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b/ n CO\(_2\)= 8,8 : 44 = 0,2 (mol)
n H\(_2\)O = 3,6 : 18 = 0,2 (mol)
=> n O\(_2\) = 0,2 mol
=> a là : 16 . 0,2 = 3.2 (g)
nC = 4,8/12 = 0,4 mol
nS = 6,4/32 = 0,2 mol
a. C + O2 -> (nhiệt độ) CO2
S + O2 -> (nhiệt độ) SO2
nO2 = nC + nS = 0,6 mol
=> nN2 = 4 x nO2 = 2,4 mol
=> n không khí = 3 mol => V = 67,2 L
b. mB = 44 x 0,4 + 64 x 0,2 = 30,4 g
nB = 0,6 mol
=> M(trung bình của B) = 30,4/0,6 = 50,67 g/mol
\(1,2H_2+O_2\underrightarrow{t}2H_2O\)
\(2Mg+O_2\underrightarrow{t}2MgO\)
\(2Cu+O_2\underrightarrow{t}2CuO\)
\(S+O_2\underrightarrow{t}SO_2\)
\(4Al+3O_2\underrightarrow{t}2Al_2O_3\)
\(C+O_2\underrightarrow{t}CO_2\)
\(4P+5O_2\underrightarrow{t}2P_2O_5\)
\(2,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(a,n_{O_2}=0,2\left(mol\right)\Rightarrow n_{CO_2}=0,2\left(mol\right)\Rightarrow m_{CO_2}=8,8\left(g\right)\)
\(b,n_C=0,3\left(mol\right)\Rightarrow n_{CO_2}=0,3\left(mol\right)\Rightarrow m_{CO_2}=13,2\left(g\right)\)
c, Vì\(\frac{0,3}{1}>\frac{0,2}{1}\)nên C phản ửng dư, O2 phản ứng hết, Bài toán tính theo O2
\(n_{O_2}=0,2\left(mol\right)\Rightarrow n_{CO_2}=0,2\left(mol\right)\Rightarrow m_{CO_2}=8,8\left(g\right)\)
\(3,PTHH:CH_4+2O_2\underrightarrow{t}CO_2+2H_2O\)
\(C_2H_2+\frac{5}{2}O_2\underrightarrow{t}2CO_2+H_2O\)
\(C_2H_6O+3O_2\underrightarrow{t}2CO_2+3H_2O\)
\(4,a,PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
\(n_P=1,5\left(mol\right)\Rightarrow n_{O_2}=1,2\left(mol\right)\Rightarrow m_{O_2}=38,4\left(g\right)\)
\(b,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(n_C=2,5\left(mol\right)\Rightarrow n_{O_2}=2,5\left(mol\right)\Rightarrow m_{O_2}=80\left(g\right)\)
\(c,PTHH:4Al+3O_2\underrightarrow{t}2Al_2O_3\)
\(n_{Al}=2,5\left(mol\right)\Rightarrow n_{O_2}=1,875\left(mol\right)\Rightarrow m_{O_2}=60\left(g\right)\)
\(d,PTHH:2H_2+O_2\underrightarrow{t}2H_2O\)
\(TH_1:\left(đktc\right)n_{H_2}=1,5\left(mol\right)\Rightarrow n_{O_2}=0,75\left(mol\right)\Rightarrow m_{O_2}=24\left(g\right)\)
\(TH_2:\left(đkt\right)n_{H_2}=1,4\left(mol\right)\Rightarrow n_{O_2}=0,7\left(mol\right)\Rightarrow m_{O_2}=22,4\left(g\right)\)
\(5,PTHH:S+O_2\underrightarrow{t}SO_2\)
\(n_{O_2}=0,46875\left(mol\right)\)
\(n_{SO_2}=0,3\left(mol\right)\)
Vì\(0,46875>0,3\left(n_{O_2}>n_{SO_2}\right)\)nên S phản ứng hết, bài toán tính theo S.
\(a,\Rightarrow n_S=n_{SO_2}=0,3\left(mol\right)\Rightarrow m_S=9,6\left(g\right)\)
\(n_{O_2}\left(dư\right)=0,16875\left(mol\right)\Rightarrow m_{O_2}\left(dư\right)=5,4\left(g\right)\)
\(6,a,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_C=1,5\left(mol\right)\Rightarrow m_C=18\left(g\right)\)
\(b,PTHH:2H_2+O_2\underrightarrow{t}2H_2O\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_{H_2}=0,75\left(mol\right)\Rightarrow m_{H_2}=1,5\left(g\right)\)
\(c,PTHH:S+O_2\underrightarrow{t}SO_2\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_S=1,5\left(mol\right)\Rightarrow m_S=48\left(g\right)\)
\(d,PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_P=1,2\left(mol\right)\Rightarrow m_P=37,2\left(g\right)\)
\(7,n_{O_2}=5\left(mol\right)\Rightarrow V_{O_2}=112\left(l\right)\left(đktc\right)\);\(V_{O_2}=120\left(l\right)\left(đkt\right)\)
\(8,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(m_C=0,96\left(kg\right)\Rightarrow n_C=0,08\left(kmol\right)=80\left(mol\right)\Rightarrow n_{O_2}=80\left(mol\right)\Rightarrow V_{O_2}=1792\left(l\right)\)
\(9,n_p=0,2\left(mol\right);n_{O_2}=0,3\left(mol\right)\)
\(PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
Vì\(\frac{0,2}{4}< \frac{0,3}{5}\)nên P hết O2 dư, bài toán tính theo P.
\(a,n_{O_2}\left(dư\right)=0,05\left(mol\right)\Rightarrow m_{O_2}\left(dư\right)=1,6\left(g\right)\)
\(b,n_{P_2O_5}=0,1\left(mol\right)\Rightarrow m_{P_2O_5}=14,2\left(g\right)\)
$n_{CO_2} = \dfrac{8,8}{44} = 0,2(mol) ; n_{H_2O} = \dfrac{3,6}{18} = 0,2(mol)$
$C_xH_y + (x + \dfrac{y}{4})O_2 \xrightarrow{t^o} xCO_2 + \dfrac{y}{2}H_2O$
Theo PTHH :
$0,1.x = 0,2$ và $0,1.\dfrac{y}{2} = 0,2$
Suy ra : x = 2 ; y = 4
Vậy CTHH cần tìm là $C_2H_4$(M = 28)
\(n_C=n_S=x\left(mol\right)\\ m_C+m_S=m_{hh}\\ \Leftrightarrow12x+32x=4,4\\ \Leftrightarrow x=n_C=n_S=0,1\left(mol\right)\\ a,\%m_C=\dfrac{0,1.12}{4,4}.100\approx27,273\%\\ \Rightarrow\%m_S\approx72,727\%\\ b,C+O_2\rightarrow\left(t^o\right)CO_2\\ S+O_2\rightarrow\left(t^o\right)SO_2\\ n_{O_2\left(tồng\right)}=n_C+n_S=0,1+0,1=0,2\left(mol\right)\\ V_{O_2\left(đktc\right)}=0,2.22,4=4,48\left(l\right)\\ M_{hh\left(CO_2,SO_2\right)}=\dfrac{44.0,1+64.0,1}{0,2}=54\left(\dfrac{g}{mol}\right)\\ \Rightarrow d_{\dfrac{hh\left(CO_2,SO_2\right)}{H_2}}=\dfrac{54}{2}=27\)
\(n_{H_2}=\dfrac{V}{24,79}=\dfrac{11,2}{24,79}\approx0,45\left(mol\right)\)
a) \(PTHH:2H_2+O_2\underrightarrow{t^o}2H_2O\)
2 1 2
0,45 0,225 0,45
b) \(m_{O_2}=n.M=0,225.\left(16.2\right)=7,2\left(g\right)\\ V_{O_2}=n.24,79=0,225.24,79=5,57775\left(l\right)\)
c) \(PTHH:2KMnO_4\rightarrow K_2MnO_4+MnO_2+O_2\)
2 1 1 1
0,45 0,225 0,225 0,225
\(m_{KMnO_4}=n.M=0,45.\left(39+55+16.4\right)=71,1\left(g\right).\)
a, \(2H_2+O_2\underrightarrow{t^o}2H_2O\)
b, Ta có: \(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{H_2}=0,25\left(mol\right)\)
\(\Rightarrow m_{O_2}=0,25.32=8\left(g\right)\)
\(V_{O_2}=0,25.22,4=5,6\left(l\right)\)
c, \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
Theo PT: \(n_{KMnO_4}=2n_{O_2}=0,5\left(mol\right)\Rightarrow m_{KMnO_4}=0,5.158=79\left(g\right)\)