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\(n_P=\dfrac{7,44}{31}=0,24mol\)
\(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
0,24 0,3 0,12
\(V_{O_2}=0,3\cdot22,4=6,72l\)
\(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
0,2 0,3
\(m_{KClO_3}=0,2\cdot122,5=24,5g\)
1. a. \(PTHH:2Mg+O_2\overset{t^o}{--->}2MgO\left(1\right)\)
b. Ta có: \(n_{Mg}=\dfrac{24}{24}=1\left(mol\right)\)
Theo PT(1): \(n_{O_2}=\dfrac{1}{2}.n_{Mg}=\dfrac{1}{2}.0,1=0,5\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,5.22,4=11,2\left(lít\right)\)
c. \(PTHH:2KClO_3\xrightarrow[t^o]{MnO_2}2KCl+3O_2\left(2\right)\)
Theo PT(2): \(n_{KClO_3}=\dfrac{2}{3}.n_{O_2}=\dfrac{2}{3}.0,5=\dfrac{1}{3}\left(mol\right)\)
\(\Rightarrow m_{KClO_3}=\dfrac{1}{3}.122,5=40,83\left(g\right)\)
2. \(PTHH:3Fe+2O_2\overset{t^o}{--->}Fe_3O_4\)
Ta có: \(n_{Fe_3O_4}=\dfrac{2,32}{232}=0,01\left(mol\right)\)
a. Theo PT: \(n_{Fe}=3.n_{Fe_3O_4}=0,01.3=0,03\left(mol\right)\)
\(\Rightarrow m_{Fe}=0,03.56=1,68\left(g\right)\)
b. Theo PT: \(n_{O_2}=2.n_{Fe_3O_4}=2.0,01=0,02\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,02.22,4=0,448\left(lít\right)\)
a) PTHH: \(Zn+\dfrac{1}{2}O_2\xrightarrow[]{t^o}ZnO\)
b) Ta có: \(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\) \(\Rightarrow n_{O_2}=0,15\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,15\cdot22,4=3,36\left(l\right)\)
c) PTHH: \(KClO_3\xrightarrow[MnO_2]{t^o}KCl+\dfrac{3}{2}O_2\uparrow\)
Theo PTHH: \(n_{KClO_3}=0,1\left(mol\right)\) \(\Rightarrow m_{KClO_3}=0,1\cdot122,5=12,25\left(g\right)\)
a, \(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
b, \(n_{Al}=\dfrac{8,1}{27}=0,3\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{3}{4}n_{Al}=0,225\left(mol\right)\Rightarrow V_{O_2}=0,225.22,4=5,04\left(l\right)\)
c, \(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
Theo PT: \(n_{KClO_3}=\dfrac{2}{3}n_{O_2}=0,15\left(mol\right)\Rightarrow m_{KClO_3}=0,15.122,5=18,375\left(g\right)\)
3Fe+2O2-to>Fe3O4
0,225--0,15
n Fe=\(\dfrac{12,6}{56}\)=0,225 mol
VO2=0,15.22,4=3,36l
2KClO3-to>2KCl+3O2
0,1---------------------0,15
=>m KClO3=0,1.122,5=12,25g
\(a,3Fe+2O_2\rightarrow Fe_3O_4\)
\(b,\)
Ta có : \(n_{Fe}=\dfrac{m}{M}=\dfrac{126}{56}=2,25\left(mol\right)\)
\(\Rightarrow n_{O_2}=\dfrac{2}{3}n_{Fe}=\dfrac{2}{3}.2,25=1,5\left(mol\right)\)
\(\Rightarrow VO_2=33,6\left(l\right)\)
\(c,\)
\(PTHH:2KClO_3\rightarrow2KCl+3O_2\)
Theo \(PTHH:n_{KClO_3}=\dfrac{2}{3}n_{O_2}=\dfrac{2}{3}.1,5=1\left(mol\right)\)
\(\Rightarrow m_{KClO_3}=n.M=1,122,5=122,5\left(g\right)\)
a. 4Al + 3O2 -> 2Al2O3
0.3 0.225 0.15
b.\(n_{Al}=\dfrac{8.1}{27}=0.3mol\)
\(V_{O_2}=0.225\times22.4=5.04l\)
c.\(m_{Al_2O_3}=0.15\times102=15.3g\)
a, \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
b, \(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Zn}=0,3\left(mol\right)\Rightarrow V_{H_2}=0,3.22,4=6,72\left(l\right)\)
c, \(n_{ZnSO_4}=n_{Zn}=0,3\left(mol\right)\Rightarrow m_{ZnSO_4}=0,3.161=48,3\left(g\right)\)
d, \(n_{Fe_2O_3}=\dfrac{64}{160}=0,4\left(mol\right)\)
PT: \(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
Xét tỉ lệ: \(\dfrac{0,4}{1}>\dfrac{0,3}{3}\), ta được Fe2O3 dư.
Mà: H% = 30% \(\Rightarrow n_{H_2\left(pư\right)}=0,3.30\%=0,09\left(mol\right)\)
Theo PT: \(\left\{{}\begin{matrix}n_{Fe}=\dfrac{2}{3}n_{H_2}=0,06\left(mol\right)\\n_{Fe_2O_3\left(pư\right)}=\dfrac{1}{3}n_{H_2}=0,03\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{Fe_2O_3\left(dư\right)}=0,4-0,03=0,37\left(mol\right)\)
\(\Rightarrow a=m_{Fe}+m_{Fe_2O_3\left(dư\right)}=62,56\left(g\right)\)
\(n_{Fe}=\dfrac{126}{56}=2,25\left(mol\right)\\
pthh:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
2,25 1,5
=> \(V_{O_2}=1,5.22,4=33,6\left(L\right)\)
\(PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
1 1,5
=> \(m_{KClO3}=122,5\left(g\right)\)
a, PT: \(2Zn+O_2\underrightarrow{t^o}2ZnO\) - pư hóa hợp.
b, \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{Zn}=0,1\left(mol\right)\Rightarrow V_{O_2}=0,1.22,4=2,24\left(l\right)\)
c, \(n_{H_2SO_4}=\dfrac{9,8}{98}=0,1\left(mol\right)\)
PT: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
Xét tỉ lệ: \(\dfrac{0,2}{1}>\dfrac{0,1}{1}\), ta được Zn dư.
Theo PT: \(n_{H_2}=n_{H_2SO_4}=0,1\left(mol\right)\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
\(n_{ZnSO_4}=n_{H_2SO_4}=0,1\left(mol\right)\Rightarrow m_{ZnSO_4}=0,1.161=16,1\left(g\right)\)