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Câu 92:
\(a,PTHH:Zn+2HCl\to ZnCl_2+H_2\\ ZnO+2HCl\to ZnCl_2+H_2O\\ n_{H_2}=\dfrac{2,24}{22,4}=0,1(mol)\\ \Rightarrow n_{Zn}=0,1(mol)\\ \Rightarrow m_{Zn}=0,1.65=6,5(g)\\ \Rightarrow \%_{Zn}=\dfrac{6,5}{14,6}.100\%\approx44,52\%\\ \Rightarrow \%_{ZnO}=100\%-44,52\%=55,48\%\\ b,m_{ZnO}=14,6-6,5=8,1(g)\\ \Rightarrow n_{ZnO}=\dfrac{8,1}{81}=0,1(mol)\\ \Rightarrow \Sigma n_{HCl}=2n_{Zn}+2n_{ZnO}=0,4(mol)\\ \Rightarrow V_{dd_{HCl}}=\dfrac{0,4}{0,5}=0,8(mol)\)
Câu 93:
\(n_{H_2}=\dfrac{16,8}{22,4}=0,75(mol)\\ PTHH:Fe+H_2SO_4\to FeSO_4+H_2\\ \Rightarrow n_{Fe}=n_{H_2}=0,75(mol)\\ \Rightarrow m_{Fe}=0,75.56=42(g)\\ b,n_{H_2SO_4}=n_{H_2}=0,75(mol)\\ \Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,75}{0,25}=3M\\ c,n_{FeSO_4}=0,75(mol)\\ \Rightarrow m_{CT_{FeSO_4}}=0,75.152=114(g)\\ V_{dd_{FeSO_4}}=V_{dd_{H_2SO_4}}=250(ml)\\ \Rightarrow m_{dd_{FeSO_4}}=250.1,1=275(g)\\ \Rightarrow C\%_{FeSO_4}=\dfrac{114}{275}.100\%\approx41,45\%\)
\(d,m_{FeSO_4.5H_2O}=242.0,75=181,5(g)\)
Đổi 400ml = 0,4 lít
nH2SO4 = CmH2S04 * VH2SO4
= 1 * 0,4
= 0,4
PTHH: 2NaOH + H2SO4 ----> Na2SO4 + 2H2O
mol : 0,8 0,4 0,4 0,8
mNaOH = 0,8 * 40 = 32 (g)
mdd NaOH = 32 * 100 =320
10
Câu 7:
a, \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
b, \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Theo PT: \(n_{Fe}=n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,1.56}{10}.100\%=56\%\\\%m_{CuO}=44\%\end{matrix}\right.\)
c, \(n_{CuO}=\dfrac{10-0,1.56}{80}=0,055\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{Fe}+n_{CuO}=0,155\left(mol\right)\)
\(\Rightarrow C\%_{H_2SO_4}=\dfrac{0,155.98}{100}.100\%=15,19\%\)
d, Theo PT: \(\left\{{}\begin{matrix}n_{FeSO_4}=n_{Fe}=0,1\left(mol\right)\\n_{CuSO_4}=n_{CuO}=0,055\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{FeSO_4}=0,1.152=15,2\left(g\right)\\m_{CuSO_4}=0,055.160=8,8\left(g\right)\end{matrix}\right.\)
Câu 8:
a, \(CuCO_3+2HCl\rightarrow CuCl_2+CO_2+H_2O\)
b, \(n_{CO_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
Theo PT: \(n_{CuCO_3}=n_{CO_2}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{CuCO_3}=\dfrac{0,15.124}{20}.100\%=93\%\\\%m_{CuCl_2}=7\%\end{matrix}\right.\)
c, \(n_{HCl}=2n_{CO_2}=0,3\left(mol\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\)
BÀI 6
nfe= 0,1(mol)
Fe + 2HCl ➝ FeCl2 + H2
0,1➝ 0,2 ➝ 0,1 (mol)
a, VH2 = 0,1.22,4= 2,24(l)
b, CM HCl= \(\dfrac{0,2}{0,5}\)= 0,4M
BÀI 7
nAl = 0,1(mol)
nH2SO4= \(\dfrac{200.9,8\%}{100\%.98}\)= 0,2(mol)
2Al + 3H2SO4 ➝ Al2(SO4)3 + 3H2↑
0,07➝ 0,105 ➝ 0,035 (mol)
Vì hiệu suất = 70% => nAl phản ứng= \(\dfrac{70\%}{100\%}\).0,1=0,07(mol)
=> mAl2(SO4)3= 0,035.342= 11,97(g)
a) nCuCl2 = 0,15.2 = 0,3 (mol)
PTHH: 2Al + 3CuCl2 --> 2AlCl3 + 3Cu
____0,2<------0,3--------->0,2---->0,3
=> m = 0,3.64 - 0,2.27 = 13,8 (g)
b) \(C_{M\left(AlCl_3\right)}=\dfrac{0,2}{0,15}=1,3333M\)
a) 2HCl + Ca(OH)2 = CaCl2 + 2H2O
0.2 0.1 0.1 (mol)
b) nCaCl2=11.1:111 = 0.1 (mol)
=>VHCl= 0.2:0.5= 0.4 (l)
=>VCa(OH)2=0.1:2=0.05(l)
c) CM CaCl2=0.1: (0.4+0.05)=0.22M
mình chỉ làm thử thôi nhaa
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