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a, \(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)
\(m_{HCl}=200.14,6\%=29,2\left(g\right)\Rightarrow n_{HCl}=\dfrac{29,2}{36,5}=0,8\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Xét tỉ lệ: \(\dfrac{0,3}{1}< \dfrac{0,8}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,3\left(mol\right)\Rightarrow V_{H_2}=0,3.22,4=6,72\left(l\right)\)
b, \(n_{ZnCl_2}=n_{Zn}=0,3\left(mol\right)\Rightarrow m_{ZnCl_2}=0,3.136=40,8\left(g\right)\)
c, \(n_{HCl\left(pư\right)}=2n_{Zn}=0,6\left(mol\right)\Rightarrow n_{HCl\left(dư\right)}=0,2\left(mol\right)\)
Ta có: m dd sau pư = 19,5 + 200 - 0,3.2 = 218,9 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{HCl}=\dfrac{0,2.36,5}{218,9}.100\%\approx3,33\%\\C\%_{ZnCl_2}=\dfrac{40,8}{218,9}.100\%\approx18,64\%\end{matrix}\right.\)
\(a)n_{Zn}=\dfrac{19,5}{65}=0,3mol\\ n_{HCl}=\dfrac{200.14,6}{100.36,5}=0,8mol\\ Zn+2HCl\rightarrow ZnCl_2+H_2\\ \Rightarrow\dfrac{0,3}{1}< \dfrac{0,8}{2}\Rightarrow HCl.dư\\ n_{H_2}=n_{ZnCl_2}=n_{Zn}=0,3mol\\ V_{H_2}=0,3.22,4=6,72l\\ b)m_{ZnCl_2}=0,3.136=40,8g\\ c)n_{HCl.pư}=0,3.2=0,6mol\\ C_{\%ZnCl_2}=\dfrac{40,8}{200+19,5-0,3.2}\cdot100=18,64\%\\ C_{\%HCl.dư}=\dfrac{\left(0,8-0,6\right).36,5}{200+19,5-0,3.2}\cdot100=3,33\%\)
a, \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Theo PT: \(n_{H_2}=n_{FeCl_2}=n_{Fe}=0,2\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
b, \(m_{FeCl_2}=0,2.127=25,4\left(g\right)\)
c, \(n_{HCl}=2n_{H_2}=0,4\left(mol\right)\Rightarrow C_{M_{HCl}}=\dfrac{0,4}{0,3}=\dfrac{4}{3}\left(M\right)\)
\(C_{M_{FeCl_2}}=\dfrac{0,2}{0,3}=\dfrac{2}{3}\left(M\right)\)
a. \(m_{Al.pứ}=15-9,6=5,4\left(g\right)\)
b. \(\left\{{}\begin{matrix}\%m_{Al}=\dfrac{5,4.100\%}{15}=36\%\\\%m_{Cu}=\dfrac{9,6.100\%}{15}=64\%\end{matrix}\right.\)
c. \(n_{H_2}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}.\dfrac{5,4}{27}=0,3\left(mol\right)\Rightarrow V_{H_2\left(đkc\right)}=0,3.24,79=7,437\left(l\right)\)
d. \(\%m_{AlCl_3}=\dfrac{0,2.133,5.100\%}{15+200-9,6}=13\%\)
a) Bảo toàn nguyên tố H : \(n_{HCl}.1=2n_{H_2}=0,6\left(mol\right)\)
=> nH2=0,3(mol)
=> \(V_{H_2}=0,3.22,4=6,72\left(l\right)\)
b) Áp dụng định luật bảo toàn khối lượng :
\(m_{ct}=m_{kl}+m_{HCl}-m_{H_2}=10,4+0,6.36,5-0,3.2=31,7\left(g\right)\)
Sửa đề: Sau phản ứng thu đc \(2240(cm^3)\) lít khí (đktc)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1(mol)\\ a,PTHH:Zn+2HCl\to ZnCl_2+H_2\\ ZnO+2HCl\to ZnCl_2+H_2O\\ b,n_{Zn}=n_{H_2}=0,1(mol)\\ \Rightarrow m_{Zn}=0,1.65=6,5(g)\\ \Rightarrow \%_{Zn}=\dfrac{6,5}{14,6}.100\%= 44,52\%\\ \Rightarrow \%_{ZnO}=100\%-44,52\%=55,48\%\\ n_{ZnO}=\dfrac{14,6-6,5}{81}=0,1(mol)\\ \Sigma n_{ZnCl_2}=n_{Zn}+n_{ZnO}=0,1+0,1=0,2(mol)\\ \Rightarrow C_{M_{ZnCl_2}}=\dfrac{0,2}{0,2}=1M\)
\(a/\\3Al+2H_2SO_4 \to Al_2(SO_4)_3+3H_2\\ Zn+H_2SO_4 \to ZnSO_4+H_2\\ n_{H_2SO_4}=\frac{400.9.8\%}{98}=0,4(mol)\\ n_{Al}=a(mol)\\ n_{Zn}=b(mol) m_{hh}=27a+65b=11,9(1)\\ n_{H_2SO_4}=1,5a+b=0,4(mol)\\ (1)(2)\\ a=0,2; b=0,1\\ b/\\ \%m_{Al}=\frac{0,2.27}{11,9}.100=45,38\%\\ \%m_{Zn}=54,62\% \)
PTHH: \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
Ta có; \(n_{CaCO_3}=\dfrac{3}{100}=0,03\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,06\left(mol\right)\\n_{CO_2}=0,03\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{ddHCl}=\dfrac{0,06\cdot36,5}{10\%}=21,9\left(g\right)\\V_{CO_2}=0,03\cdot22,4=0,672\left(l\right)\end{matrix}\right.\)
a)
$n_{Al} = 0,3(mol)$
$2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$
Theo PTHH :
$n_{H_2SO_4} = \dfrac{3}{2}n_{Al} = 0,45(mol)$
$m_{dd\ H_2SO_4} = \dfrac{0,45.98}{12,25\%} = 360(gam)$
b)
$n_{H_2} = n_{H_2SO_4} = 0,45(mol)$
$V_{H_2} = 0,45.22,4 = 10,08(lít)$
c)
$n_{Al_2(SO_4)_3} = 0,15(mol)$
$m_{dd\ sau\ pư} = 8,1 + 360 - 0,45.2 = 367,2(gam)$
$C\%_{Al_2(SO_4)_3} = \dfrac{0,15.342}{367,2}.100\% = 14\%$
a) \(n_{HCl}=0,5.1,6=0,8\left(mol\right)\)
PTHH: Zn + 2HCl → ZnCl2 + H2
Mol: x 2x x x
PTHH: 2Al + 6HCl → 2AlCl3 + 3H2
Mol: y 3y y 1,5y
Ta có: \(\left\{{}\begin{matrix}65x+27y=11,9\\2x+3y=0,8\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)
\(\Rightarrow V_{H_2}=\left(0,1+1,5.0,2\right).22,4=8,96\left(l\right)\)
b, \(m_{muối}=0,1.136+0,2.133,5=40,3\left(g\right)\)