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\(n_{Na_2O}=\dfrac{15,5}{62}=0,25\left(mol\right)\\ PTHH:Na_2O+H_2O\rightarrow2NaOH\\ n_{NaOH}=2.0,25=0,5\left(mol\right)\\ a,C_{MddNaOH}=\dfrac{0,5}{0,5}=1\left(M\right)\\ b,2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\\ n_{H_2SO_4}=n_{Na_2SO_4}=\dfrac{0,5}{2}=0,25\left(mol\right)\\ m_{H_2SO_4}=0,25.98=24,5\left(g\right)\\ m_{ddH_2SO_4}=\dfrac{24,5.100}{20}=122,5\left(g\right)\\ V_{ddH_2SO_4}=\dfrac{122,5}{1,14}\approx107,456\left(ml\right)\\ c,V_{ddsau}=V_{ddNaOH}+V_{ddH_2SO_4}\approx0,5+0,107456=0,607456\left(l\right)\\C_{MddNa_2SO_4}\approx\dfrac{ 0,25}{0,607456}\approx0,411552\left(M\right)\)
Anh bổ sung câu c)
\(C_{MddNa_2SO_4}=\dfrac{0,25}{0,09879+0,5}=0,4175\left(M\right)\)
nNa2O = 0,125 mol
a. Na2O + H2O --------> NaOH
0,125 mol ----------------> 0,125 mol
--> CM(NaOH) n/V = 0,125/ 0,25 = 0,5 M
b. H2SO4 + 2NaOH ------> Na2SO4 + H2O
....0,0625 <---0,125 mol
--> mH2SO4(nguyên chất) = 0,0625*98 = 6,125 g
--> mH2SO4(20%) = 6,125/20% = 30,625 g
suy ra V = m/D = 30,625 / 1,14 = 26,86 ml
nNa2O = 0,125 mol
a. Na2O + H2O --------> NaOH
0,125 mol ----------------> 0,125 mol
--> CM(NaOH) n/V = 0,125/ 0,25 = 0,5 M
b. H2SO4 + 2NaOH ------> Na2SO4 + H2O
....0,0625 <---0,125 mol
--> mH2SO4(nguyên chất) = 0,0625*98 = 6,125 g
--> mH2SO4(20%) = 6,125/20% = 30,625 g
suy ra V = m/D = 30,625 / 1,14 = 26,86 ml
Na2O + H2O → 2NaOH
1 1 2
0,1 0,2
a). nNa2O=\(\dfrac{6,2}{62}\)= 0,1(mol)
CM=\(\dfrac{n}{V}\)=\(\dfrac{0,1}{4}\)= 0,025M
b). Na2O + H2SO4 → Na2SO4 + H2O
1 1 1 1
0,1 0,1
mH2SO4= n.M = 0,1 . 98 = 9,8g
⇒mddH2SO4= mct=\(\dfrac{mct.100\%}{C\%}\)= \(\dfrac{9,8.100}{20}\)= 49(g).
1. \(n_{Na_2O}=\dfrac{15,5}{62}=0,25\left(mol\right)\)
PTHH: Na2O + H2O → 2NaOH
Mol: 0,25 0,5
\(C_{M_{ddNaOH}}=\dfrac{0,5}{0,5}=1M\)
2.
PTHH: 2NaOH + H2SO4 → Na2SO4 + 2H2O
Mol: 0,5 0,25
\(m_{ddH_2SO_4}=\dfrac{0,25.98.100}{20}=122,5\left(g\right)\)
\(V_{ddH_2SO_4}=\dfrac{122,5}{1,14}=107,456\left(ml\right)\)
\(n_{Na2O}=\dfrac{m_{Na2O}}{M_{Na2O}}=0,25\left(mol\right)\)
\(Na_2O+H_2O\rightarrow2NaOH\)
0,25 mol - 0,25 mol - 0,5 mol
a) \(C_{M_{NaOH}}=\dfrac{n_{NaOH}}{V_{NaOH}}=1\left(M\right)\)
b) \(H_2SO_4+2NaOH\rightarrow Na_2SO4+2H_2O\)
0,25 mol - 0,5 mol - 0,25 mol - 0,5 mol
\(m_{ctH2SO4}=n_{H2SO4}.M_{H2SO4}=24,5\left(g\right)\)
\(C_{\%_{H2SO4}}=\dfrac{m_{ctH2SO4}}{m_{ddH2SO4}}.100\%\)
\(\Rightarrow m_{ddH2SO4}=\dfrac{m_{ctH2SO4}.100\%}{C_{\%_{H2SO4}}}=122,5\left(g\right)\)
\(D_{H2SO4}=\dfrac{m_{ddH2SO4}}{V_{H2SO4}}\Rightarrow V_{H2SO4}=\dfrac{m_{ddH2SO4}}{D_{H2SO4}}\approx107,46\left(ml\right)\)
\(n_{HCl}=\dfrac{V}{22,4}=\dfrac{5,6}{22,4}=0,25mol\)
\(m_{HCl}=n.M=0,25.36,5=9,125g\)
\(C_{M_{HCl}}=\dfrac{n}{V}=\dfrac{0,25}{0,1}=2,5M\)
mdd=v.d=mH2O=0,1.1000.1=100g
\(C\%_{HCl}=\dfrac{m_{HCl}.100}{m_{dd}}=\dfrac{9,125.100}{100}=9,125\%\)
a, \(n_{K_2O}=\dfrac{4,7}{94}=0,05\left(mol\right)\)
PTHH: K2O + H2O → 2KOH
Mol: 0,05 0,1
b) \(C_{M_{ddKOH}}=\dfrac{0,1}{0,02}=5M\)
c)
PTHH: KOH + HCl → KCl + H2O
Mol: 0,1 0,1 0,1
\(m_{ddHCl}=\dfrac{0,1.36,5.100}{20}=18,25\left(g\right)\)
\(\Rightarrow V_{ddHCl}=\dfrac{18,25}{0,9125}=103,9\left(ml\right)=0,1039\left(l\right)\)
d) \(C_{M_{ddKCl}}=\dfrac{0,1}{0,02+0,1039}=0,8071M\)
\(n_{K_2O}=\dfrac{23.5}{94}=0.25\left(mol\right)\)
\(K_2O+H_2O\rightarrow2KOH\)
\(0.25...................0.5\)
\(C_{M_{KOH}}=\dfrac{0.5}{0.5}=1\left(M\right)\)
\(2KOH+H_2SO_4\rightarrow K_2SO_4+H_2O\)
\(0.5............0.25............0.25\)
\(m_{dd_{H_2SO_4}}=\dfrac{0.25\cdot98}{20\%}=122.5\left(g\right)\)
\(V_{dd_{H_2SO_4}}=\dfrac{122.5}{1.14}=107.5\left(ml\right)=0.1075\left(l\right)\)
\(C_{M_{K_2SO_4}}=\dfrac{0.25}{0.1075+0.5}=0.4\left(M\right)\)
nK2O = 23,5 : 94 = 0,25 (mol)
Vdd = 500ml = 0,5l
PT K2O + H2O ==> 2KOH
TPT 1 1 2 (mol)
TĐB: 0,25 --> 0,5 (mol)
a) CM KOH = 0,5 : 0,5 = 1(M)
b) PT: H2SO4 + 2KOH ==> K2SO4 + 2H2O
TPT: 1 2 1 2 (mol)