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Ta có: \(\overline{A}=\dfrac{24\cdot69+25\cdot\left(100-69\right)}{100}=24,31\)
Gọi \(n_{MgCl_2}=1\left(mol\right)=n_{Mg}\) \(\Rightarrow n_{^{25}Mg}=0,31\left(mol\right)\)
\(\Rightarrow\%m_{^{25}Mg}=\dfrac{25\cdot0.31}{24,31+35,5\cdot2}\approx8,13\%\)
\(n_{H_2}=\dfrac{0,784}{22,4}=0,035\left(mol\right)\\ Đặt:n_{Al}=a\left(mol\right);n_{Fe}=b\left(mol\right)\left(a,b>0\right)\\ PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ \Rightarrow\left\{{}\begin{matrix}27a+56b=1,39\\1,5a+b=0,035\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,01\\b=0,02\end{matrix}\right.\\ \Rightarrow\%m_{Al}=\dfrac{0,01.27}{1,39}.100=37,53\%\\ \Rightarrow\%m_{Fe}=100\%-37,53\%=62,47\%\)
\(n_{Cl_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\\ Cl_2+2NaOH\rightarrow NaCl+NaClO+H_2O\\ C_{MddNaOH\left(dư\right)}=0,05\left(mol\right)\Rightarrow Tính.theo.Cl_2\\ n_{NaOH\left(P.Ứ\right)}=2.n_{Cl_2}=2.0,05=0,1\left(mol\right)\\ n_{NaOH\left(dư\right)}=0,2.0,05=0,01\left(mol\right)\\ \Rightarrow C_{MddNaOH\left(ban.đầu\right)}=\dfrac{0,1+0,01}{0,2}=0,55\left(M\right)\\ \Rightarrow Chọn.D\)
Câu 10:
\(PCl_3+3H_2O\rightarrow H_3PO_3+3HCl\\ H_3PO_3+3NaOH\rightarrow Na_3PO_3+3H_2O\\HCl+NaOH\rightarrow NaCl+H_2O\\ Đặt:n_{PCl_3}=k\left(mol\right)\\ \Rightarrow n_{H_3PO_3}=k\left(mol\right);n_{HCl}=3k\left(mol\right)\\ Ta.có:n_{NaOH}=3.n_{H_3PO_3}+n_{HCl}=3k+3k\\ \Leftrightarrow0,6=6k\\ \Leftrightarrow k=0,1\left(mol\right)\\ \Rightarrow n_{PCl_3}=0,1\left(mol\right)\\ \Rightarrow Chọn.A\)
Câu 8:
\(n_{NaCl}=\dfrac{8,775}{58,5}=0,15\left(mol\right)\\ NaCl+H_2SO_{4\left(đặc\right)}\rightarrow\left(250^oC\right)NaHSO_4+HCl\uparrow\\ n_{HCl}=n_{NaCl}=0,15\left(mol\right)\\ \Rightarrow C\%_{ddHCl}=\dfrac{0,15.36,5}{0,15.36,5+14,525}.100=27,375\%\\ \Rightarrow Chọn.A\\ MnO_2+4HCl_{đặc}\rightarrow\left(t^o\right)MnCl_2+Cl_2+2H_2O\\ n_{Cl_2\left(thu\right)}=70\%.n_{Cl_2\left(LT\right)}=70\%.\dfrac{0,15}{4}=0,02625\left(mol\right)\\ \Rightarrow V_{Cl_2\left(đktc,thu\right)}=0,02625.22,4=0,588\left(l\right)\\ \Rightarrow Chọn.B\)
Câu 29:
(1) \(Cl_2+2NaOH\rightarrow NaCl+NaClO+H_2O\)
(2) \(2Fe+3Cl_2\underrightarrow{t^o}2FeCl_3\)
(3) \(H_2+Cl_2\underrightarrow{t^o}2HCl\)
(4) \(HCl+NaOH\rightarrow NaCl+H_2O\)
(5) \(NaCl+AgNO_3\rightarrow NaNO_3+AgCl_{\downarrow}\)
(6) \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Câu 30:
a, PT: \(Zn+S\underrightarrow{t^o}ZnS\)
\(Fe+S\underrightarrow{t^o}FeS\)
b, Giả sử: \(\left\{{}\begin{matrix}n_{Zn}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\)
⇒ 65x + 56y = 26,55 (1)
Ta có: \(n_S=\dfrac{14,4}{32}=0,45\left(mol\right)\)
Theo PT: \(n_S=n_{Zn}+n_{Fe}=x+y\left(mol\right)\)
⇒ x + y = 0,45 (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,15\left(mol\right)\\y=0,3\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,15.65}{26,55}.100\%\approx36,7\%\\\%m_{Fe}\approx63,3\%\end{matrix}\right.\)
Bạn tham khảo nhé!