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- Chuỗi 1:
(1) \(CH_3COONa+NaOH\underrightarrow{^{t^o,CaO}}CH_4+Na_2CO_3\)
(2) \(C_4H_{10}\underrightarrow{^{t^o,p,xt}}CH_4+C_3H_6\)
(3) \(Al_4C_3+12H_3O\rightarrow4Al\left(OH\right)_3+3CH_4\)
(4) \(2CH_4\underrightarrow{^{1500^oC,lln}}C_2H_2+3H_2\)
(5) \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
(6) \(CH_4+Cl_2\underrightarrow{^{as}}CH_3Cl+HCl\)
(7) \(CH_3Cl+Cl_2\underrightarrow{^{as}}CH_2Cl_2+HCl\)
(8) \(CH_4+O_2\underrightarrow{^{t^o,xt}}HCHO+H_2O\)
- Chuỗi 2:
(1) \(C_2H_2+H_2\underrightarrow{^{t^o,Pd}}C_2H_4\)
(2) \(nCH_2=CH_2\underrightarrow{^{t^o,p,xt}}\left(-CH_2-CH_2-\right)_n\)
(3) \(3C_2H_4+2KMnO_4+4H_2O\rightarrow3C_2H_4\left(OH\right)_2+2MnO_{2\downarrow}+2KOH\)
(4) \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
(5) \(C_2H_4+H_2O\underrightarrow{^{t^o,xt}}C_2H_5OH\)
(6) \(C_2H_5OH\xrightarrow[170^oC]{^{H_2SO_4\left(đ\right)}}C_2H_4+H_2O\)
(7) \(C_2H_4+H_2\underrightarrow{t^o,Ni}C_2H_6\)
(8) \(C_2H_6\underrightarrow{t^o,p,xt}C_2H_4+H_2\)
(9) \(C_2H_4+HCl\underrightarrow{t^o,xt}C_2H_5Cl\)
(10) \(C_2H_6+Cl_2\underrightarrow{as}C_2H_5Cl+HCl\)
- Chuỗi 3:
(1) \(2CH_4\underrightarrow{^{1500^oC,lln}}C_2H_2+3H_2\)
(2) \(CaC_2+2H_2O\rightarrow C_2H_2+Ca\left(OH\right)_2\)
(3) \(C_2H_2+2H_2\underrightarrow{^{t^o,Ni}}C_2H_6\)
(4) \(C_2H_2+H_2\underrightarrow{t^o,Pd}C_2H_4\)
(5) \(C_2H_2+H_2O\underrightarrow{t^o,xt}CH_3CHO\)
(6) \(C_2H_2+HCl\underrightarrow{t^o,xt}CH_2=CHCl\)
(7) \(nCH_2=CHCl\underrightarrow{t^o,p,xt}\left(-CH_2-CHCl-\right)_n\)
(8) \(2C_2H_2\underrightarrow{t^o,p,xt}C_4H_4\)
(9) \(3C_2H_2\underrightarrow{t^o,p,xt}C_6H_6\)
(10) \(C_2H_2+2AgNO_3+2NH_3\rightarrow Ag_2C_2+2NH_4NO_3\)
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Bài 1 :
\(CT:C_nH_{2n-6}\left(n\ge6\right)\)
\(\%C=\dfrac{12n}{14n-6}\cdot100\%=90.57\%\)
\(\Rightarrow n=8\)
\(CT:C_8H_{10}\)
Bài 2 :
\(n_{CO_2}=\dfrac{17.6}{44}=0.4\left(mol\right)\)
\(CT:C_nH_{2n+1}OH\)
\(\Rightarrow n_{ancol}=\dfrac{n_{CO_2}}{n}=\dfrac{0.4}{n}\left(mol\right)\)
\(M_A=\dfrac{7.4}{\dfrac{0.4}{n}}=\dfrac{37}{2}n\left(\dfrac{g}{mol}\right)\)
\(\Rightarrow14n+18=\dfrac{37}{2}n\)
\(\Rightarrow n=4\)
\(CT:C_4H_9OH\)
\(CTCT:\)
\(B1:\)
\(CH_3-CH_2-CH_2-CH_2-OH:butan-1-ol\)
\(B2:\)
\(CH_3-CH_2-CH\left(CH_3\right)-OH:butan-2-ol\)
\(B2:\)
\(CH_3-CH\left(CH_3\right)-CH_2-OH:2-metylpropan-1-ol\)
\(B3:\)
\(C\left(CH_3\right)_3-OH:2-metylpropan-2-ol\)
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