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a) Fe + H2SO4 -----------> FeSO4 + H2
\(n_{Fe}=n_{H_2}=0,75\left(mol\right)\)
=> \(m_{Fe}=0,75.56=42\left(g\right)\)
b) \(CM_{H_2SO_4}=\dfrac{0,75}{0,25}=3M\)
c) \(m_{ddsaupu}=42+250.1,1-0,75.2=315,5\left(g\right)\)
=> \(C\%_{FeSO_4}=\dfrac{0,75.152}{315,5}.100=36,13\%\)
\(n_{SO_2}=\dfrac{16,8}{22,4}=0,75\left(mol\right)\)
\(PTHH:2Fe+6H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3SO_2+6H_2O\)
Mol: 0,5 1,5 0,25 0,75 1,5
a)mFe=0,5.56=28 (g)
b)\(C_{MddH_2SO_4}=\dfrac{1,5}{0,25}=6\left(mol/l\right)\)
c)\(m_{Fe_2\left(SO_4\right)_3}=0,25.400=100\left(g\right)\)
\(m_{H_2O}=1,5.18=27\left(g\right)\)
\(C\%_{ddFe_2\left(SO_4\right)_3}=\dfrac{100.100}{100+27}=78,74\%\)
a, PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(FeO+2HCl\rightarrow FeCl_2+H_2O\)
b, Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,2\left(mol\right)\)
\(\Rightarrow m_{Al}=0,2.27=5,4\left(g\right)\)
⇒ mFeO = 12,6 - 5,4 = 7,2 (g)
c, Phần này đề cho dd NaOH dư hay vừa đủ bạn nhỉ?
d, Cho hh vào dd H2SO4 đặc nguội thì có khí thoát ra.
PT: \(2FeO+4H_2SO_{4\left(đ\right)}\rightarrow Fe_2\left(SO_4\right)_3+SO_2+4H_2O\)
Ta có: \(n_{FeO}=\dfrac{7,2}{72}=0,1\left(mol\right)\)
Theo PT: \(n_{SO_2}=\dfrac{1}{2}n_{FeO}=0,05\left(mol\right)\)
\(\Rightarrow V_{SO_2}=0,05.22,4=1,12\left(l\right)\)
\(n_{Zn}=\dfrac{4,55}{65}=0,07(mol)\\ Zn+2HCl\to ZnCl_2+H_2\\ a,n_{HCl}=0,14(mol)\\ \Rightarrow C_{M_{HCl}}=\dfrac{0,14}{0,2}=0,7M\\ b,n_{H_2}=0,07(mol)\\ \Rightarrow V_{H_2}=0,07.22,4=1,568(l)\\ c,n_{ZnCl_2}=0,07(mol)\\ \Rightarrow m_{ZnCl_2}=0,07.136=9,52(g)\\ c,ZnCl_2+2AgNO_3\to 2AgCl\downarrow+Zn(NO_3)_2\)
\(m_{dd_{ZnCl_2}}=200.0,8+4,55-0,07.2=164,41(g)\\ n_{AgCl}=0,14(mol);n_{Zn(NO_3)_2}=0,07(mol)\\ \Rightarrow C\%_{Zn(NO_3)_2}=\dfrac{0,07.189}{164,41+200-0,14.143,5}.100\%=3,84%\)
\(PTHH:4Al+6HCl\rightarrow2Al_2Cl_3+3H_2\uparrow\)
\(n_{Al}=\frac{3,78}{27}=0,14\left(mol\right)\)
\(\Rightarrow n_{H_2}=\frac{3}{4}n_{Al}=0,105\left(mol\right)\)
\(V_{H_2}=0,105.22,4=2,352\left(l\right)\)
\(n_{HCl}=\frac{3}{2}n_{Al}=\frac{3}{2}.0,14=0,21\left(mol\right)\)
\(C_{M_{ddHCl}}=\frac{0,21}{0,2}=1,05\left(M\right)\)
\(n_{Al_2Cl_3}=\frac{1}{2}n_{Al}=\frac{1}{2}.0,14=0,07\left(mol\right)\)
\(m_{Al_2Cl_3}=0,07.160,5=11,235\left(g\right)\)
a) mCuO= 3,2/80= 0,04(mol)
mH2SO4= 40%.100=40(g)
=>nH2SO4=40/98=20/49(mol)
PTHH: CuO + H2SO4 -> CuSO4 + H2O
Ta có: 0,04/1 < 20/49:1
=> H2SO4 dư, CuO hết -> Tính theo nCuO
=> nH2SO4(P.Ứ)=nCuSO4=nCuO=0,04(mol)
=>mH2SO4(p.ứ)=0,04.98=3,92(g)
b) mCuSO4=0,04.160=6,4(g)
c) mH2SO4(dư)= 40 - 3,92= 36,08(g)
mddsau= 3,2+100=103,2(g)
=>C%ddH2SO4(dư sau p.ứ)= (36,08/103,2).100=34,961%
PTHH: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
a) Ta có: \(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)=n_{Fe}\)
\(\Rightarrow m_{Fe}=0,25\cdot56=14\left(g\right)\) \(\Rightarrow m_{Cu}=6\left(g\right)\)
b) Theo PTHH: \(n_{FeSO_4}=0,25mol\) \(\Rightarrow m_{FeSO_4}=0,25\cdot152=38\left(g\right)\)
Mặt khác: \(\left\{{}\begin{matrix}m_{ddH_2SO_4}=\dfrac{0,25\cdot98}{10\%}=245\left(g\right)\\m_{H_2}=0,25\cdot2=0,5\left(g\right)\end{matrix}\right.\)
\(\Rightarrow m_{dd}=m_{hh}+m_{H_2SO_4}-m_{Cu}-m_{H_2}=258,5\left(g\right)\)
\(\Rightarrow C\%_{FeSO_4}=\dfrac{38}{258,5}\cdot100\%\approx14,7\%\)
pthh : Fe +H2SO4 → FeSO4 +H2
theo bài ra số mol của h2 =0,15 (mol)
theo pt : nFe=nH2=0,15 (mol)
mFe=0,15 .56 =8,4 (g) ⇒mCu=20-8,4=11,6 (g)
a, \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
b, Ta có: \(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=\dfrac{4}{15}\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{\dfrac{4}{15}.27}{10}.100\%=72\%\\\%m_{Cu}=28\%\end{matrix}\right.\)
c, Theo PT: \(n_{H_2SO_4}=n_{H_2}=0,4\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}=0,4.98=39,2\left(g\right)\)
\(\Rightarrow C\%_{H_2SO_4}=\dfrac{39,2}{300}.100\%\approx13,067\%\)
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