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Trả lời:
\(n_{FeO}=\dfrac{10,8}{72}=0,15\left(mol\right)\)
\(m_{HCl}=\dfrac{150.18,25}{100}=27,375\left(g\right)=>n_{HCl}=\dfrac{27,375}{36,5}=0,75\left(mol\right)\)
PTHH :
\(FeO+2HCl-->FeCl_2+H_2O\)
\(\dfrac{0,15}{1}< \dfrac{0,75}{2}\)
\(=>FeO\) hết , \(HCl\) dư , tính theo FeO
a,
\(n_{FeCl_2}=n_{FeO}=0,15\left(mol\right)=>m_{FeCl_2}=0,15.127=19,05\left(g\right)\)
b, Sau phản ứng HCl dư nên :
\(m_{HCl_{dư}}=m_{HCl_{bđ}}-m_{HCl_{pư}}=36,5.0,75-36,5.0,3=16,425\left(g\right)\)
c, H\(_2\)SO\(_4\) phản ứng với FeO
\(FeO+H_2SO_4-->FeSO_4+H_2O\)
\(n_{H_2SO_4}=n_{FeO}=0,15mol=>m_{H_2SO_4}=0,15.98=14,7\left(g\right)\)
\(=>m_{ddH_2SO_4}=\dfrac{14,7.100}{20}=73,5\left(g\right)\)
a)
NaCl + AgNO3 -> NaNO3 + AgCl↓
0,1 0,1 0,1 0,1
b)
mNaCl = \(\frac{100.5,85}{100}=5,85\)=> nNaCl = 5,85 : 58,5 = 0,1 mol
mAgCl = 0,1 . 143,5 = 14,35 g
c)
mNaNO3 = 0,1 . 85 = 8,5 g
a, NaCl + AgNO3 --> NaNO3 +AgCl
1mol 1mol 1mol 1mol
0,1mol 0,1mol 0,1mol 0,1mol
b, mNaCl=100.5,85%=5,85g
nNaCl=\(\frac{5,85}{58,5}\)=0,1(mol)
mAgNO3=0,1.170=17g
mNaNO3=0,1.85=8,5g
mAgCl=0,1.143,5=14,35g
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ FeO+H_2SO_4\rightarrow FeSO_4+H_2O\)
nH2=4,48/22,4=0,2(mol)
=>nFe=0,2(mol)=>mFe=0,2.56=11,2(g)
=>mFeO=18,4-11,2=7,2(g)
b)nH2SO4=nH2=0,2(mol)
=>mH2SO4 7%=0,2.98=19,6(g)
=>mH2SO4 =19,6:7%=280(g)
c)mFeSO4=0,2.152=30,4(g)
mdd sau pư=18,4+280-0,2.2=298(g)
=>C%FeSO4=\(\frac{30,4}{298}.100\%\)=10,2%
Câu 4:
\(n_{H_2SO_4}=\dfrac{200.19,6}{98.100}=0,4mol\)
\(n_{BaCl_2}=\dfrac{50.25}{208.100}\approx0,06mol\)
H2SO4+BaCl2\(\rightarrow\)BaSO4\(\downarrow\)+2HCl
-Tỉ lệ: \(\dfrac{0,4}{1}>\dfrac{0,06}{1}\rightarrow H_2SO_4dư\)
\(n_{H_2SO_4\left(pu\right)}=n_{BaSO_4}=n_{BaCl_2}=0,06mol\)
\(m_{BaSO_4}=0,06.233=13,98gam\)
\(n_{HCl}=2n_{BaCl_2}=2.0,06=0,12mol\)
\(n_{H_2SO_4\left(dư\right)}=0,4-0,06=0,34mol\)
\(m_{dd}=200+50-13,98=236,02gam\)
C%HCl=\(\dfrac{0,12.36,5}{236,02}.100\approx1,9\%\)
C%H2SO4=\(\dfrac{0,34.98}{236,02}.100\approx14,12\%\)
Câu 1:\(\%O=\dfrac{48}{2R+48}.100=47\rightarrow\)(2R+48).47=4800
\(\rightarrow\)94R+2256=4800\(\rightarrow\)94R=2544\(\rightarrow\)R=27(Al)
Theo đề bài ta có : ⎧⎪ ⎪ ⎪⎨⎪ ⎪ ⎪⎩VddH2O4=601,2=50(ml)nNaOH=20.20100.40=0,1(mol){VddH2O4=601,2=50(ml)nNaOH=20.20100.40=0,1(mol)
nFe = 1,68/56 = 0,03 mol
a) Ta có PTHH :
2NaOH + H2SO4 -> Na2SO4 + 2H2O
0,1mol......0,05mol
=> CMH2SO4 = 0,05/0,05=1(M)
nAl2O3=10.2:102=0.1(mol)
PTHH:Al2O3+6HCl->2AlCl3+3H2O
theo pthh:nHCl:nAl2O3=6->nHCl=6*0.1=0.6(mol)
mHCl=0.6*36.5=21.9(g)
mdd HCl=21.9*100:14.6=150(g)
theo pthh:nAlCl3:nAl2O3=2->nAlCl3=0.1*2=0.2(mol)
mAlCl3=0.2*133.5=26.7(g)
mdd sau phản ứng:10.2+150=160.2
C%=26.7:160.2*100=16.7%
\(a,PTHH:\text{2Al + 3H2SO4 → Al2(SO4)3 + 3H2}\uparrow\)
\(\text{2Fe + 6H2SO4 → Fe2(SO4)3 + 6H2O + 3SO2}\uparrow\)
Cu không phản ứng.
Bạn tự viết tỉ lệ phương trình nhé :
\(b,nH2=0,4\left(mol\right)\)
Gọi số mol của Al , Fe lần lượt là x, y
\(\Rightarrow mCu=1\left(g\right)\)
\(\text{Nên : mAl+mFe=11}\)
\(\Rightarrow\left\{{}\begin{matrix}\text{27x+56y=11}\\\text{3/2x+y=0,4}\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)
\(\Rightarrow\%Al=\frac{0,2.27.100}{11}=49,09\%\)
\(\Rightarrow\%Fe=\frac{0,1.\frac{3}{2}.100}{0,3}=50\%\)
\(c,\text{Theo PT nH2SO4=nH2=0,4}\)
\(\Rightarrow\text{mH2SO4=39,2}\)
\(\Rightarrow m_{dd}=\text{39,2.100/9,8=400 g}\)
Cu k phản ứng với H2SO4
\(\Rightarrow m_{Cu}=m_{cr}=1\left(g\right)\)
\(\Rightarrow m_{hhcl}=12-1=11\left(g\right)\)
\(n_{Al}=x;n_{Fe}=y\)
\(PTHH:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(PTHH:Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
Theo đề ta có:
\(hpt:\left\{{}\begin{matrix}27x+56y=11\\1,5x+y=\frac{8,96}{22,4}\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\frac{0,2.27}{11}.100\%=49,1\left(\%\right)\\\%m_{Fe}=100-49,1=50,9\left(\%\right)\end{matrix}\right.\)
\(m_{H_2SO_4}=98.\left(\frac{0,2.3}{2}+0,1\right)=39,2\left(g\right)\)
\(\rightarrow m_{dd}=\frac{39,2.100}{9,8}=400\left(g\right)\)