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\(a,Gọi\left\{{}\begin{matrix}n_{CH_4}=a\left(mol\right)\\n_{C_2H_4}=b\left(mol\right)\\n_{C_2H_2}=c\left(mol\right)\end{matrix}\right.\\ n_{hhkhí}=0,4\left(mol\right)\\ n_{CO_2}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\\ n_{Br_2}=\dfrac{64}{160}=0,4\left(mol\right)\\ PTHH:C_2H_4+Br_2\rightarrow C_2H_4Br_2\\ Mol:a\rightarrow a\\ C_2H_2+2Br_2\rightarrow C_2H_2Br_4\\ Mol:b\rightarrow2b\\ CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\\ Mol:a\rightarrow2a\rightarrow a\)
\(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\\ Mol:b\rightarrow3b\rightarrow2b\\ 2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\\ Mol:c\rightarrow2,5c\rightarrow2c\\ Hệ.pt\left\{{}\begin{matrix}a+b+c=0,4\\b+2c=0,4\\a+2b+2c=0,7\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\left(mol\right)\\b=0,2\left(mol\right)\\c=0,1\left(mol\right)\end{matrix}\right.\)
\(\%V_{CH_4}=\%V_{C_2H_2}=\dfrac{0,1}{0,4}=25\%\\ \%V_{C_2H_4}=\dfrac{0,2}{0,4}=50\%\)
\(m_{CH_4}=0,1.16=1,6\left(g\right)\\ m_{C_2H_4}=28.0,2=5,6\left(g\right)\\ m_{C_2H_2}=0,1.26=2,6\left(g\right)\\ \%m_{CH_4}=\dfrac{1,6}{1,6+5,6+2,6}=16,32\%\\ \%m_{C_2H_4}=\dfrac{5,6}{1,6+5,6+2,6}=57,14\%\\ \%m_{C_2H_2}=100\%-16,32\%-57,14\%=26,54\%\)
\(b,PTHH:C_2H_5OH\rightarrow C_2H_4+H_2O\\ Mol:0,2\leftarrow0,2\\ m_{C_2H_5OH}=0,2.46=9,2\left(g\right)\)
Dài quá!!!
a) PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
Hiện tượng: Dung dịch Brom bị nhạt màu
b) Ta có: \(n_{Br_2}=\dfrac{24}{160}=0,15\left(mol\right)=n_{C_2H_4Br_2}\)
\(\Rightarrow m_{C_2H_4Br_2}=0,15\cdot188=28,2\left(g\right)\)
c) Theo PTHH: \(n_{C_2H_4}=0,15\left(mol\right)\)
\(\Rightarrow\%V_{C_2H_4}=\dfrac{0,15\cdot22,4}{4,48}\cdot100\%=75\%\)
\(\Rightarrow\%V_{CH_4}=25\%\)
a) Khi cho metan và axetilen qua dung dịch brom thì metan không phản ứng với brom nên thoát ra khỏi bình còn axetilen phản ứng với dung dịch brom.
=> 20,16 lít khí thoát là metan CH4
=> V axetilen = 40,32 - 20,16 = 20,16 lít
<=> %V CH4 = %V C2H2 = 50%
b)
nCH4 = nC2H2 = \(\dfrac{20,16}{22,4}\)= 0,9 lít
CH4 + 2O2 → CO2 + 2H2O
C2H2 + \(\dfrac{5}{2}\)O2 → 2CO2 + H2O
Theo tỉ lệ phản ứng cháy => nO2 cần để đốt cháy hết hỗn hợp khí = 2nCH4+\(\dfrac{5}{2}\)nC2H2= 4,05 mol.
=> V O2 cần dùng = 4,05.22,4 = 90,72 lít
a, PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
b, - Khí thoát ra là CH4.
⇒ VCH4 = 4,48 (l)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{4,48}{11,2}.100\%=40\%\\\%V_{C_2H_4}=100-40=60\%\end{matrix}\right.\)
a) C2H4 + Br2 --> C2H4Br2
b) nBr2 = 0,2.0,2 = 0,04 (mol)
PTHH: C2H4 + Br2 --> C2H4Br2
0,04<--0,04
=> \(m_{C_2H_4}=0,04.28=1,12\left(g\right)\)
\(m_{CH_4}=n_{CH_4}.M_{CH_4}=\left(\dfrac{1,12}{22,4}-0,04\right).16=0,16\left(g\right)\)
c) \(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,04.22,4}{1,12}.100\%=80\%\\\%V_{CH_4}=100\%-80\%=20\%\end{matrix}\right.\)
a, nBr2 = 8/160 = 0,05 (mol)
PTHH: C2H4 + Br2 -> C2H4Br2
Mol: 0,05 <--- 0,05 <--- 0,05
Vhh khí = 2,8/22,4 = 0,125 (mol)
%VC2H4 = 0,05/0,125 = 40%
%CH4 = 100% - 40% = 60%
b, nCH4 = 0,125 - 0,05 = 0,075 (mol)
PTHH: C2H4 + 3O2 -> (t°) 2CO2 + 2H2O
Mol: 0,05 ---> 0,15
CH4 + 2O2 -> (t°) CO2 + 2H2O
Mol: 0,075 ---> 0,15
Vkk = (0,15 + 0,15) . 5 . 22,4 = 33,6 (l)
a) \(n_{Br_2\left(p\text{ư}\right)}=\dfrac{6,4}{160}=0,04\left(mol\right);n_{hh}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,04<--0,04
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,04}{0,6}.100\%=6,67\%\\\%V_{CH_4}=100\%-6,67\%=93,33\%\end{matrix}\right.\)
b) \(n_{CH_4}=0,6-0,04=0,56\left(mol\right)\)
PTHH: \(CH_4+2O_2\xrightarrow[]{t^o}CO_2+2H_2O\)
0,56----------->0,56
\(C_2H_4+3O_2\xrightarrow[]{t^o}2CO_2+2H_2O\)
0,04----------->0,08
\(\Rightarrow V_{CO_2}=\left(0,08+0,56\right).22,4=14,336\left(l\right)\)
a. \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
b. nBr2 pứ = 0,2 . 0,5 = 0,1 (mol)
=> nC2H4 = 0,1 (mol)
=> %V C2H4 = \(\dfrac{0,1}{0,3}=33,33\%\)
=> %V CH4 = 66,67%
c. nC2H4Br2 = 0,1 (mol)
=> mC2H4Br2 = 0,1. 188 = 18,8 (g)
d.
\(CH_4+2O_2\rightarrow CO_2+2H_2O\)
0,2 ...... 0,4 (mol)
\(C_2H_4+3O_2\rightarrow2CO_2+2H_2O\)
0,1........ 0,3 (mol)
=> nO2 = 0,7 (mol)
=> V KK = 78,4 (l)
PTHH: \(CH_4+2O_2\xrightarrow[]{t^o}CO_2+2H_2O\)
Ta có: \(n_{CO_2}=\dfrac{1,68}{22,4}=0,075\left(mol\right)=n_{CH_4}\)
Đặt \(\left\{{}\begin{matrix}n_{C_2H_4}=a\left(mol\right)\\n_{C_2H_2}=b\left(mol\right)\end{matrix}\right.\) \(\Rightarrow a+b=\dfrac{5,04}{22,4}-0,075=0,15\) (1)
PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
Theo PTHH: \(28a+26b=4,1\) (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}a=n_{C_2H_4}=0,1\left(mol\right)\\b=n_{C_2H_2}=0,05\left(mol\right)\end{matrix}\right.\)
Mặt khác: \(n_{hh}=\dfrac{5,04}{22,4}=0,225\left(mol\right)\) \(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,075}{0,225}\cdot100\%\approx33,33\%\\\%V_{C_2H_4}=\dfrac{0,1}{0,225}\cdot100\%\approx44,44\%\\\%V_{C_2H_2}=22,23\%\end{matrix}\right.\)
\(n_{CO_2}=\dfrac{9,916}{24,79}=0,4\left(mol\right);n_{CH_4}=\dfrac{7,437}{24,79}=0,3\left(mol\right)\\ a,CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\\ C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\\ Đặt:n_{CH_4}=a\left(mol\right);n_{C_2H_4}=b\left(mol\right)\left(a,b>0\right)\\ \Rightarrow\left\{{}\begin{matrix}a+2b=0,4\\a+b=0,3\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\\ \Rightarrow\%V_{CH_4}=\%n_{CH_4}=\dfrac{a}{0,3}.100\%=\dfrac{0,2}{0,3}.100\approx66,667\%\\ \Rightarrow\%V_{C_2H_4}\approx33,333\%\\ c,C_2H_4+Br_2\rightarrow C_2H_4Br_2\\ n_{Br_2}=n_{C_2H_4}=0,1\left(mol\right)\\ \Rightarrow C_{MddBr_2}=\dfrac{0,1}{0,2}=0,5\left(M\right)\)
Chỗ kia chắc 200ml dung dịch Br2 chứ 200gam thì cần cho thêm KLR á em