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\(\left\{{}\begin{matrix}n_{CH_4}=a\left(mol\right)\\n_{C_2H_4}=b\left(mol\right)\end{matrix}\right.\)\(\Rightarrow a + b = \dfrac{3,36}{22,4} = 0,15(1) \)
\(CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_4 + 3O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O\\ n_{CO_2} = a + 2b = \dfrac{4,48}{22,4} = 0,2(2)\)
Từ (1)(2) suy ra: a = 0,1 ; b = 0,05
Suy ra:
\(\%V_{CH_4} = \dfrac{0,1}{0,15}.100\% = 66,67\%\\ \%V_{C_2H_4} = 100\% - 66,67\% = 33,33\%\)
b)
\(C_2H_4 + Br_2 \to C_2H_4Br_2\\ n_{Br_2} = n_{C_2H_4} = 0,05(mol)\\ \Rightarrow m_{Br_2} = 0,05.160 = 8\ gam\)
\(n_{CO_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
Đặt \(\left\{{}\begin{matrix}n_{CH_4}=x\\n_{C_2H_4}=y\end{matrix}\right.\) ( mol ) \(\Rightarrow m_{hh}=16x+28y=6\left(g\right)\) (1)
\(CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\)
x x ( mol )
\(C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\)
y 2y ( mol )
\(n_{CO_2}=x+2y=0,4\left(mol\right)\) (2)
\(\left(1\right);\left(2\right)\Rightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)
\(\%m_{CH_4}=\dfrac{0,2.16}{6}.100=53,33\%\)
\(\%m_{C_2H_4}=100-53,33=46,67\%\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,1 0,1 ( mol )
\(m_{Br_2}=0,1.160=16\left(g\right)\)
a, Ta có \(n_{CH_4}+n_{C_2H_4}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\left(1\right)\)
PT: \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
\(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)
Theo PT: \(n_{O_2}=2n_{CH_4}+3n_{C_2H_4}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,05\left(mol\right)\\n_{C_2H_4}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}V_{CH_4}=0,05.22,4=1,12\left(l\right)\\V_{C_2H_4}=0,1.22,4=2,24\left(l\right)\end{matrix}\right.\)
b, \(m_{CH_4}=0,05.16=0,8\left(g\right)\)
c, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
Theo PT: \(n_{Br_2}=n_{C_2H_4}=0,1\left(mol\right)\Rightarrow V_{ddBr_2}=\dfrac{0,1}{1}=0,1\left(l\right)\)
\(m_{C_2H_4}=0,1.28=2,8\left(g\right)\)
\(a)\\ C_3H_4 + 4O_2 \xrightarrow{t^o} 3CO_2 + 2H_2O\\ C_3H_8 + 5O_2 \xrightarrow{t^o} 3CO_2 + 4H_2O\\ C_3H_6 + \dfrac{9}{2}O_2 \xrightarrow{t^o} 3CO_2 + 3H_2O\)
Coi X là C3Hx
Ta có : 12.3 + x = 21,2.2 ⇒ x = 6,4
\(n_X = \dfrac{15,9}{21,2.2} = 0,375(mol)\\ n_{CO_2} = 3n_X = 0,375.3 = 1,125(mol)\\ \Rightarrow m_{CO_2} = 1,125.44 = 49,5(gam)\\ n_{H_2O} = \dfrac{6,4}{2}.0,375 = 1,2(mol)\\ \Rightarrow m_{H_2O} = 1,2.18 = 21,6(gam)\)
C1:
Bảo toàn C: nC = 0,4 (mol)
Bảo toàn H: nH = 1,2 (mol)
=> mhh = 12.0,4 + 1.1,2 = 6(g)
C2:
Bảo toàn O: nO2 = \(\dfrac{0,4.2+0,6}{2}=0,7\left(mol\right)\)
Theo ĐLBTKL: mhh + mO2 = mCO2 + mH2O
=> mhh = 0,4.44 + 0,6.18 - 0,7.32 = 6(g)
C3:
Gọi công thức chung của hh là CxH4
PTHH: CxH4 + (x+1)O2 --to--> xCO2 + 2H2O
a------------------------>ax----->2a
=> \(\left\{{}\begin{matrix}ax=0,4\\2a=0,6\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}a=0,3\\x=\dfrac{4}{3}=>CTHH:C_{\dfrac{4}{3}}H_4\end{matrix}\right.\)
=> \(m_{hh}=0,3.20=6\left(g\right)\)