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\(n_{Mg}=a;n_{Fe}=0,5a;n_{Zn}=b\\ a\left(24+28\right)+65b=52a+65b=44,2\\ 1,5a+b=\dfrac{24,64}{22,4}1,1\\ a=0,6;b=0,2\\ \%m_{Mg}=\dfrac{24a}{44,2}=32,58\%\\ \%m_{Fe}=\dfrac{28a}{44,2}=38\%\\ \%m_{Zn}=29,42\%\\ m_{ddacid}=\dfrac{98\left(1,5a+b\right)}{0,08}=1347,5g\\ m_{ddsau}=1389,5g\\ C\%_{MgCl_2}=\dfrac{95a}{1389,5}=4,10\%\\ C\%_{FeCl_2}=\dfrac{127.0,5a}{1389,5}=2,74\%\\ C\%_{ZnCl_2}=\dfrac{136b}{1389,5}=1,96\%\)
\(a,n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\\ PTHH:Mg+H_2SO_4\rightarrow MgSO_4+H_2\uparrow\left(1\right)\\ Theo.pt\left(1\right):n_{H_2}=n_{MgSO_4}=n_{Mg}=0,1\left(mol\right)\\ V_{H_2}=0,1.22,4=2,24\left(l\right)\\ m_{MgSO_4}=0,1.120=12\left(g\right)\\ b,PTHH:CuO+H_2\underrightarrow{t^o}Cu+H_2O\left(2\right)\\ Theo.pt\left(2\right):n_{Cu}=n_{H_2}=0,1\left(mol\right)\\ m_{Cu}=0,1.64=6,4\left(g\right)\)
1:
a) \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)
______0,2------>0,2------------------->0,2_____(mol)
=> \(V_{H_2}=0,2.22,4=4,48\left(l\right)\)
b) \(V_{ddH_2SO_4}=\dfrac{0,2}{1}=0,2\left(l\right)\)
2:
a)
\(n_{HCl}=2.0,2=0,4\left(mol\right)\)
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
______0,2<------0,4------------------>0,2______(mol)
=> \(m_{Mg}=0,2.24=4,8\left(g\right)\)
b) \(V_{H_2}=0,2.22,4=4,48\left(l\right)\)
\(\left\{{}\begin{matrix}Zn\\Fe\\Mg\end{matrix}\right.+H_2SO_4\rightarrow\left\{{}\begin{matrix}ZnSO_4\\FeSO_4\\MgSO_4\end{matrix}\right.+H_2\uparrow\)
Ta có: \(m_{SO_4}=8,25-2,49=5,76\left(g\right)\)
\(\Rightarrow n_{H_2SO_4}=n_{H_2}=n_{SO_4}=\dfrac{5,76}{96}=0,06\left(mol\right)\)
a, \(m_{H_2SO_4}=0,06.98=5,88\left(g\right)\)
b, \(V_{H_2}=0,06.22,4=1,344\)
Gọi \(n_{H_2\left(Mg\right)}=a\left(mol\right)\rightarrow n_{H_2\left(Al\right)}=2a\left(mol\right)\)
PTHH:
2Al + 3H2SO4 ---> Al2(SO4)3 + 3H2
\(\dfrac{4a}{3}\) 2a
Mg + H2SO4 ---> MgSO4 + H2
a a
\(m_{Al}=\dfrac{4a}{3}.27=36a\left(g\right)\\ \rightarrow V_{Mg}=V_{Al}=\dfrac{36a}{2,7}=\dfrac{40a}{3}\left(cm^3\right)\)
\(m_{Mg}=24a\left(g\right)\\ \rightarrow D_{Mg}=\dfrac{24a}{\dfrac{40}{3}}=1,8\left(\dfrac{g}{cm^3}\right)\)
Giả sử có 1 mol khí ở 0oC, 2atm
Theo phương trình trạng thái khí lý tưởng:
\(P.V=n.R.T\)
=> \(V=\dfrac{n.R.T}{P}=\dfrac{1.0,082.273}{2}\approx11,2\left(l\right)\)
=> 1 mol khí chiếm thể tích 11,2 lít ở 0oC, 2atm nhé :)
\(n_{H_2}=\dfrac{P.V}{R.T}=\dfrac{2.6,72}{0,082.\left(0+273\right)}=0,6\left(mol\right)\\ n_{H_2SO_4}=n_{H_2}=n_{SO^{2-}_4}=0,6\left(mol\right)\\ \Rightarrow m_{muối}=m_{hhkimloai}+m_{SO^{2-}_4}=21+96.0,6=78,6\left(g\right)\\ V_{ddH_2SO_4}=\dfrac{0,6}{0,5}=1,2\left(l\right)\)
Em ơi Mg, Al nó là kim loại thì cho 3 lít hơi vô lí , thường sẽ cho khối lượng í
a)
\(n_{H_2} = \dfrac{3,36}{22,4} = 0,15(mol)\\ n_{Mg} = a\ mol; n_{Fe} = b\ mol\\ Mg + 2HCl \to MgCl_2 + H_2\\ Fe + 2HCl \to FeCl_2 + H_2 \)
Theo PTHH, ta có:
\(\left\{{}\begin{matrix}24a+56b=5,2\\a+b=0,15\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}a=0,1\\b=0,05\end{matrix}\right.\)
Suy ra:
\(\%m_{Mg} = \dfrac{0,1.24}{5,2}.100\% = 46,15\%\\ \%m_{Fe} = 100\% - 46,15\% = 53,85\% \)
b)
\(n_{HCl} = 2n_{H_2} = 0,15.2 = 0,3(mol)\\ \Rightarrow V_{dd\ HCl} = \dfrac{0,3}{1} = 0,3(lít) \)
Đặt :
nMg = a mol
nFe= b mol
mhh = 24a + 56b = 5.2 (g) (1)
Mg + 2HCl => MgCl2 + H2
Fe + 2HCl => FeCl2 + H2
nH2 = a + b = 0.15 (2)
(1) , (2)
a = 0.1
b = 0.05
%Mg = 2.4/5.2 * 100% = 46.15%
%Fe = 100 - 46.15 = 53.85%
nHCl = 2a + 2b = 0.05 * 2 + 0.1*2 = 0.3 (mol)
VddHCl = 0.3/1=0.3 (l)
mMg = 8,9 . 26,96% = 2,4 (g)
nMg = 2,4/24 = 0,1 (mol)
mZn = 8,9 - 2,4 = 6,5 (g)
nZn = 6,5/65 = 0,1 (mol)
PTHH:
Mg + H2SO4 -> MgSO4 + H2
Mol: 0,1 ---> 0,1 ---> 0,1 ---> 0,1
Zn + H2SO4 -> ZnSO4 + H2
Mol: 0,1 ---> 0,1 ---> 0,1 ---> 0,1
VH2 = (0,1 + 0,1) . 90% . 22,4 = 4,032 (l)
nH2SO4 = (0,1 + 0,1) . 90% = 0,18 (mol)
VddH2SO4 = 0,18/0,2 = 0,9 (l) = 900 (ml)
mMg = 8,9 . (26,9663/100) = 2,4 g
nMg =2,4/24 = 0,1 mol
n Zn = ( 8,9 -2,4)/65 = 0,1 mol
Mg + H2S04 --> MgS04 + H2
0,1 ---------------------------------> 0,1
Zn + H2S04 ----> ZnS04 + H2 0,1 ----------------------------------> 0,1
VH2 = 22,4 . 0,2 . 0,9 = 4,032 lít