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mKOH=28(g)
nKOH=0.5(mol)
PTHH:2KOH+H2SO4->K2SO4+2H2O
a)Theo pthh:nH2SO4=1/2 nKOH->nH2SO4=0.25(mol)
mH2SO4=0.25*98=24.5(g)
C%ddH2SO4=24.5/100*100=24.5%
theo pthh:nK2SO4=nH2SO4->nK2SO4=0.25(mol)
mK2SO4=0.25*(39*2+96)=43.5(g)
c)mdd sau phản ứng:200+100=300(g)
d) C% muối=43.5:300*100=14.5%
Đổi 300ml = 0,3 lít
Ta có: \(n_{H_2SO_4}=0,3.0,5=0,15\left(mol\right)\)
PTHH: H2SO4 + 2KOH ---> K2SO4 + 2H2O
a. Theo PT: \(n_{KOH}=2.n_{H_2SO_4}=2.0,15=0,3\left(mol\right)\)
\(\Rightarrow V_{dd_{KOH}}=\dfrac{0,3}{0,2}=1,5\left(lít\right)\)
b. Theo PT: \(n_{K_2SO_4}=n_{H_2SO_4}=0,15\left(mol\right)\)
\(\Rightarrow m_{K_2SO_4}=0,15.174=26,1\left(g\right)\)
c. Ta có: \(V_{dd_{K_2SO_4}}=V_{dd_{H_2SO_4}}=0,3\left(lít\right)\)
\(\Rightarrow C_{M_{K_2SO_4}}=\dfrac{0,15}{0,3}=0,5M\)
Câu 16:
PTHH: \(KOH+HCl\rightarrow KCl+H_2O\)
Ta có: \(n_{HCl}=0,25\cdot1,5=0,375\left(mol\right)=n_{KOH}=n_{KCl}\)
\(\Rightarrow\left\{{}\begin{matrix}V_{KOH}=\dfrac{0,375}{2}=0,1875\left(l\right)\\C_{M_{KCl}}=\dfrac{0,375}{0,1875+0,25}\approx0,86\left(M\right)\end{matrix}\right.\)
Câu 18:
PTHH: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
a) Ta có: \(n_{H_2SO_4}=\dfrac{200\cdot14,7\%}{98}=0,3\left(mol\right)\)
\(\Rightarrow n_{KOH}=0,6\left(mol\right)\) \(\Rightarrow m_{ddKOH}=\dfrac{0,6\cdot56}{5,6\%}=600\left(g\right)\) \(\Rightarrow V_{ddKOH}=\dfrac{600}{10,45}\approx57,42\left(ml\right)\)
b) Theo PTHH: \(n_{K_2SO_4}=0,3\left(mol\right)\) \(\Rightarrow C\%_{K_2SO_4}=\dfrac{0,3\cdot174}{600+200}\cdot100\%=6,525\%\)
PTHH: \(H_2SO_4+2KOH\rightarrow K_2SO+2H_2O\)
Ta có: \(n_{H_2SO_4}=0,2\cdot1=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{KOH}=0,4\left(mol\right)\\n_{K_2SO_4}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{ddKOH}=\dfrac{\dfrac{0,4\cdot56}{6\%}}{1,048}\approx356,2\left(ml\right)\\C_{M_{K_2SO_4}}=\dfrac{0,2}{0,2+0,3562}\approx0,36\left(M\right)\end{matrix}\right.\)
\(n_{H_2SO_4}=1.0,2=0,2\left(mol\right)\\ H_2SO_4+2KOH\rightarrow K_2SO_4+2H_2O\\ 0,2.........0,4........0,2.......0,2\left(mol\right)\\ a.m_{ddKOH}=\dfrac{0,4.56.100}{6}=\dfrac{1120}{3}\left(g\right)\\ V_{ddKOH}=\dfrac{\dfrac{1120}{3}}{1,048}=\dfrac{140000}{393}\left(ml\right)\approx0,356\left(l\right)\)
\(b.C_{MddK_2SO_4}=\dfrac{0,2}{\dfrac{140000}{393}+0,2}\approx0,00056\left(M\right)\)
\(n_{H_2SO_4}=0,1.0,75=0,075mol\\ H_2SO_4+2KOH\rightarrow K_2SO_4+2H_2O\)
0,075 0,15 0,075 0,15
\(a)m_{K_2SO_4}=0,075.175=13,05mol\)
\(b)H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\\ n_{NaOH}=0,075.2=0,15mol\\ m_{ddNaOH}=\dfrac{0,15.40}{15\%}\cdot100\%=40g\\ V_{ddNaOH}=\dfrac{40}{1,05}=38,1ml\)
\(n_{H_2SO_4}=0,1.0,5=0,05\left(mol\right)\)
\(PT:H_2SO_4+2KOH\rightarrow K_2SO_4+2H_2O\)
vậy: 0,05------------->0,1-------->0,05(mol)
b) do đó: \(V_{ddKOH}=\dfrac{n}{C_M}=\dfrac{0,1}{0,2}=0,5\left(lít\right)\)
c) \(m_{K_2SO_4}=n.M=0,05.174=8,7\left(g\right)\)
\(C_{M_{K_2SO_4}}=\dfrac{n}{V}=\dfrac{0,05}{0,1+0,5}\approx0,083\left(M\right)\)
a) H2SO4+2 KOH -> K2SO4+ 2H20
b) 100ml= 0,1 l
nH2SO4=0,5*0.1=0,05(mol)