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Đặt \(n_{H_2SO_4}=a\left(mol\right)\rightarrow n_{HCl}=3a\left(mol\right)\)
\(n_{NaOH}=0,05.0,5=0,025\left(mol\right)\)
PTHH:
\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)
a--------->2a
\(HCl+NaOH\rightarrow NaCl+H_2O\)
3a----->3a
\(\rightarrow2a+3a=0,025\\ \Leftrightarrow a=0,005\left(mol\right)\\ \rightarrow\left\{{}\begin{matrix}C_{M\left(H_2SO_4\right)}=\dfrac{0,005}{0,1}=0,05M\\C_{M\left(HCl\right)}=\dfrac{0,005.3}{0,1}=0,15M\end{matrix}\right.\)
\(NaOH+HCl->NaCl+H_2O\\ 2NaOH+H_2SO_4->Na_2SO_4+2H_2O\\ a.V=\dfrac{0,1.1}{2}=0,05\left(L\right)\\ b.m_{ddH_2SO_4}=\dfrac{0,1.1.98}{2.0,1}=49\left(g\right)\)
NaOH + HCl --> NaCl+H2O (1)
2NaOH +H2SO4 --> Na2SO4 +2H2O (2)
Đặt nNaOH (1)= a(mol)
nNaOH(2) = b (mol)
=>a + b = 0,3.2 =0,6( *)
Theo PT (1) : nNaCl = nNaOH(1) = a(mol)
Theo PT (2) : nNa2SO4=12
nNaOH(2) = 0,5b(mol)
=>58,5a + 71b =40,1(**)
Từ (*), (**) => a= 0,2 ; b = 0,4
nHCl = nNaOH (1)=0,2 mol
=> x=CMHCl=0,20,2=1M
nH2SO4 = nNaOH (2)=0,4 mol
y=CMH2SO4=0,40,2=2M
a) \(m_{HCl}=200.10,95\%=21,9\left(g\right)\)
b) \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
x_______2x________x____x(mol)
\(n_{HCl}=\dfrac{200.10,95\%}{36,5}=0,6\left(mol\right)\)
Dung dịch A phải có HCl dư mới có thể trung hòa được NaOH.
\(n_{NaOH}=0,05.2=0,1\left(mol\right)\)
\(NaOH+HCl\rightarrow NaCl+H_2O\)
y________y______y(mol)
Ta có hpt:
\(\left\{{}\begin{matrix}2x+y=0,6\\y=0,1\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,25\\y=0,1\end{matrix}\right.\)
\(\Rightarrow a=m_{CaCO_3}=100x=100.0,25=25\left(g\right)\\ V=V_{CO_2\left(đktc\right)}=22,4x=22,4.0,25=5,6\left(l\right)\)
c)
\(m_{ddA}=25+200-0,25.44=214\left(g\right)\\ C\%_{ddCaCl_2}=\dfrac{0,25.111}{214}.100\approx12,967\%\\ C\%_{ddHCl\left(dư\right)}=\dfrac{0,1.36,5}{214}.100\approx1,706\%\)
Ba(OH)2+Na2CO3−−>BaCO3+2NaOH
...0.001......................................0.001...............mol
NaOH+HCl−−>NaCl+H2O
Ba(OH)2+2HCl−−>BaCl2+2H2O
....0.001............0.002................................mol
nHCl=0.1∗0.06=0.006mol
=> nNaOH=0.006−0.002=0.004mol
=> CM từng chất =......
HCl + NaOH ----> NaCl + H2O
nNaOH = 0,025 mol
nHCl = 0,1.x mol
=> x = 0,25 (M)
CM = n/V => n = CM . V = 0,5 . (50/1000) = 0,025 mol
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