Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
Đáp án B
Fe+2HCl → FeCl2 + H2
a 2a a a
Mg + 2HCl → MgCl2+H2
b 2b b b
mchất rắn X = 56a + 24b ; mddHCl = 36,5/20% .2.(a + b) = 365(a + b)
⇒ mddsau pư = 56a + 24b + 365(a + b) – 2(a + b) = 419a + 387b
.100 = 15,76
Giải PT ⇒ a = b ⇒ .100 = 11,79%
Chọn đáp án B
L ấ y 1 m o l F e : x m o l M g : x - 1 m o l
F e + 2 H C l → F e C l 2 + H 2 ↑ x 2 x x x
M g + 2 H C l → M g C l 2 + H 2 ↑ 1 - x 2 1 - x 1 - x 1 - x
n H 2 = 1 m o l , n H C l = 2 m o l ⇒ m d d H C l = 2 . 36 , 5 . 100 20 = 365 g m d d Y = 56 x + 24 1 - x + 365 - 1 . 2 = 387 + 32 x
C % F e C l 2 = 127 x 387 + 32 x . 100 % = 15 , 76 % ⇒ x = 0 , 5 m o l ⇒ C % M g C l 2 = 95 . 0 , 5 387 + 32 . 0 , 5 . 100 % = 11 , 79 %
a, \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Ta có: \(n_{Fe}=\dfrac{14}{56}=0,25\left(mol\right)\)
Theo PT: \(\left\{{}\begin{matrix}n_{HCl}=2n_{Fe}=0,5\left(mol\right)\\n_{H_2}=n_{Fe}=0,25\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow V_{H_2}=0,25.24,79=6,1975\left(l\right)\)
\(a=C_{M_{HCl}}=\dfrac{0,5}{0,1}=5\left(M\right)\)
b, Theo PT: \(n_{FeCl_2}=n_{Fe}=0,25\left(mol\right)\)
Ta có: \(n_{AgNO_3}=0,4.1,3=0,52\left(mol\right)\)
PT: \(2AgNO_3+FeCl_2\rightarrow Fe\left(NO_3\right)_2+2AgCl_{\downarrow}\)
______0,5______0,25______0,25________0,5 (mol)
\(AgNO_3+Fe\left(NO_3\right)_2\rightarrow Fe\left(NO_3\right)_3+Ag_{\downarrow}\)
0,02______0,02________0,02________0,02 (mol)
⇒ m = mAgCl + mAg = 0,5.143,5 + 0,02.108 = 73,91 (g)
- Dd sau pư gồm: Fe(NO3)3: 0,02 (mol) và Fe(NO3)2: 0,25 - 0,02 = 0,23 (mol)
\(\Rightarrow\left\{{}\begin{matrix}C_{M_{Fe\left(NO_3\right)_3}}=\dfrac{0,02}{0,1+0,4}=0,04\left(M\right)\\C_{M_{Fe\left(NO_3\right)_2}}=\dfrac{0,23}{0,1+0,4}=0,46\left(M\right)\end{matrix}\right.\)
\(Fe+2HCl->FeCl_2+H_2\\ a.V=\dfrac{14}{56}\cdot22,4=5,6\left(L\right)\\ a=\dfrac{\dfrac{14}{56}\cdot2}{0,1}=5\left(M\right)\\ b.n_{AgNO_3}=0,4\cdot1,3=0,52mol\\ FeCl_2+AgNO_3->Fe\left(NO_3\right)_2+AgCl\\ Fe\left(NO_3\right)_2+AgNO_3->Ag+Fe\left(NO_3\right)_3\\ m=0,25\cdot143,5+0,25\cdot108=62,875\left(g\right)\\ C_{M\left(AgNO_3\right)}=\dfrac{0,02}{0,5}=0,04M\\ C_{M\left(Fe\left(NO_3\right)_3\right)}=\dfrac{0,25}{0,5}=0,5M\)
`1)`
`n_{Al}={2,7}/{27}=0,1(mol)`
`2Al+3H_2SO_4->Al_2(SO_4)_3+3H_2`
`0,1->0,15->0,05->0,15(mol)`
`V_{dd\ H_2SO_4}={0,15}/1=0,15(l)=150(ml)`
`->V=150`
`V'=V_{H_2}=0,15.22,4=3,36(l)`
`C_{M\ X}=C_{M\ Al_2(SO_4)_3}={0,05}/{0,15}=1/3M`
`2)`
`n_{Fe}={2,8}/{56}=0,05(mol)`
`Fe+2HCl->FeCl_2+H_2`
`0,05->0,1->0,05->0,05(mol)`
`V_{dd\ HCl}={0,1}/1=0,1(l)=100(ml)`
`->V=100`
`V_{H_2}=0,05.22,4=1,12(l)`
`C_{M\ FeCl_2}={0,05}/{0,1}=0,5M`
18.
Gọi mỗi dd có thể tích là 1l
\(n_{HCl\left(1\right)}=0,1.1=0,1\left(mol\right)\)
\(n_{HCl\left(2\right)}=0,3.1=0,3\left(mol\right)\)
\(n_{HCl\left(3\right)}=0,5.1=0,5\left(mol\right)\)
\(\rightarrow\) nHCl sau pư
\(=0,1+0,3+0,5=0,9\left(mol\right)\)
\(x=\frac{0,9}{3}=0,3M\)
20.
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
Gọi m là m của Mg và Fe
\(\Rightarrow n_{Mg}=\frac{m}{24}\left(mol\right);n_{Fe}=\frac{m}{56}\left(mol\right)\)
Ta có
\(m_{HCl}=\frac{2xm}{24}+\frac{2xm}{56}=\frac{5m}{52}\)
\(\Rightarrow m_{dd_{HCl}}=\frac{5m}{43}.\frac{36,5}{20\%}=\frac{1825m}{84}\left(g\right)\)
mdd spu=2m+1825m/84-2m/24-2m/56=661m/28 g
C%FeCl2=m/56.127:661m/28.100%=9,6%
Giả sử có 365g dung dịch HCl
\(m_{HCl}=365.20\%=73\left(g\right)\)
\(n_{HCl}=\frac{73}{36,5}=2\)
Gọi công thức chung của kim loại là R
\(R+2HCl\rightarrow RCl_2+H_2\)
1____2______1___________
Gọi số mol: \(\left\{{}\begin{matrix}Fe:a\left(mol\right)\\Mg:b\left(mol\right)\end{matrix}\right.\)
\(a+b=1\left(1\right)\)
\(\frac{127a}{56a+24b+365-1.2}=15,76\%\)
\(\Leftrightarrow127a=8,8256+3,7825b+57,2088\)
\(\Rightarrow118,1744-3,7824b=57,2088\left(2\right)\)
\(\left(1\right)+\left(2\right)\Rightarrow\left\{{}\begin{matrix}a=0,5\\b=0,5\end{matrix}\right.\)
\(C\%_{MgCl2}=\frac{0,5.95}{365+56.0,5+24.0,5-1.2}.100\%=11,79\%\)
nH2=6,72/22,4=0,3 mol
Mg + 2HCl \(\rightarrow\) MgCl + H2
a a mol
Fe + 2HCl \(\rightarrow\) FeCl2 +H2
b b mol
ta có 24a + 56b =13,6
và a + b=0,3
=>a=0,1 mol , b=0,2 mol
=>mMg=0,2*24=2,4 g
=>%Mg=2,48100/13,6=17,65%
=>%Fe=100-17,65=82,35%
nMgCl2=nMg=0,1mol=>mMgCl2=0,1*95=9,5 g
nFeCl2=nFe=0,2 mol=>mFeCl2 = 0,2*127=25,4 g
nHCl=nMg+nFe=0,1+0,2=0,3mol
=>CMHCl=0,3/0,4=0,75M
Fe + 2HCl => FeCl2 + H2 (1)
Mg + 2HCl => MgCl2 + H2 (2)
=> Y : FeCl2 , MgCl2
Giả sử nHCl = 1(mol),nFe = a (mol),nMg = b (mol)
=> mdd HCl = \(\frac{1.36,5}{20\%}=182,5\left(g\right)\)
mX = mFe + mMg = 56.a + 24.b (g)
(1),(2) => nH2 = nFe + nMg = a+b (mol)
=> mH2 = 2.(a+b) (g)
(1),(2) => nHCl = 2.(nFe + nMg) = 2.(a+b )(mol)
=> 2.(a+b) = 1 => a+b= 0,5
mY = mX + mdd HCl - mH2
= 56.a+24.b+182,5-2(a+b)
= 32.a+193,5 (g)
%mFeCl2 = 15,76%
=> \(\frac{127.a}{32.a+193,5}.100\%=15,76\%\)
=> a = 0,25
=> b = 0,25
=> mMgCl2 = 0,25.95 = 23,75 (g)
mY = 32.0,25+193,5 = 201,5 (g)
=> %mMgCl2 = \(\frac{23,75}{201,5}.100\%=11,79\%\)