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\(n_{CuCl_2}=0,1.0,3=0,03mol\)
PTHH: \(CuCl_2+2KOH\rightarrow2KCl+Cu\left(OH\right)_2\)
\(Cu\left(OH\right)_2\rightarrow^{t^o}CuO+H_2O\)
\(m_{CuO}=0,03.80=2,4g\)
a, \(FeCl_3+3NaOH\rightarrow3NaCl+Fe\left(OH\right)_3\)
\(2Fe\left(OH\right)_3\underrightarrow{t^o}Fe_2O_3+3H_2O\)
b, \(n_{FeCl_3}=0,4.2=0,8\left(mol\right)\)
Theo PT: \(n_{NaCl}=3n_{FeCl_3}=2,4\left(mol\right)\)
\(\Rightarrow C_{M_{NaCl}}=\dfrac{2,4}{0,4+0,2}=4\left(M\right)\)
c, \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=\dfrac{1}{2}n_{FeCl_3}=0,4\left(mol\right)\)
\(\Rightarrow m_{Fe_2O_3}=0,4.160=64\left(g\right)\)
\(n_{FeCl3}=2.0,4=0,8\left(mol\right)\)
PTHH : \(FeCl_3+3NaOH\rightarrow Fe\left(OH\right)_3+3NaCl\)
0,8----------------------->0,8----------->2,4
b) \(C_{MNaCl}=\dfrac{2,4}{0,4+0,2}=4M\)
c) \(2Fe\left(OH\right)_3\xrightarrow[]{t^o}Fe_2O_3+3H_2O\)
0,8--------------->0,4
\(\Rightarrow a=m_{Fe2O3}=0,4.160=64\left(g\right)\)
Đề không đề cập nung trong điều kiện nào nên mình coi như nung trong không khí nhé.
PT: \(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
\(MgSO_4+2NaOH\rightarrow Mg\left(OH\right)_2+Na_2SO_4\)
\(FeSO_4+2NaOH\rightarrow Fe\left(OH\right)_2+Na_2SO_4\)
\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)
\(4Fe\left(OH\right)_2+O_2\underrightarrow{t^o}2Fe_2O_3+4H_2O\)
Giả sử dd chứa a (l)
Ta có: nCuSO4 = 0,2a (mol), nMgSO4 = 0,1a (mol), nFeSO4 = 0,2a (mol)
Theo PT: \(\left\{{}\begin{matrix}n_{CuO}=n_{Cu\left(OH\right)_2}=n_{CuSO_4}=0,2a\left(mol\right)\\n_{MgO}=n_{Mg\left(OH\right)_2}=n_{MgSO_4}=0,1a\left(mol\right)\\n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_2}=\dfrac{1}{2}n_{FeSO_4}=0,1a\left(mol\right)\end{matrix}\right.\)
⇒ 0,2a.80 + 0,1a.40 + 0,1a.160 = 18
⇒ a = 0,5 (l)
⇒ V = 500 (ml)
\(a,PTHH:3NaOH+FeCl_3\rightarrow3NaCl+Fe\left(OH\right)_3\downarrow\\ 2Fe\left(OH\right)_3\rightarrow^{t^o}Fe_2O_3+3H_2O\uparrow\\ b,n_{FeCl_3}=1,5\cdot0,2=0,3\left(mol\right)\\ \Rightarrow n_{NaOH}=3n_{FeCl_3}=0,9\left(mol\right)\\ \Rightarrow V_{dd_{NaOH}}=\dfrac{0,9}{2}=0,45\left(l\right)\)
Theo đề: \(\left\{{}\begin{matrix}X:Fe\left(OH\right)_3\\A:NaCl\\Y:Fe_2O_3\end{matrix}\right.\)
Theo PT: \(n_{NaCl}=3n_{FeCl_3}=0,9\left(mol\right)\)
\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,9}{0,45+0,2}\approx1,4M\)
\(c,\) Theo PT: \(n_{Fe\left(OH\right)_3}=n_{FeCl_3}=0,3\left(mol\right);n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_X=m_{Fe\left(OH\right)_3}=0,3\cdot107=32,1\left(g\right)\\m_Y=m_{Fe_2O_3}=0,15\cdot160=24\left(g\right)\end{matrix}\right.\)
a)
\(FeSO_4 + 2NaOH \to Fe(OH)_2 + Na_2SO_4\)
b)
\(n_{FeSO_4} = 0,4.0,5 = 0,2(mol) ; n_{NaOH} = 0,5.0,5 = 0,25(mol)\)
Ta thấy : \(2n_{FeSO_4} = 0,4 > n_{NaOH} = 0,25\) nên FeSO4 dư.
Theo PTHH :
\(n_{Fe(OH)_2} = 0,5n_{NaOH} = 0,125(mol)\\ \Rightarrow m_{Fe(OH)_2} = 0,125.90 = 11,25(gam)\)
c)
\(4Fe(OH)_2 + O_2 \xrightarrow{t^o} 2Fe_2O_3 + 4H_2O\)
Theo PTHH :
\(n_{Fe_2O_3} = 0,5n_{Fe(OH)_2} = 0,0625(mol)\\ \Rightarrow m_{Fe_2O_3} = 0,0625.160 = 10(gam)\)
\(3NaOH+FeCl_3\rightarrow Fe\left(OH\right)_3+3NaCl\)
\(n_{NaCl}=n_{NaOH}=0,2.3=0,6\left(mol\right)\)
=> \(C_{M\left(NaCl\right)}=\dfrac{0,6}{0,2}=3M\)
\(n_{Fe\left(ỌH\right)_3}=\dfrac{1}{3}n_{NaOH}=0,2\left(mol\right)\)
\(2Fe\left(OH\right)_3-^{t^o}\rightarrow Fe_2O_3+3H_2O\)
Ta có \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=0,1\left(mol\right)\)
=> m Fe2O3 = 0,1 . 160=16(g)