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\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\ n_S=\dfrac{3,2}{32}=0,1\left(mol\right)\\ PTHH:Fe+S\underrightarrow{t^o}FeS\left(1\right)\\ LTL:0,2>0,1\Leftrightarrow Fe.dư\)
\(Theo.pt\left(1\right):n_{Fe\left(pư\right)}=n_{FeS}=0,1\left(mol\right)\\ n_{FeS\left(dư\right)}=0,2-0,1=0,1\left(mol\right)\)
\(PTHH:FeS+H_2SO_4\rightarrow FeSO_4+H_2S\uparrow\left(2\right)\\ Fe+2H_2SO_4\rightarrow FeSO_4+SO_2\uparrow+2H_2O\left(3\right)\)
\(Theo.pt\left(2\right):n_{H_2S}=n_{FeS}=0,1\left(mol\right)\\ Theo.pt\left(3\right):n_{SO_2}=n_{Fe}=0,1\left(mol\right)\\ \%V_{H_2S}=\dfrac{0,1}{0,1+0,1}=50\%\\ \%V_{SO_2}=100\%-50\%=50\%\)
\(Theo.pt\left(2\right):n_{H_2SO_4\left(2\right)}=n_{FeS}=0,1\left(mol\right)\\ Theo.pt\left(3\right):n_{H_2SO_4\left(3\right)}=2n_{Fe}=2.0,1=0,3\left(mol\right)\\ C_{MddH_2SO_4}=\dfrac{0,3}{0,2}=1,5M\)
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nKMnO4 = 14,2/158 ≃ 0,0899 mol
2KMnO4 + 16HCl → 2KCl + 2MnCl2 + 5Cl2 + 8H2O
0,0899 \(\dfrac{0,0899\times5}{2}\)
→ nCl2 = 0,22475 mol → VCl2 = 22,4.nCl2 = 5,0344 lít
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\(n_{Fe}=\dfrac{5,6}{56}=0,1mol\)
\(n_S=\dfrac{4,8}{32}=0,15mol\)
\(Fe+S\underrightarrow{t^o}FeS\)
0,1 0,15 0,1
\(FeS+2HCl\rightarrow FeCl_2+H_2S\uparrow\)
0,1 0,1 0,1
\(V_Y=0,1\cdot22,4=2,24l\)
\(m_Z=m_{FeCl_2}=0,1\cdot127=12,7g\)
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14A
15B
16B
17C
18B
19B
20C
Anh giải chi tiết em câu 16 với 20 được không ạ