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a) \(C_2H_4 + Br_2 \to C_2H_4Br_2\)
b)
\(n_{C_2H_4} = n_{Br_2} = \dfrac{5,6}{160} = 0,035(mol)\\ \%V_{C_2H_4} = \dfrac{0,035.22,4}{0,86}.100\% = 91,16\%\\ \%V_{CH_4} = 100\% - 91,16\% = 8,84\%\)
Gọi số mol của C2H4 và C2H2 lần lượt là x và y mol
theo bài ra: x+y = 0,56/22,4 = 0,025 (mol)
Pt:
C2H4 + Br2 → C2H4Br2
x mol x mol x mol
C2H2 + 2 Br2 → C2H2Br4
y mol 2y mol y mol
Số mol n Br2 = x+2y = 5,6/160 = 0,035 9mol)
Giải hệ ta đc: x = 0,015 và y = 0,01
=> %V C2H4 = 0,015/0,025 = 60% ; %V C2H2 = 40%
a) C2H4 + Br2 --> C2H4Br2
C2H2 + 2Br2 --> C2H2Br4
b) Gọi số mol C2H4, C2H2 là a, b (mol)
=> a + b = \(\dfrac{1,68}{22,4}=0,075\left(mol\right)\) (1)
\(n_{Br_2}=\dfrac{16}{160}=0,1\left(mol\right)\)
=> a + 2b = 0,1 (2)
(1)(2) => a = 0,05 (mol); b = 0,025 (mol)
=> \(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,05}{0,075}.100\%=66,67\%\\\%V_{C_2H_2}=\dfrac{0,025}{0,075}.100\%=33,33\%\end{matrix}\right.\)
c)
PTHH: C2H4 + 3O2 --to--> 2CO2 + 2H2O
0,05--->0,15
2C2H2 + 5O2 --to--> 4CO2 + 2H2O
0,025-->0,0625
=> VO2 = (0,15 + 0,0625).22,4 = 4,76 (l)
a.b.\(n_{Br_2}=\dfrac{16}{160}=0,1mol\)
\(n_{hh}=\dfrac{1,68}{22,4}=0,075mol\)
Gọi \(\left\{{}\begin{matrix}n_{C_2H_2}=x\\n_{C_2H_4}=y\end{matrix}\right.\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
x 2x ( mol )
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
y y ( mol )
Ta có:
\(\left\{{}\begin{matrix}22,4x+22,4y=1,68\\2x+y=0,1\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,025\\y=0,05\end{matrix}\right.\)
\(\%V_{C_2H_2}=\dfrac{0,025}{0,075}.100=33,33\%\)
\(\%V_{C_2H_4}=100\%-33,33\%=66,67\%\)
c.
\(2C_2H_2+5O_2\rightarrow\left(t^o\right)4CO_2+2H_2O\)
0,025 0,0625 ( mol )
\(C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\)
0,05 0,15 ( mol )
\(V_{O_2}=\left(0,0625+0,15\right).22,4=4,76l\)
a) C2H4 + Br2 --> C2H4Br2
b) \(n_{Br_2}=\dfrac{24}{160}=0,15\left(mol\right)\)
PTHH: C2H4 + Br2 --> C2H4Br2
0,15<--0,15----->0,15
=> \(\%V_{C_2H_4}=\dfrac{0,15.22,4}{7,84}.100\%=42,857\%\)
=> \(\%V_{CH_4}=\dfrac{7,84-0,15.22,4}{7,84}.100\%=57,143\%\)
c) mC2H4Br2 = 0,15.188 = 28,2 (g)
a, \(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
\(n_{Br_2}=\dfrac{8}{160}=0,05\left(mol\right)\)
\(n_{C_2H_2}=\dfrac{1}{2}n_{Br_2}=0,025\left(mol\right)\Rightarrow m_{C_2H_2}=0,025.26=0,65\left(g\right)\)
b, \(\left\{{}\begin{matrix}\%V_{C_2H_2}=\dfrac{0,025.22,4}{33,6}.100\%\approx1,67\%\\\%V_{CH_4}\approx98,33\%\end{matrix}\right.\)
a) C2H4 + Br2 --> C2H4Br2
b) nBr2 = 0,2.0,2 = 0,04 (mol)
PTHH: C2H4 + Br2 --> C2H4Br2
0,04<--0,04
=> \(m_{C_2H_4}=0,04.28=1,12\left(g\right)\)
\(m_{CH_4}=n_{CH_4}.M_{CH_4}=\left(\dfrac{1,12}{22,4}-0,04\right).16=0,16\left(g\right)\)
c) \(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,04.22,4}{1,12}.100\%=80\%\\\%V_{CH_4}=100\%-80\%=20\%\end{matrix}\right.\)
PTPU
C2H4+ Br2\(\rightarrow\) C2H4Br2
có: nBr2= \(\dfrac{2,8}{160}\)= 0,0175( mol)
theo PTPU có: nC2H4= nBr2= 0,0175( mol)
có: nhh khí= \(\dfrac{0,56}{22,4}\)= 0,025( mol)
\(\Rightarrow\) %VC2H4= \(\dfrac{0,0175}{0,025}\). 100%= 70%
%VCH4= 100%- 70%= 30%
có: nCH4= nhh khí- nC2H4
= 0,025- 0,0175= 0,0075( mol)
\(\Rightarrow\) mhh khí= 0,0075. 16+ 0,0175. 28= 0,61( g)
\(\Rightarrow\) %mCH4=\(\dfrac{0,0075.16}{0,61}\). 100%= 19,67%
%mC2H4= 100%- 19,67%= 80,33%