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Zn + 2Hcl = Zncl2 + H2
x........2x......................x
Fe + 2HCl = FeCl2 + H2
y.......2y..........................y
65x + 56y = 18,6
x+y = 6.72/22.4
=> x =0,2 y=0,1
=> m Hcl = ( 2x + 2y) 36,5= 21,9
=> %Zn = 0,2.65:18,6.100%= 70%
%Fe = 30%
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\) (1)
\(R+H_2SO_4\rightarrow RSO_4+H_2\) (2)
Ta có: \(n_{H_2}=\frac{14,56}{22,4}=0,65\left(mol\right)\)
Đặt số mol của \(Al\) là \(a\) \(\Rightarrow n_R=\frac{2}{3}a\)
Theo PTHH(1): \(n_{Al}:n_{H_2\left(1\right)}=2:3\) \(\Rightarrow n_{H_2\left(1\right)}=\frac{3}{2}a\left(mol\right)\)
Theo PTHH(2): \(n_R=n_{H_2\left(2\right)}=\frac{2}{3}a\left(mol\right)\)
\(\Rightarrow\frac{3}{2}a+\frac{2}{3}a=0,65\) \(\Rightarrow a=0,3\)
\(\Rightarrow\left\{{}\begin{matrix}n_{Al}=0,3\left(mol\right)\\n_R=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Al}=0,3\cdot27=8,1\left(g\right)\\m_R=12,9-8,1=4,8\left(g\right)\end{matrix}\right.\)
\(\Rightarrow M_R=\frac{4,8}{0,2}=24\) \(\Rightarrow R\) là \(Mg\)
\(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
\(A+2HCl\rightarrow ACl_2+H_2\)
ta có:\(\dfrac{A}{16,25}=\dfrac{1}{0,25}\)=> A=65 ( A là Zn )
b) tự tính nha
Tương tự nè:
https://hoc24.vn/hoi-dap/question/64498.html
\(n_{H_2SO_4}=0,09\left(mol\right)\)
* Giả sử X không tác dụng H2SO4
\(\Rightarrow n_{Mg}=n_{H_2SO_4}=0,09\left(mol\right)\)
\(\Rightarrow m_X=-0,18\left(g\right)< 0\)
Chứng tỏ kim loại X tác dụng được với H2SO4 giải phóng khí
Bảo toàn H: \(n_{H_2}=n_{H_2SO_4}=0,09\left(mol\right)\)\(\Rightarrow V=2,016\left(l\right)\)
Đặt \(n_X=a\left(mol\right)\rightarrow n_{Mg}=3a\left(mol\right)\)
\(\Rightarrow24.3a+X.a=1,98\)\(\left(1\right)\)
\(Mg\left(3a\right)+H_2SO_4\left(3a\right)\rightarrow MgSO_4+H_2\)
\(2X\left(a\right)+nH_2SO_4\left(\dfrac{a.n}{2}\right)\rightarrow X_2\left(SO_4\right)_n+nH_2\)
\(\Rightarrow\dfrac{a.n}{2}+3a=0,09\)\(\left(2\right)\)
Từ (1), (2) \(\rightarrow\)\(\dfrac{1,98}{24.3+X}=\dfrac{0,09}{\dfrac{n}{2}+3}\)
Sau đó suy ra quan hệ của X và n rồi suy ra X
a) Do dd sau pư có 3 chát tan với nồng độ % bằng nhau
=> \(m_{Al_2\left(SO_4\right)_3}=m_{ZnSO_4}=m_{H_2SO_4\left(dư\right)}\)
Gọi số mol Al, Zn là a, b (mol)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
a----->1,5a------->0,5a----->1,5a
Zn + H2SO4 --> ZnSO4 + H2
b----->b--------->b----->b
=> \(\left\{{}\begin{matrix}m_{Al_2\left(SO_4\right)_3}=342.0,5a=171a\left(g\right)\\m_{ZnSO_4}=161b\left(g\right)\end{matrix}\right.\)
=> 171a = 161b
=> \(\dfrac{a}{b}=\dfrac{161}{171}\) (1)
Có: \(\dfrac{m_{Al}}{m_{Zn}}=\dfrac{27.n_{Al}}{65.n_{Zn}}=\dfrac{27}{65}.\dfrac{161}{171}=\dfrac{483}{1235}\)
b) \(n_{H_2}=1,5a+b=\dfrac{11,2}{22,4}=0,5\left(mol\right)\) (2)
(1)(2) => \(\left\{{}\begin{matrix}a=\dfrac{161}{825}\left(mol\right)\\b=\dfrac{57}{275}\left(mol\right)\end{matrix}\right.\)
=> \(x=\dfrac{161}{825}.27+\dfrac{57}{275}.65=\dfrac{5154}{275}\left(g\right)\)
\(m_{H_2SO_4\left(dư\right)}=m_{Al_2\left(SO_4\right)_3}=342.0,5\dfrac{161}{825}=\dfrac{9177}{275}\left(g\right)\)
=> \(m_{H_2SO_4\left(bđ\right)}=98\left(1,5a+b\right)+\dfrac{9177}{275}=\dfrac{22652}{275}\left(g\right)\)
=> \(y=\dfrac{\dfrac{22652}{275}.100}{10}=\dfrac{45304}{55}\left(g\right)\)
a) Do dd sau pư có 3 chát tan với nồng độ % bằng nhau
=> \(m_{Al_2\left(SO_4\right)_3}=m_{ZnSO_4}=m_{H_2SO_4\left(dư\right)}\)
Gọi số mol Al, Zn là a, b (mol)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
a----->1,5a------->0,5a----->1,5a
Zn + H2SO4 --> ZnSO4 + H2
b----->b--------->b----->b
=> \(\left\{{}\begin{matrix}m_{Al_2\left(SO_4\right)_3}=342.0,5a=171a\left(g\right)\\m_{ZnSO_4}=161b\left(g\right)\end{matrix}\right.\)
=> 171a = 161b
=> \(\dfrac{a}{b}=\dfrac{161}{171}\) (1)
Có: \(\dfrac{m_{Al}}{m_{Zn}}=\dfrac{27.n_{Al}}{65.n_{Zn}}=\dfrac{27}{65}.\dfrac{161}{171}=\dfrac{483}{1235}\)
b) \(n_{H_2}=1,5a+b=\dfrac{11,2}{22,4}=0,5\left(mol\right)\) (2)
(1)(2) => \(\left\{{}\begin{matrix}a=\dfrac{161}{825}\left(mol\right)\\b=\dfrac{57}{275}\left(mol\right)\end{matrix}\right.\)
=> \(x=\dfrac{161}{825}.27+\dfrac{57}{275}.65=\dfrac{5154}{275}\left(g\right)\)
\(m_{H_2SO_4\left(dư\right)}=m_{Al_2\left(SO_4\right)_3}=342.0,5\dfrac{161}{825}=\dfrac{9177}{275}\left(g\right)\)
=> \(m_{H_2SO_4\left(bđ\right)}=98\left(1,5a+b\right)+\dfrac{9177}{275}=\dfrac{22652}{275}\left(g\right)\)
=> \(y=\dfrac{\dfrac{22652}{275}.100}{10}=\dfrac{45304}{55}\left(g\right)\)
3X+4nHNO3=3X(NO3)n+nNo+2H2O
10X+12nHNO3=10X(NO3)n+nN2+6nH2o
goi nNO =x,nN2=y
nkhi=5,6:22,4=0,25mol
=>x+y=0,25 *
ta co m khi =30x+28y=7,2**
tu *va **.
=>x=0,1 ,y=0,15
theo pt 1 nHNO3=4nNo=0,4mol
theo pt 2 nHNO3=12nN2=1,8 mol
ta co nHno3=5.0,5=2,5 mol
vi 0,4+1,8<2,5 => Hno3 du X tg het
theo pt 1 nX=0,3/n
theo pt 2 nX=1,5/n
=>nX=1,8/n
=> 1.8/n.MX=16,2
=>X=9n
thu 1<=n<=3
=>X :Al