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\(n_{SO_3}=\dfrac{8}{80}=0,1\left(mol\right)\)
PTHH: SO3 + H2O --> H2SO4
0,1------------->0,1
\(m_{H_2SO_4\left(bđ\right)}=242.10\%=24,2\left(g\right)\)
mH2SO4(sau pư) = 24,2 + 0,1.98 = 34 (g)
mdd sau pư = 8 + 242 = 250 (g)
\(C\%_{dd.H_2SO_4.sau.pư}=\dfrac{34}{250}.100\%=13,6\%\)
\(a.Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\\ b.n_{Fe_2O_3}=\dfrac{24}{160}=0,15\left(mol\right)\\ n_{H_2SO_4}=3.0,15=0,45\left(mol\right)\\ m_{ddH_2SO_4}=\dfrac{0,45.98.100}{14,7}=300\left(g\right)\\ m_{ddsau}=24+300=324\left(g\right)\\ n_{Fe_2\left(SO_4\right)_3}=n_{Fe_2O_3}=0,15\left(mol\right)\\ C\%_{ddFe_2\left(SO_4\right)_3}=\dfrac{0,15.400}{324}.100\approx18,519\%\)
\(SO_3+H_2O\rightarrow H_2SO_4\)
\(n_{SO_3}=\dfrac{12}{80}=0,15\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{SO_3}=0,15\left(mol\right)\)
\(\Rightarrow C\%_{H_2SO_4}=\dfrac{0,15.98}{12+100}.100\%=13,125\%\)
\(SO_3+H_2O\rightarrow H_2SO_4\\ m_{H_2SO_4\left(tăng\right)}=\dfrac{98}{80}m=\dfrac{49}{40}m=1,225m\left(g\right)\\ m_{H_2SO_4\left(dd.14,7\%\right)}=14,7.200=29,4\left(g\right)\\ Ta.có:C\%_{ddH_2SO_4\left(cuối\right)}=20\%\\ \Leftrightarrow\dfrac{29,4+1,225m}{m+200}.100\%=20\%\\ m\approx10,3415\left(g\right)\)
\(m_{H_2SO_4}=9.8\left(g\right)\)
\(n_{H_2SO_4}=\dfrac{9.8}{98}=0.1\left(mol\right)\)
\(Đặt:n_{Ba\left(1\right)}=a\left(mol\right)\)
\(Ba+H_2SO_4\rightarrow BaSO_4+H_2\)
\(0.1........0.1.........0.1.........0.1\)
\(Ba+2H_2O\rightarrow Ba\left(OH\right)_2+H_2\left(1\right)\)
\(a..................a........a\)
\(m_{Ba\left(OH\right)_2}=171a\left(g\right)\)
\(m_{dd}=m_{Ba}+m_{ddH_2SO_4}-m_{H_2}-m_{BaSO_4}=\left(0.1+a\right)\cdot137+200-23.3-\left(0.1+a\right)\cdot2=190.2+136.8a\left(g\right)\)
\(C\%Ba\left(OH\right)_2=\dfrac{171a}{190.2+136.8a}\cdot100\%=2.51\%\)
\(\Leftrightarrow a=0.028\)
\(m_{Ba}=\left(0.1+0.028\right)\cdot137=17.536\left(g\right)\)
Số mình ra hơi lẻ chút ,hông biết đúng hay sai. Bạn xem thử nha
