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a) \(Ca+2H_2O\rightarrow Ca\left(OH\right)_2+H_2\uparrow\)
\(n_{Ca}=\frac{8}{40}=0,2mol\)
Theo phương trình \(n_{H_2}=n_{Ca}=0,2mol\)
\(\rightarrow V_{H_2}=0,2.22,4=4,48l\)
b) Theo phương trình \(n_{Ca\left(OH\right)_2}=n_{Ca}=0,2mol\)
\(\rightarrow m_{Ca\left(OH\right)_2}=0,2.\left(40+17.2\right)=14,8g\)
\(m_{ddsaupu}=m_{Ca}+m_{H_2O}-m_{H_2}\)
\(\rightarrow m_{ddsaupu}=8+200-0,2.2=207,6g\)
\(\rightarrow C\%_{ddCa\left(OH\right)_2}=\frac{14,8.100}{207,6}=7,13\%\)
a)\(n_K=\dfrac{0,39}{39}=0,01mol\)
\(\left\{{}\begin{matrix}X:KOH\\Y:H_2\end{matrix}\right.\)
b)\(2K+2H_2O\rightarrow2KOH+H_2\)
0,01 0,01 0,01 0,005
\(V_{H_2}=0,005\cdot22,4=0,112l=112ml\)
Sửa lại câu c .
\(n_{H_2SO_4}=\dfrac{49.40}{100}:98=0,2\left(mol\right)\)
\(PTHH:\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
trc p/u : 0,3 0,2
p/u : 0,2 0,2 0,2 0,2
sau : 0,1 0 0,2 0,2
-> Fe dư
\(m_{ddFeSO_4}=0,3.56+49-0,4=65,4\left(g\right)\) ( ĐLBTKL )
\(m_{FeSO_4}=0,2.152=30,4\left(g\right)\)
\(C\%=\dfrac{30,4}{65,4}.100\%\approx46,48\%\)
PTHH :
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
0,3 0,3 0,3 0,3
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
\(a,m_{Fe}=0,3.56=16,8\left(g\right)\)
\(b,C_M=\dfrac{n}{V}=\dfrac{0,3}{0,2}=1,5M\)
\(c,n_{H_2SO_4}=\dfrac{\dfrac{49.40}{100}}{98}=0,2\left(mol\right)\)
\(\rightarrow n_{FeSO_4}=n_{H_2SO_4}=0,2\left(mol\right)\)
\(m_{FeSO_4}=0,2.152=30,4\left(g\right)\)
\(m_{ddFeSO_4}=49+\left(0,2.56\right)-0,2.2=59,8\left(g\right)\)( định luật bảo toàn khối lượng )
\(C\%=\dfrac{30,4}{59,8}.100\%\approx50,84\%\)
Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
Theo PT: \(n_{H_2SO_4}=n_{FeSO_4}=n_{H_2}=n_{Fe}=0,1\left(mol\right)\)
a, \(V_{H_2}=0,1.24,79=2,479\left(l\right)\)
b, \(m_{H_2SO_4}=0,1.98=9,8\left(g\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{9,8}{9,8\%}=100\left(g\right)\)
c, Ta có: m dd sau pư = 5,6 + 100 - 0,1.2 = 105,4 (g)
\(\Rightarrow C\%_{FeSO_4}=\dfrac{0,1.152}{105,4}.100\%\approx14,42\%\)
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
Làm gộp các phần còn lại
Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\) \(\Rightarrow\left\{{}\begin{matrix}n_{Al_2\left(SO_4\right)_3}=0,1mol\\n_{H_2SO_4}=n_{H_2}=0,3mol\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\\m_{Al_2\left(SO_4\right)_3}=0,1\cdot342=34,2\left(g\right)\\m_{H_2SO_4}=0,3\cdot98=29,4\left(g\right)\end{matrix}\right.\)
\(nAl=\dfrac{2,7}{27}=0,1\left(mol\right)\)
\(mHCl=\dfrac{200.7,3\%}{100\%}=14,6\left(g\right)\)
\(nHCl=\dfrac{14,6}{36,5}=0,4\left(mol\right)\)
PTHH:
\(2Al+6HCl\rightarrow2AlCl_2+3H_2\)
2 6 2 3 (mol)
0,1 0,3 0,1 0,15 (mol)
LTL : 0,1 / 2 < 0,4/6
=> Al đủ , HCl dư
1. \(VH_2=0,15.22,4=3,36\left(l\right)\)
2. \(mH_2=0,15.2=0,3\left(g\right)\)
mdd = mAl + mddHCl - mH2 = 2,7 + 200 - 0,3 = 202,4 (g)
\(mH_2SO_{4\left(dưsaupứ\right)}=0,1.98=9,8\left(g\right)\)
\(mAlCl_2=0,1.98=9,8\left(g\right)\)
\(C\%_{ddH_2SO_4}=\dfrac{9,8.100}{202,4}=4,84\%\)
\(C\%_{AlCl_2}=\dfrac{9,8.100}{202,4}=4,84\%\)