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\(a/ZnO+2HCl\rightarrow ZnCl_2+H_2O\\ Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\\ b/n_{HCl}=\dfrac{250.7,3}{100}:36,5=0,5mol\\ n_{ZnO}=a;n_{Fe_2O_3}=b\\ \Rightarrow\left\{{}\begin{matrix}81a+160b=16,1\\2a+6b=0,5\end{matrix}\right.\\ \Rightarrow a=b=0,1mol\\ \%m_{ZnO}=\dfrac{0,1.81}{16,1}\cdot100=50,3\%\\ \%m_{Fe_2O_3}=100-50,3=49,7\%\\ c/C_{\%ZnCl_2}=\dfrac{136.0,1}{16,1+250}\cdot100=5\%\\ C_{\%FeCl_3}=\dfrac{0,1.2.162,5}{16,1+250}=12\%\)
a) CuO + 2HCl ⟶CuCl2 + 2H2O
6HCl + Fe2O3 → 2FeCl3 + 3H2O
Gọi x, y lần lượt là số mol CuO, Fe2O3
\(\left\{{}\begin{matrix}80x+160y=16\\135x+162,5.2y=29,75\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}x=0,1\\y=0,05\end{matrix}\right.\)
=> \(\%m_{CuO}=\dfrac{0,1.80}{16}.100=50\%\)
\(\%m_{Fe_2O_3}=100-50=50\%\)
b) \(n_{HCl}=2n_{CuO}+6n_{Fe_2O_3}=0,5\left(mol\right)\)
=> \(CM_{HCl}=\dfrac{0,3}{0,1}=3M\)
Zn+2HCl->ZnCl2+H2
ZnO+2HCl->ZnCl2+H2O
nH2=0.2(mol)->nZn=0.2(mol).mZn=13(g)
mZnO=21.1-13=8.1(g)
nZnO=0.1(mol)
Tổng nHCl cần dùng:0.2*2+0.1*2=0.6(mol)
mHCl=21.9(g)
C%ddHCl=21.9:200*100=10.95%
n muối=0.2+.1=0.3(mol)
m muối=40.8(g)
a,\(n_{HCl}=0,5.1=0,5\left(mol\right)\)
PTHH: CuO + 2HCl → CuCl2 + H2O
Mol: x 2x
PTHH: Fe2O3 + 6HCl → 2FeCl3 + 3H2O
Mol: y 6y
Ta có: \(\left\{{}\begin{matrix}80x+160y=16\\2x+6y=0,5\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,05\end{matrix}\right.\)
PTHH: CuO + 2HCl → CuCl2 + H2O
Mol: 0,1 0,2
PTHH: Fe2O3 + 6HCl → 2FeCl3 + 3H2O
Mol: 0,05 0,3
\(\Rightarrow m_{CuO}=0,1.80=8\left(g\right);m_{Fe_2O_3}=16-8=8\left(g\right)\)
b,\(\%m_{CuO}=\dfrac{8.100\%}{16}=50\%;\%m_{Fe_2O_3}=100-50=50\%\)
Đặt: \(n_{Zn}=a\left(mol\right);n_{ZnO}=b\left(mol\right)\left(a,b>0\right)\)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(a.Zn+2HCl\rightarrow ZnCl_2+H_2\\ ZnO+2HCl\rightarrow ZnCl_2+H_2O\\ \Rightarrow\left\{{}\begin{matrix}65a+81b=14,6\\a=0,1\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\\ b.m_{Zn}=0,1.65=6,5\left(g\right)\\ m_{ZnO}=0,1.81=8,1\left(g\right)\\ d.m_{ddHCl}=\dfrac{\left(0,1+0,1\right).2.36,5.100}{7,3}=200\left(g\right)\)
\(Fe_2O_3\left(a\right)+6HCl\left(6a\right)->2FeCl_3\left(2a\right)+3H_2O\)
\(CuO\left(b\right)+2HCl\left(2b\right)->CuCl_2\left(b\right)+H_2O\)
a) Gọi a,b lần lượt là sm của Fe2O3 , CuO
\(n_{HCl}=0,5\left(mol\right)\)
Ta có: \(\left\{{}\begin{matrix}160a+80b=16\\3a+b=0,25\end{matrix}\right.=>\left\{{}\begin{matrix}a=0,05\\b=0,1\end{matrix}\right.\)
\(\Rightarrow\%m\)
b) \(m_{FeCl_3}=0,1.162,5=16,25g\)
\(m_{CuCl_2}=13,5g\)
c) \(C\%ddFeCl_2=\dfrac{16,25}{266}.100\%=6,1\%\)
\(C\%ddCuCl_2=5\%\)