ddHCl\left(dư\right)}=\dfrac{3,65}{102,2}.100\approx3,571\%\)
\(C\%_{ddMgCl_2}=\dfrac{9,5}{102,2}.100\approx9,295\%\)