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a) $n_{H_2SO_4} = \dfrac{44,1}{98} = 0,45(mol)$
$2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$
Theo PTHH :
$n_{Al} = \dfrac{2}{3}n_{H_2SO_4} = 0,3(mol)$
$m_{Al} = 0,3.27 = 8,1(gam)$
b) $n_{H_2} = n_{H_2SO_4} = 0,45(mol)$
$\Rightarrow V_{H_2} = 0,45.22,4 =1 0,08(lít)$
c)
Cách 1 : $n_{Al_2(SO_4)_3} = \dfrac{1}{3}n_{H_2SO_4} = 0,15(mol)$
$\Rightarrow m_{Al_2(SO_4)_3} = 0,15.342 = 51,3(gam)$
Cách 2 : Bảo toàn khối lượng, $m_{Al_2(SO_4)_3} = 8,1 + 44,1 - 0,45.2 = 51,3(gam)$
a) Fe + 2HCl --> FeCl2 + H2
b) \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
_____0,1--------------->0,1---->0,1
=> mFeCl2 = 0,1.127 = 12,7(g)
c) VH2 = 0,1.22,4 = 2,24(l)
\(n_{Fe}=\dfrac{5,6}{56}=0,1(mol)\\ a,Fe+2HCl\to FeCl_2+H_2\\ \Rightarrow n_{FeCl_2}=n_{H_2}=0,1(mol)\\ a,m_{FeCl_2}=0,1.127=12,7(g)\\ b,V_{H_2}=0,1.22,4=2,24(l)\)
a, Gọi \(\left\{{}\begin{matrix}n_{Fe}=a\left(mol\right)\\n_{Al}=b\left(mol\right)\end{matrix}\right.\)
\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH:
Fe + 2HCl ---> FeCl2 + H2
a--->2a------------------>a
2Al + 6HCl ---> 2AlCl3 + 3H2
b---->3b-------------------->1,5b
=> \(\left\{{}\begin{matrix}56a+27b=16,6\\a+1,5b=0,5\end{matrix}\right.\Leftrightarrow a=b=0,2\left(mol\right)\)
=> \(\left\{{}\begin{matrix}m_{Fe}=0,2.56=11,2\left(g\right)\\m_{Al}=0,2.27=5,4\left(g\right)\end{matrix}\right.\)
b) \(C\%_{HCl}=\dfrac{\left(0,2.2+0,2.3\right).36,5}{300}.100\%=12,167\%\)
\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
gọi nFe : a , nAl: b (a,b>0) => 56a + 27b = 16,6 (g)
\(pthh:Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
a a
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
b \(\dfrac{3b}{2}\)
=> \(a+\dfrac{3b}{2}=0,5\)
ta có hệ pt
\(\left\{{}\begin{matrix}56a+27b=16,6\\a+\dfrac{3b}{2}=0,5\end{matrix}\right.\)
=> a= 0,2 , b = 0,2
\(\left\{{}\begin{matrix}m_{Fe}=0,2.56=11,2\left(g\right)\\m_{Al}=16,6-11,2=5,4\left(g\right)\end{matrix}\right.\)
\(pthh:Fe+2HCl\rightarrow FeCl_2+H_2\)
0,2 0,4
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
0,2 0,6
=> \(m_{HCl}=\left(0,4+0,6\right).36,5=36,5\left(g\right)\)
=> \(C\%=\dfrac{36,5}{200}.100\%=18,25\%\)
\(n_{H_2}=\dfrac{13,44}{22,4}=0,6mol\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,6 1,2 0,6 0,6 ( mol )
\(m_{Fe}=0,6.56=33,6g\)
\(m_{FeCl_2}=0,6.127=76,2g\)
\(C_{M_{HCl}}=\dfrac{1,2}{0,6}=2M\)
`Fe + 2HCl -> FeCl_2 + H_2↑`
`0,3` `0,6` `0,3` `0,3` `(mol)`
`n_[H_2] = [ 6,72 ] / [ 22,4 ] = 0,3 (mol)`
`-> m_[Fe] = 0,3 . 56 = 16,8 (g)`
`-> m_[FeCl_2] = 0,3 . 127 = 38,1 (g)`
`b) C_[M_[HCl]] = [ 0,6 ] / [ 0,3 ] = 2 (M)`
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH: Fe + 2HCl ---> FeCl2 + H2
0,3<---0,6<------0,3<-----0,3
=> \(\left\{{}\begin{matrix}m_{Fe}=0,3.56=16,8\left(g\right)\\m_{FeCl_2}=127.0,3=38,1\left(g\right)\\C_{M\left(HCl\right)}=\dfrac{0,6}{0,3}=2M\end{matrix}\right.\)
nFe = \(\dfrac{22,4}{56}=0,4\left(mol\right)\)
Pt: Fe + 2HCl --> FeCl2 + H2
....0,4........0,8.........0,4........0,4
Vdd HCl đã dùng = \(\dfrac{0,8}{0,5}=1,6M\)
VH2 thu được = 0,4 . 22,4 = 8,96 (lít)
mFeCl2 thu được sau pứ = 0,4 . 127 = 50,8 (g)
nNa=11,5/23=0,5(mol)
nH2O=189/18=10,5(mol)
2Na+2H2O--->2NaOH+H2
2_____2
0,5___10,5
Ta có: 0,5/2<10,5/2
=>H2O dư
Theo pt: nH2=1/2nNa=1/2.0,5=0,25(mol)
=>VH2=0,25.22,4=5,6(l)
Theo pt: nNaOH=nNa=0,5(mol)
=>mNaOH=0,5.40=20(g)
mdd=11,5+189-0,25.2=200(g)
=>C%=20/200.100%=10%
nFeO=14,4/72=0,2(mol)
FeO+H2--->Fe+H2O
1____1
0,2___0,25
Ta có: 0,2/1<0,25/1
=>H2 dư
Theo pt: nFe=nFeO=0,2(mol)
=>mFe=0,2.56=11,2(g)
===>mFe thu đc= 11,2.75%=8,4(g)
nNa2O = 31/62 = 0.5 (mol)
Na2O + H2O => 2NaOH
0.5............................1
mNaOH = 1 * 40 = 40 (g)
m dung dịch = 31 + 50 = 81 (g)
C% NaOH = 40/81 * 100% = 49.38%
Cái này không lập tỉ lệ dư em nha !