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a, PT: \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
\(FeO+H_2SO_4\rightarrow FeSO_4+H_2O\)
Gọi: \(\left\{{}\begin{matrix}n_{CuO}=x\left(mol\right)\\n_{FeO}=y\left(mol\right)\end{matrix}\right.\) ⇒ 80x + 72y = 11,2 (1)
Ta có: \(n_{H_2SO_4}=0,15.1=0,15\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{CuO}+n_{FeO}=x+y=0,15\left(2\right)\)
Từ (1) và (2) ⇒ x = 0,05 (mol), y = 0,1 (mol)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{CuO}=\dfrac{0,05.80}{11,2}.100\%\approx35,71\%\\\%m_{FeO}\approx64,28\%\end{matrix}\right.\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{CuSO_4}=n_{Cu}=0,05\left(mol\right)\\n_{FeSO_4}=n_{FeO}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}C_{M_{CuSO_4}}=\dfrac{0,05}{0,15}=\dfrac{1}{3}\left(M\right)\\C_{M_{FeSO_4}}=\dfrac{0,1}{0,15}=\dfrac{2}{3}\left(M\right)\end{matrix}\right.\)
\(n_{H_2}=\dfrac{4.48}{22.4}=0.2\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(0.2.........0.4.........0.2......0.2\)
\(m_{Zn}=0.2\cdot65=13\left(g\right)\Rightarrow m_{ZnO}=14.6-13=1.6\left(g\right)\)
\(\%Zn=\dfrac{13}{14.6}\cdot100\%=89.04\%\)
\(\%ZnO=100\%-89.04\%=10.96\%\)
\(n_{ZnO}=\dfrac{1.6}{81}\approx0.02\left(mol\right)\)
\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
\(0.02........0.04........0.02........0.02\)
\(n_{HCl}=0.4+0.04=0.44\left(mol\right)\)
\(C_{M_{HCl}}=\dfrac{0.44}{0.8}=0.55\left(M\right)\)
Eeeee ngồi tính sang chấn thật nó ra số xấu lần mò hơn 20p chưa biết tính sai chỗ nào
a) PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
b) \(n_{H_2}=\dfrac{0,672}{22,4}=0,03\left(mol\right)\)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
_____0,02<---0,03<---------------------0,03
=> \(\left\{{}\begin{matrix}\%Al=\dfrac{0,02.27}{2,16}.100\%=25\%\\\%Cu=100\%-25\%=75\%\end{matrix}\right.\)
c) mH2SO4 = 0,03.98 = 2,94 (g)
=> \(C\%\left(H_2SO_4\right)=\dfrac{2,94}{200}.100\%=1,47\%\)
Đặt : \(n_{CuO}=a\left(mol\right),n_{ZnO}=b\left(mol\right)\)
\(\Rightarrow80a+81b=28,25g\left(1\right)\)
a) Pt : \(CuO+2HCl\rightarrow CuCl_2+H_2O\)
\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
b) Ta có : \(n_{HCl}=\dfrac{20\%.127,75}{100\%.36,5}=0,7\left(mol\right)\Rightarrow2a+2b=0.7\left(2\right)\)
Từ (1),(2) \(\Rightarrow\left\{{}\begin{matrix}a=0,1=n_{CuCl2}\\b=0,25=n_{ZnCl2}\end{matrix}\right.\)
c) \(m_{muối}=m_{CuCl2}+m_{ZnCl2}=0,1.135+0,25.136=47,5\left(g\right)\)
d) \(\left\{{}\begin{matrix}C\%_{CuCl2}=\dfrac{0,1.135}{28,25+127,75}.100\%=8,65\%\\C\%_{ZnCl2}=\dfrac{0,25.136}{28,25+127,75}.100\%=21,79\%\end{matrix}\right.\)
\(a.n_{CO_2}=\dfrac{3,36}{22,4}=0,15mol\\ Na_2CO_3+2HCl\rightarrow2NaCl+CO_2\uparrow+H_2O\left(1\right)\\ NaOH+HCl\rightarrow NaCl+H_2O\\ n_{Na_2CO_3}=n_{CO_2}=0,15mol\\ \%m_{Na_2CO_3}=\dfrac{0,15.106}{23,9}\cdot100=66,5\%\\ \%m_{NaOH}=100-66,5=33,5\%\)
b. Sai đề, vì
\(n_{HCl\left(thực,tế\right)}=\dfrac{200.3,65}{100}:36,5=0,2mol\\ n_{HCl\left(pư\right)}=0,15.2+\left(23,9-0,15.106\right):40=0,5mol\)
mà \(n_{CO_2}=0,15mol\Rightarrow n_{HCl}=0,3mol\left(pt1\right)\)(nên NaOH và Na2CO3 ko dư)
vậy cần ít nhất 0,5mol HCl để tính
⇒cần thay đổi \(m_{ddHCl}\) hoặc \(C_{\%HCl}\) để tính được câu b
a)
$Mg + H_2SO_4 \to MgSO_4 + H-2$
b) $n_{H_2SO_4} = n_{Mg} = \dfrac{4,8}{24} = 0,2(mol)$
$C\%_{H_2SO_4} = \dfrac{0,2.98}{200}.100\% = 9,8\%$
$n_{H_2} = n_{Mg} = 0,2(mol)$
$\Rightarrow m_{dd\ A} = 4,8 + 200 - 0,2.2 = 204,4(gam)$
$C\%_{MgSO_4} = \dfrac{0,2.120}{204,4}.100\% = 11,7\%$
c) $V_{H_2} = 0,2.22,4 = 4,48(lít)$
nH2 = \(\frac{1,68}{22,4}\) = 0,075 (mol)
Mg + 2HCl \(\rightarrow\) MgCl2 + H2\(\uparrow\) (1)
0,075 <--------0,075 <--0,075 (mol)
MgO + 2HCl \(\rightarrow\) MgCl2 + H2O (2)
%mMg= \(\frac{0,075.24}{5,8}\) . 100% = 31,03 %
%m MgO = 68,97%
nMgO = \(\frac{5,8-0,075.24}{40}\) = 0,1 (mol)
Theo pt(2) nMgCl2 = nMgO= 0,1 (mol)
mdd sau pư = 5,8 + 194,35 - 0,075.2 = 200 (g)
C%(MgCl2) = \(\frac{95\left(0,075+0,1\right)}{200}\) . 100% = 8,3125%