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\(CuO+CO\rightarrow Cu+CO_2\)
..x..........x.........................
\(PbO+CO\rightarrow Pb+CO_2\)
..y........y........................
- Theo bài ra ta có hệ : \(\left\{{}\begin{matrix}80x+223y=3,83\\x+y=0,03\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}x=0,02\\y=0,01\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{CuO}=1,6\\m_{PbO}=2,23\end{matrix}\right.\) ( g )
b, \(n_K=n_{CO_2}=x+y=0,03\left(mol\right)\)
\(\Rightarrow V=0,672\left(l\right)\)
c, \(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\)
........................0,03........0,03.............
\(\Rightarrow m_{kt}=3\left(g\right)\)
Đặt \(\left\{{}\begin{matrix}n_{CuO}=x\left(mol\right)\\n_{PbO}=y\left(mol\right)\end{matrix}\right.\)
\(m_{CuO}+m_{PbO}=3,83\\ \Rightarrow80x+223y=3,83\left(1\right)\)
\(PTHH:CuO+CO\underrightarrow{t^o}Cu+CO_2\uparrow\\ \left(mol\right)......x\rightarrow..x....x.....x\\ PTHH:PbO+CO\underrightarrow{t^o}Pb+CO_2\uparrow\\ \left(mol\right)......y\rightarrow..y....y.....y\\ n_{CO}=\dfrac{0,84}{28}=0,03\\ \Rightarrow x+y=0,03\left(2\right)\)
Từ (1) và (2) ta có hpt \(\left\{{}\begin{matrix}80x+223y=3,83\\x+y=0,03\end{matrix}\right.\)
Giải hpt ta được \(\left\{{}\begin{matrix}x=0,02\\y=0,01\end{matrix}\right.\)
\(a,\left\{{}\begin{matrix}m_{CuO}=80.0,02=1,6\left(g\right)\\m_{PbO}=3,83-1,6=2,23\left(g\right)\end{matrix}\right.\)
\(b,V_{CO_2}=\left(x+y\right).22,4=\left(0,02+0,01\right).22,4=0,672\left(l\right)\)
\(c,n_{CO_2}=x+y=0,02+0,01=0,03\left(mol\right)\\ PTHH:Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3\downarrow+H_2O\\ \left(mol\right)................0,03\rightarrow0,03\\ m_{CaCO_3}=0,03.100=3\left(g\right)\)
A, Gọi X,y lần lượt là số mol của Mg và Al
Pthh:
Mg + H2SO4---> MgSO4 + H2
X. X. X. X
2Al + 3H2SO4---> Al2(SO4)3+3H2
Y. 1.5y. Y. 1.5y
Ta có pt:
24x + 27y= 1.95
X+1.5y=2.24/22.4=0.1
=> X=0.025, Y=0.05
%Mg= 0.025×24×100)/1.95=30.8%
%Al= 100%-30.8%=69.2%
mH2SO4= 0.025+1.5×0.05=0.1g
mH2= (0.025+0.05)×2=0.15g
C, Mdd H2SO4 = 0.1/6.5×100=1.54g
MddY= 1.54+1.95-0.15=3.34g
%MgSO4 vs %Al2(SO4)3 b tự tính nha
a, PT: \(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_{3\downarrow}+H_2O\)
\(CO+CuO\underrightarrow{t^o}Cu+CO_2\)
Ta có: \(n_{CaCO_3}=\dfrac{5}{100}=0,05\left(mol\right)\)
Theo PT: \(n_{Ca\left(OH\right)_2}=n_{CaCO_3}=0,05\left(mol\right)\Rightarrow m_{Ca\left(OH\right)_2}=0,05.74=3,7\left(g\right)\)
\(\Rightarrow m_{ddCa\left(OH\right)_2}=\dfrac{3,7}{1,85\%}=200\left(g\right)\)
b, \(n_{CO_2}=n_{CaCO_3}=0,05\left(mol\right)\)
Ta có: \(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)
Theo PT: \(n_{CO}=n_{CuO}=0,1\left(mol\right)\)
\(\Rightarrow V=V_{CO_2}+V_{CO}=0,05.22,4+0,1.22,4=3,36\left(l\right)\)
a)
nBr2 = 0,2.0,2 = 0,04 (mol)
nCaCO3 = \(\dfrac{10}{100}=0,1\left(mol\right)\)
PTHH: C2H4 + Br2 --> C2H4Br2
0,04<--0,04---->0,04
C2H4 + 3O2 --to--> 2CO2 + 2H2O
0,04--------------->0,08
CH4 + 2O2 --to--> CO2 + 2H2O
0,02<-------------0,02
Ca(OH)2 + CO2 --> CaCO3 + H2O
0,1<------0,1
=> \(\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,02}{0,02+0,04}.100\%=33,33\%\\\%V_{C_2H_4}=\dfrac{0,04}{0,02+0,04}.100\%=66,67\%\end{matrix}\right.\)
b) mC2H4Br2 = 0,04.188 = 7,52 (g)
\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ a,PTHH:MgCO_3+H_2SO_4\rightarrow MgSO_4+H_2O+CO_2\uparrow\\ MgO+H_2SO_4\rightarrow MgSO_4+H_2O\\ \Rightarrow n_{MgCO_3}=n_{CO_2}=0,1\left(mol\right)\\ \Rightarrow m_{MgCO_3}=0,1\cdot84=8,4\left(g\right)\\ \Rightarrow\%_{MgCO_3}=\dfrac{8,4}{10,4}\cdot100\%\approx80,77\%\\ \Rightarrow\%_{MgO}=100\%-80,77\%=19,23\%\)
\(b,m_{MgO}=10,4-8,4=2\left(g\right)\\ \Rightarrow n_{MgO}=\dfrac{2}{40}=0,05\left(mol\right)\\ \Rightarrow\sum n_{H_2SO_4}=n_{MgCO_3}+n_{MgO}=0,15\left(mol\right)\\ \Rightarrow\sum m_{H_2SO_4}=0,15\cdot98=14,7\left(g\right)\\ \Rightarrow\sum m_{dd_{H_2SO_4}}=\dfrac{14,7}{9,8\%}=150\left(g\right)\\ \sum n_{MgSO_4}=\sum n_{H_2SO_4}=0,15\left(mol\right)\\ \Rightarrow\sum m_{MgSO_4}=0,15\cdot120=18\left(g\right)\\ \Rightarrow C\%_{MgSO_4}=\dfrac{18}{10,4+150-0,1\cdot44}\approx11,54\%\)
a) \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Cu+HCl\rightarrow\)(không phản ứng)
2Al + 6HCl => 2AlCl3 + 3H2
0,3/3*2 (6,72/22,4)
=> mAl = 0,2 *27 =5,4g; mCu = 11,8 - 5,4 = 6,4g
\(Đặt:n_{CH_4}=a\left(mol\right),n_{C_2H_2}=b\left(mol\right)\)
\(n_{hh}=a+b=0.35\left(mol\right)\left(1\right)\)
\(BTC:\)
\(a+2b=0.6\)
\(a=1\)
\(b=0.25\)
\(\%CH_4=\dfrac{0.1}{0.35}\cdot100\%=28.57\%\)
\(\%C_2H_2=71.43\%\)
\(\left\{{}\begin{matrix}n_{CH_4}=x\left(mol\right)\\n_{C_2H_2}=y\left(mol\right)\end{matrix}\right.\)⇒ x + y = \(\dfrac{7,84}{22,4} = 0,35(mol)\)
\(CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_2 + \dfrac{5}{2}O_2 \xrightarrow{t^o} 2CO_2 + H_2O\\ CO_2 + Ca(OH)_2 \to CaCO_3 + H_2O\)
Theo PTHH : x + 2y = \(\dfrac{60}{100} = 0,6(2)\)
Từ (1)(2) suy ra x = 0,1 ; y = 0,25
Vậy :
\(\%V_{CH_4} = \dfrac{0,1}{0,35}.100\% = 28,57\%\\ \%V_{C_2H_2} = 100\% - 28,57\% = 71,43\%\)
\(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\\ n_{CO_2}=n_{CaCO_3}=\dfrac{25}{100}=0,25\left(mol\right)\\ PTHH:CO+CuO\rightarrow\left(t^o\right)Cu+CO_2\\ n_{CO}=n_{CuO}=\dfrac{40}{80}=0,5\left(mol\right)\\ V_{hh\left(đktc\right)}=\left(n_{CO}+n_{CO_2}\right).22,4=\left(0,5+0,25\right).22,4=16,8\left(l\right)\)