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PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
_____0,9___0,6______0,3 (mol)
a, \(V_{O_2}=0,6.22,4=13,44\left(l\right)\)
b, \(m_{Fe}=0,9.56=50,4\left(g\right)\)
c, \(V_{kk}=\dfrac{V_{O_2}}{20\%}=67,2\left(l\right)\)
PTHH: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
Ta có: \(\left\{{}\begin{matrix}n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\n_{O_2}=\dfrac{12,8}{32}=0,4\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{3}< \dfrac{0,4}{2}\) \(\Rightarrow\) Oxi còn dư, Fe p/ứ hết
\(\Rightarrow n_{O_2\left(dư\right)}=0,4-\dfrac{2}{15}=\dfrac{4}{15}\left(mol\right)\)
+) Theo PTHH: \(\left\{{}\begin{matrix}n_{O_2}=\dfrac{2}{15}\left(mol\right)\\n_{Fe_3O_4}=\dfrac{1}{15}\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}V_{kk}=\dfrac{2}{15}\cdot22,4\cdot5\approx14,93\left(l\right)\\m_{Fe_3O_4}=\dfrac{1}{15}\cdot232\approx15,47\left(g\right)\end{matrix}\right.\)
\(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
\(PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\\ Mol:0,4\rightarrow\dfrac{4}{15}\rightarrow\dfrac{2}{15}\)
\(\rightarrow\left\{{}\begin{matrix}V_{O_2}=\dfrac{4}{15}.22,4=\dfrac{448}{75}\left(l\right)\rightarrow V_{kk}=\dfrac{448}{75}.5=\dfrac{448}{15}\left(l\right)\\m_{Fe_3O_4}=\dfrac{2}{15}.232=\dfrac{464}{15}\left(g\right)\end{matrix}\right.\)
2KClO3 --to--> 2KCl + 3O2
\(\dfrac{8}{45}\) \(\dfrac{4}{15}\)
\(m_{KClO_3}=\dfrac{8}{45}.122,5=\dfrac{196}{9}\left(g\right)\)
a, \(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
PTHH: 3Fe + 2O2 ---to---> Fe3O4
Mol: 0,4 \(\dfrac{0,8}{3}\) \(\dfrac{0,4}{3}\)
b, \(V_{O_2}=\dfrac{0,8}{3}.22,4=5,973\left(l\right)\)
c, \(V_{kk}=\dfrac{448}{75}.5=29,867\left(l\right)\)
d, \(m_{Fe_3O_4}=\dfrac{0,4}{3}.232=30,93\left(g\right)\)
e,
PTHH: 2KClO3 ---to---> 2KCl + 3O2
Mol: \(\dfrac{0,16}{9}\) \(\dfrac{0,8}{3}\)
\(m_{KClO_3}=\dfrac{0,16}{9}.122,5=2,178\left(g\right)\)
a) \(4Al+3O_2-^{t^o}\rightarrow2Al_2O_3\)
Bảo toàn khối lượng : \(m_{O_2}=12,24-8,1=4,14\left(g\right)\)
=>\(n_{O_2}=\dfrac{207}{1600}\left(mol\right)\)
Vì O2 chiếm 20% thể tích không khí
\(V_{kk}=\dfrac{\dfrac{207}{1600}.22,4}{20\%}=14,49\left(lít\right)\)
b) \(n_{Al}=\dfrac{8,1}{27}=0,3\left(mol\right)\)
Lập tỉ lệ : \(\dfrac{0,3}{4}>\dfrac{\dfrac{207}{1600}}{3}\)
=> Sau phản ứng Al dư
\(n_{Al\left(pứ\right)}=\dfrac{207}{1600}.\dfrac{4}{3}=0,1725\left(mol\right)\)
=> \(H=\dfrac{0,1725}{0,3}.100=57,5\%\)
c) D gồm Al2O3 và Al dư
\(n_{Al_2O_3}=\dfrac{2}{3}n_{O_2}=\dfrac{69}{800}\left(mol\right);n_{Al\left(dư\right)}=0,3-0,1725=0,1275\left(mol\right)\)
\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(\Sigma n_{HCl}=\dfrac{69}{800}.6+0,1275.3=0,9\left(mol\right)\)
=> \(m_{HCl}=0,9.36,5=32,85\left(g\right)\)
a. \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
PTHH : 3Fe + 2O2 -to> Fe3O4
0,3 0,2 0,1
b. \(m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)
c. \(V_{O_2}=0,2.22,4=4,48\left(l\right)\)
a \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b \(\Rightarrow n_{Fe}=\dfrac{16,8}{56}=0,3mol\) \(\Rightarrow n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,1mol\Rightarrow m_{Fe_3O_4}=0,1\cdot232=2,32g\)
c \(\Rightarrow n_{O_2}=\dfrac{2}{3}n_{Fe}=0,2mol\Rightarrow V_{O_2}=0,2\cdot22,4=4,48l\)
có nFe =2,8/56 = 0,05 mol
a. PTHH : 3Fe + 2O2 --to--> Fe3O4
b. Theo phương trình , nO2 = 2/3 . nFe = 0,05.2/3 = 1/30 mol
⇒ VO2 = 1/30 .22,4 =0,7467 lít
c. có nFe3O4 = nFe/3 = 0,05/3 = 1/60 mol
⇒ mFe3O4 = 1/60 .232 =3,867 gam
