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\(n_{H_2SO_4}=\dfrac{98.5\%}{98}=0,05\left(mol\right)\\ PTHH:CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ n_{CuSO_4}=n_{CuO}=n_{H_2SO_4}=0,05\left(mol\right)\\ a,m_{CuO}=0,05.80=4\left(g\right)\\ b,m_{CuSO_4}=0,05.160=8\left(g\right)\\ m_{ddCuSO_4}=98+4=102\left(g\right)\\ C\%_{ddCuSO_4}=\dfrac{8}{102}.100\approx7,843\%\)
nCuO=0.2(mol)
CuO+2HCl->CuCl2+H2O
0.2 0.4 0.2
m muối=0.2*(64+71)=27(g)
m HCl=14.6(g)
CM=0.4/0.2=2(M)
\(n_{KOH}=\dfrac{100.14}{100.56}=0,25(mol)\\ 2KOH+CuCl_2\to Cu(OH)_2\downarrow+2KCl\\ \Rightarrow n_{CuCl_2}=n_{Cu(OH)_2}=0,125(mol);n_{KCl}=0,25(mol)\\ a,m_{CuCl_2}=0,125.135=16,875(g)\\ b,m_{Cu(OH)_2}=0,125.98=12,25(g)\\ c,C\%_{KCl}=\dfrac{0,25.74,5}{100+16,875-12,25}.100\%=17,8\%\\ d,Cu(OH)_2\xrightarrow{t^o}CuO+H_2O\\ \Rightarrow n_{CuO}=0,125(mol)\\ \Rightarrow m_{CuO}=0,125.80=10(g)\)
a)
$Fe_2O_3 + 3CO \xrightarrow{t^o} 2Fe +3 CO_2$
$Fe + 2HCl \to FeCl_2 + H_2$
$RO + H_2 \xrightarrow{t^o} R + H_2O$
b)
Coi m = 160(gam)$
Suy ra: $n_{Fe_2O_3} = 1(mol)$
Theo PTHH :
$n_{RO} = n_{H_2} = n_{Fe} = 2n_{Fe_2O_3} = 2(mol)$
$M_{RO} = R + 16 = \dfrac{160}{2} = 80 \Rightarrow R = 64(Cu)$
Vậy oxit là CuO
PTHH: \(CuO+2HCl\rightarrow CuCl_2+H_2O\)
Ta có: \(n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,1\left(mol\right)\\n_{CuCl_2}=0,05\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{ddHCl}=\dfrac{0,1\cdot36,5}{7,3\%}=50\left(g\right)\\C\%_{CuCl_2}=\dfrac{0,05\cdot135}{4+50}\cdot100\%=12,5\%\end{matrix}\right.\)
a) Zn + 2HCl → ZnCl2 + H2
nZn = 9,75 : 65 = 0,15 mol
Theo ptpư
nH2 = nZn = 0,15 mol
VH2 = 0,15 . 22,4 = 3,36 lit
b) CuO + H2 →H2O + Cu
nCuO = 20 : 80 = 0,25 mol
nCuO p/ư = nH2 = 0,15 mol
=> Dư CuO
nCu thu được= nH2 = 0,15 mol
mCu= 0,15 x 64 = 9,6 gam
Ta có: \(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)
PT: \(CuO+2HCl\rightarrow CuCl_2+H_2O\)
______0,2_____0,4_____0,2 (mol)
a, \(m_{CuCl_2}=0,2.135=27\left(g\right)\)
b, \(m_{HCl}=0,4.36,5=14,6\left(g\right)\Rightarrow C\%_{HCl}=\dfrac{14,6}{300}.100\%\approx4,867\%\)
c, Ta có: m dd sau pư = 16 + 300 = 316 (g)
\(\Rightarrow C\%_{CuCl_2}=\dfrac{27}{316}.100\%\approx8,54\%\)
\(n_{HCl}=2\cdot0,1=0,2\left(mol\right)\\ PTHH:CuO+2HCl\rightarrow CuCl_2+H_2O\\ \Rightarrow n_{CuCl_2}=n_{CuO}=\dfrac{1}{2}n_{HCl}=0,1\left(mol\right)\\ \Rightarrow\left\{{}\begin{matrix}m_{CuCl_2}=0,1\cdot135=13,5\left(g\right)\\m_{CuO}=0,1\cdot80=8\left(g\right)\end{matrix}\right.\)