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a, Ta có: 27nAl + 56nFe = 22 (1)
PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}+n_{Fe}=\dfrac{19,832}{24,79}=0,8\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}m_{Al}=0,4\left(mol\right)\\n_{Fe}=0,2\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,4.27}{22}.100\%\approx49,09\%\\\%m_{Fe}\approx50,91\%\end{matrix}\right.\)
b, \(n_{HCl}=2n_{H_2}=1,6\left(mol\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{1,6}{0,5}=3,2\left(M\right)\)
a) Gọi $n_{Al} =a (mol) ; n_{Fe} = b(mol) \Rightarrow 27a + 56b = 13(1)$
$2Al + 6HCl \to 2AlCl_3 + 3H_2$
$Fe + 2HCl \to FeCl_2 + H_2$
Theo PTHH : $n_{H_2} = 1,5a + b = \dfrac{6,72}{22,4} = 0,3(2)$
Từ (1)(2) suy ra : $a = \dfrac{1}{15} ; b = 0,2$
$\%m_{Al} = \dfrac{ \dfrac{1}{15}.27}{13}.100\% = 13,8\%$
$\%m_{Fe} = 100\% - 13,8\% = 86,2\%$
b) $n_{HCl} = 2n_{H_2} = 0,3.2 = 0,6(mol)$
$\Rightarrow C_{M_{HCl}} = \dfrac{0,6}{0,15} = 4M$
c) $n_{muối} = m_{kim\ loại} + m_{HCl} - m_{H_2} = 13 + 0,6.36,5 - 0,3.2 = 34,3(gam)$
a, Ta có: 27nAl + 56nFe = 27,8 (1)
PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}+n_{Fe}=\dfrac{17,353}{24,79}=0,7\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Al}=0,2\left(mol\right)\\n_{Fe}=0,4\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,2.27}{27,8}.100\%\approx19,42\%\\\%m_{Fe}\approx80,58\%\end{matrix}\right.\)
b, \(n_{H_2SO_4}=n_{H_2}=0,7\left(mol\right)\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,7}{0,5}=1,4\left(M\right)\)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
\(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)
a) Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)=n_{Fe}\)
\(\Rightarrow m_{Fe}=0,2\cdot56=11,2\left(g\right)\) \(\Rightarrow m_{Fe_2O_3}=16\left(g\right)\)
b+c) Ta có: \(\left\{{}\begin{matrix}n_{Fe}=0,2\left(mol\right)\\n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{HCl}=2n_{Fe}+6n_{Fe_2O_3}=1\left(mol\right)\) \(\Rightarrow m_{ddHCl}=\dfrac{36,5}{20\%}=182,5\left(g\right)\)
Mặt khác: \(n_{FeCl_2}=0,2\left(mol\right)=n_{H_2}=n_{FeCl_3}\) \(\Rightarrow\left\{{}\begin{matrix}m_{FeCl_2}=0,2\cdot127=25,4\left(g\right)\\m_{FeCl_3}=0,2\cdot162,5=32,5\left(g\right)\\m_{H_2}=0,2\cdot2=0,4\left(g\right)\end{matrix}\right.\)
\(\Rightarrow m_{dd}=m_{hhA}+m_{ddHCl}-m_{H_2}=209,3\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{FeCl_2}=\dfrac{25,4}{209,3}\cdot100\%\approx12,14\%\\C\%_{FeCl_3}=\dfrac{32,5}{209,3}\cdot100\%\approx15,53\%\end{matrix}\right.\)
\(n_{H2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Pt : \(Fe+2HCl\rightarrow FeCl_2+H_2|\)
1 2 1 1
0,2 0,4 0,2 0,2
\(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O|\)
1 6 2 3
0,1 0,6 0,2
a) \(n_{Fe}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
\(m_{Fe}=0,2.56=11,2\left(g\right)\)
\(m_{Fe2O3}=27,2-11,2=16\left(g\right)\)
b) Có : \(m_{Fe2O3}=16\left(g\right)\)
\(n_{Fe2O3}=\dfrac{16}{160}=0,1\left(mol\right)\)
\(n_{HCl\left(tổng\right)}=0,4+0,6=1\left(mol\right)\)
⇒ \(m_{HCl}=1.36,5=36,5\left(g\right)\)
\(m_{ddHCl}=\dfrac{36,5.100}{20}=182,5\left(g\right)\)
c) \(n_{FeCl2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
⇒ \(m_{FeCl2}=0,2.127=25,4\left(g\right)\)
\(n_{FeCl3}=\dfrac{0,6.2}{6}=0,2\left(mol\right)\)
⇒ \(m_{FeCl3}=0,2.162,5=32,5\left(g\right)\)
\(m_{ddspu}=27,2+182,5-\left(0,2.2\right)=209,3\left(g\right)\)
\(C_{FeCl2}=\dfrac{25,4.100}{209,3}=12,14\)0/0
\(C_{FeCl3}=\dfrac{32,5.100}{209,3}=15,53\)0/0
Chúc bạn học tốt
a) PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
x_____2x_____________x (mol)
\(Al_2\left(CO_3\right)_3+6HCl\rightarrow2AlCl_3+3H_2O+3CO_2\uparrow\)
y_____6y______________________3y (mol)
Ta lập HPT: \(\left\{{}\begin{matrix}56x+234y=29\\x+3y=\dfrac{8,96}{22,4}=0,4\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=56\cdot0,1=5,6\left(g\right)\\m_{Al_2\left(CO_3\right)_3}=23,4\left(g\right)\end{matrix}\right.\)
b) Theo PTHH: \(n_{HCl}=2n_{Fe}+6n_{Al_2\left(CO_3\right)_3}=0,8\left(mol\right)\) \(\Rightarrow V_{ddHCl}=\dfrac{0,8}{2}=0,4\left(l\right)=400\left(ml\right)\)
c) Kết tủa sau phản ứng không có Al(OH)3
Bảo toàn Sắt: \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe}=0,05\left(mol\right)\) \(\Rightarrow m_{Fe_2O_3}=0,05\cdot160=8\left(g\right)\)
a.Fe + 2HCl -> FeCl2 + H2
0.2 0.4 0.2 0.2
FeO + 2HCl -> FeCl2 + H2O
0.1 0.2 0.1
b.nH2 = 0.2 mol
mFe = \(0.2\times56=11.2g\) => \(\%mFe=\dfrac{11.2\times100}{18.4}=60.9\%\)
c.mFeO = 18.4 - 11.2 = 7.2g => nFeO = 0.1mol
mdd sau phản ứng: mFe + mFeO + mHCl - mH2
= 18.4 + 300 - 0.2\(\times2=318g\)
\(C\%FeCl2=\dfrac{0.3\times127\times100}{318}=11.98\%\)