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a) PTHH: \(K_2O+H_2O\rightarrow2KOH\)
Ta có: \(n_{KOH}=2n_{K_2O}=2\cdot\dfrac{35,25}{94}=0,75\left(mol\right)\)
\(\Rightarrow C_{M_{KOH}}=\dfrac{0,75}{0,75}=1\left(M\right)\)
b) Ta có: \(\left\{{}\begin{matrix}n_{KOH}=0,75\left(mol\right)\\n_{CO_2}=\dfrac{8,4}{22,4}=0,375\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Tạo muối trung hòa
PTHH: \(CO_2+2KOH\rightarrow K_2CO_3+H_2O\)
Theo PTHH: \(n_{K_2CO_3}=0,375\left(mol\right)\) \(\Rightarrow m_{K_2CO_3}=0,375\cdot138=51,75\left(g\right)\)
c) PTHH: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
Theo PTHH: \(n_{H_2SO_4}=0,375\left(mol\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,375\cdot98}{60\%}=61,25\left(g\right)\) \(\Rightarrow V_{ddH_2SO_4}=\dfrac{61,25}{1,5}\approx40,83\left(ml\right)\)
\(n_{K2O}=\dfrac{9,4}{94}=0,1\left(mol\right)\)
Pt : \(K_2O+H_2O\rightarrow2KOH|\)
1 1 2
0,1 0,2
a) \(n_{KOH}=\dfrac{0,1.2}{1}=0,2\left(mol\right)\)
200ml = 0,2l
\(C_{M_{ddKOH}}=\dfrac{0,2}{0,2}=1\left(M\right)\)
b) Pt : \(KOH+HCl\rightarrow KCl+H_2O|\)
1 1 1 1
0,1 0,1
\(n_{HCl}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(m_{HCl}=0,1.36,5=3,65\left(g\right)\)
\(m_{ddHCl}=\dfrac{3,65.100}{10}=36,5\left(g\right)\)
c) \(CO_2+2KOH\rightarrow K_2CO_3+H_2O|\)
1 2 1 1
0,05 0,1
\(n_{CO2}=\dfrac{0,1.1}{2}=0,05\left(mol\right)\)
\(V_{CO2\left(dktc\right)}=0,05.22,4=1,12\left(l\right)\)
Chúc bạn học tốt
a) \(n_{CO_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: CO2 + 2NaOH → Na2CO3 + H2O
Mol: 0,15 0,3 0,15
\(C_{M_{ddNaOH}}=\dfrac{0,3}{0,2}=1,5M\)
b) Na2CO3: natri cacbonat
\(m_{Na_2CO_3}=0,15.106=15,9\left(g\right)\)
c)
PTHH: 2NaOH + H2SO4 → Na2SO4 + 2H2O
Mol: 0,15 0,075
\(V_{ddH_2SO_4}=\dfrac{0,075}{1}=0,075\left(l\right)=75\left(ml\right)\)
\(a,MgCO_3\rightarrow\left(t^o\right)MgO+CO_2\\ Na_2O+H_2O\rightarrow2NaOH\\ CO_2+2NaOH\rightarrow Na_2CO_3+H_2O\\ n_{CO_2}=n_{MgO}=n_{MgCO_3}=\dfrac{84}{84}=1\left(mol\right);n_{NaOH}=2.n_{Na_2O}=2.\dfrac{4,65}{62}=0,15\left(mol\right)\\ Vì:\dfrac{0,15}{2}>\dfrac{1}{1}\Rightarrow CO_2dư\\ n_{Na_2CO_3}=\dfrac{0,15}{2}=0,075\left(mol\right)\Rightarrow m_{Na_2CO_3}=106.0,075=7,95\left(g\right)\\ m_{CO_2\left(dư\right)}=\left(1-\dfrac{0,15}{2}\right).44=40,7\left(g\right)\\ m_{MgO}=40.1=40\left(g\right)\\ b,n_{CO_2}=0,1\left(mol\right)\\ Có:1< \dfrac{0,15}{0,1}=1,5< 2\\ \Rightarrow SP:n_{Na_2CO_3}=n_{NaHCO_3}=\dfrac{0,1}{2}=0,05\left(mol\right)\\ m_{muối}=0,05.\left(106+84\right)=9,5\left(g\right)\)
\(n_{H_2SO_4}=\dfrac{400.24,5\%}{98}=1\left(mol\right)\)
2l dung dịch A có 1 mol H2SO4
=> 400ml dung dịch A có \(\dfrac{400.1}{2000}=0,2\)mol H2SO4
\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)
0,2..............0,4
Ta có : \(n_{NaOH}=2n_{H_2SO_4}\)
=> \(V_{NaOH}=\dfrac{0,4}{3,2}=0,125\left(l\right)=125ml\)
a) Fe + H2SO4 -----------> FeSO4 + H2
\(n_{Fe}=n_{H_2}=0,75\left(mol\right)\)
=> \(m_{Fe}=0,75.56=42\left(g\right)\)
b) \(CM_{H_2SO_4}=\dfrac{0,75}{0,25}=3M\)
c) \(m_{ddsaupu}=42+250.1,1-0,75.2=315,5\left(g\right)\)
=> \(C\%_{FeSO_4}=\dfrac{0,75.152}{315,5}.100=36,13\%\)
\(n_{SO_2}=\dfrac{16,8}{22,4}=0,75\left(mol\right)\)
\(PTHH:2Fe+6H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3SO_2+6H_2O\)
Mol: 0,5 1,5 0,25 0,75 1,5
a)mFe=0,5.56=28 (g)
b)\(C_{MddH_2SO_4}=\dfrac{1,5}{0,25}=6\left(mol/l\right)\)
c)\(m_{Fe_2\left(SO_4\right)_3}=0,25.400=100\left(g\right)\)
\(m_{H_2O}=1,5.18=27\left(g\right)\)
\(C\%_{ddFe_2\left(SO_4\right)_3}=\dfrac{100.100}{100+27}=78,74\%\)