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![](https://rs.olm.vn/images/avt/0.png?1311)
a)
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
0,2-->0,4----->0,2--->0,2
=> VH2 = 0,2.22,4 = 4,48 (l)
b) mHCl = 0,4.36,5 = 14,6 (g)
=> \(m_{dd.HCl}=\dfrac{14,6.100}{7,3}=200\left(g\right)\)
c)
mdd sau pư = 13 + 200 - 0,2.2 = 212,6 (g)
mZnCl2 = 0,2.136 = 27,2 (g)
=> \(C\%=\dfrac{27,2}{212,6}.100\%=12,8\%\)
![](https://rs.olm.vn/images/avt/0.png?1311)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
b, Ta có: \(n_{HCl}=0,5.0,2=0,1\left(mol\right)\)
\(n_{H_2}=\dfrac{0,896}{22,4}=0,04\left(mol\right)\)
Theo PT: \(n_{HCl\left(pư\right)}=2n_{H_2}=0,08\left(mol\right)< 0,1\left(mol\right)\)
→ HCl dư.
Gọi: \(\left\{{}\begin{matrix}n_{Zn}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\)
Theo PT: \(n_{H_2}=n_{Zn}+n_{Fe}=x+y=0,04\left(1\right)\)
\(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=x\left(mol\right)\\n_{FeCl_2}=n_{Fe}=y\left(mol\right)\end{matrix}\right.\)⇒ 136x + 127y = 5,26 (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,02\left(mol\right)\\y=0,02\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,02.65}{0,02.65+0,02.56}.100\%\approx53,72\%\\\%m_{Fe}\approx46,28\%\end{matrix}\right.\)
![](https://rs.olm.vn/images/avt/0.png?1311)
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
c, \(n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow m_{ZnCl_2}=0,2.136=27,2\left(g\right)\)
d, \(n_{HCl}=2n_{Zn}=0,4\left(mol\right)\Rightarrow m_{HCl}=0,4.36,5=14,6\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{14,6}{7,3\%}=200\left(g\right)\)
⇒ m dd sau pư = 13 + 200 - 0,2.2 = 212,6 (g)
\(\Rightarrow C\%_{ZnCl_2}=\dfrac{27,2}{212,6}.100\%\approx12,79\%\)
![](https://rs.olm.vn/images/avt/0.png?1311)
Gọi \(\left\{{}\begin{matrix}n_{Al}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
Theo pt: \(\Rightarrow\left\{{}\begin{matrix}3x+y=0,2\\27x+56y=5,5\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=\dfrac{19}{470}\\y=\dfrac{37}{470}\end{matrix}\right.\)
\(\%m_{Al}=\dfrac{\dfrac{19}{470}\cdot27}{5,5}\cdot100\%=19,84\%\)
\(\%m_{Fe}=100\%-19,84\%=80,16\%\)
![](https://rs.olm.vn/images/avt/0.png?1311)
Gọi số mol H2O sinh ra là a (mol)
=> \(n_{H_2SO_4}=a\left(mol\right)\)
Theo ĐLBTKL: moxit + mH2SO4 = mmuối + mH2O
=> 16,6 + 98a = 24,6 + 18a
=> a = 0,1 (mol)
=> nO = 0,1 (mol)
=> mkim loại = 16,6 - 0,1.16 = 15 (g)
\(m_{H_2SO_4}=0,1.98=9,8\left(g\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
Fe + 2 HCl -> FeCl2+ H2
x____2x____x_____x(mol)
Zn +2 HCl -> ZnCl2 + H2
y____2y____y______y(mol)
Ta có: nHCl(tổng)= 0,2 (mol)
<=> 2x+2y=0,2 (1)
Mặt khác: m(muối)= 10,52(g)
<=> 127x+ 136y=10,52 (2)
Từ (1), (2) ta có hpt: \(\left\{{}\begin{matrix}2x+2y=0,2\\127x+136y=10,52\end{matrix}\right.\)
Bấm ra có nghiệm âm??
a) Gọi n Zn = a(mol) ; n ZnO = b(mol)
=> 65a + 81b = 14,6(1)
$Zn + 2HCl \to ZnCl_2 + H_2$
$ZnO + 2HCl \to ZnCl_2 + H_2O$
n ZnCl2 = a + b = 27,2/136 = 0,2(2)
Từ (1)(2) suy ra : a = b = 0,1
%m Zn = 0,1.65/14,6 .100% = 44,52%
%m ZnO = 100% -44,52% = 55,45%
b)
n HCl = 2n Zn + 2n ZnO = 0,4(mol)
m dd HCl = 0,4.36,5/7,3% = 200(gam)