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a. \(Mg+2HCl\rightarrow MgCl_2+H_2\)
b. \(n_{Mg}=\dfrac{2.4}{24}=0.1mol\)
\(mct_{HCl}=\dfrac{500\times36.5}{100}=182.5g\Rightarrow n_{HCl}=\dfrac{182.5}{36.5}=5mol\)
Ta có: \(\dfrac{0.1}{1}< \dfrac{5}{2}\Rightarrow\) HCl dư
nHCl phản ứng = 0.2 mol => nHCl dư = 5 - 0.2 = 4.8 mol
mHCl dư = \(4.8\times36.5=175.2g\)
c. \(V_{H_2}=0.1\times22.4=2.24l\)
d. mdd sau phản ứng = \(2.4+500-0.1\times2=502.2g\)
\(C\%_{MgCl_2}=\dfrac{0.1\times95\times100}{502.2}=1.89\%\)
\(a) Fe + H_2SO_4 \to FeSO_4 +H_2\\ b) n_{H_2} = n_{Fe} = \dfrac{5,6}{56} = 0,1(mol)\\ V_{H_2} = 0,1.22,4 = 2,24(lít)\\ c) m_{dd\ sau\ pư} = 5,6 + 224,6 - 0,1.2 = 230(gam)\\ n_{FeSO_4} = n_{Fe} = 0,1(mol)\\ C\%_{FeSO_4} = \dfrac{0,1.152}{230}.100\% = 6,61\%\\ d) ZnO + H_2 \xrightarrow{t^o} Zn + H_2O\\ n_{ZnO} = \dfrac{32,4}{81} = 0,4 > n_{H_2} = 0,1 \to ZnO\ dư\\ n_{ZnO\ pư} = n_{H_2} = 0,1(mol)\\ m_{ZnO\ dư} = 32,4 - 0,1.81 = 24,3(gam)\)
\(n_{Zn}=\dfrac{13}{65}=0.2\left(mol\right)\)
\(n_{HCl}=\dfrac{182.5\cdot10}{100\cdot36.5}=0.5\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(0.2......0.4..........0.2........0.2\)
\(n_{HCl\left(dư\right)}=0.5-0.4=0.1\left(mol\right)\)
\(m_{HCl\left(dư\right)}=0.1\cdot36.5=3.65\left(g\right)\)
\(V_{H_2}=0.2\cdot22.4=4.48\left(l\right)\)
\(m_{\text{dung dịch sau phản ứng}}=13+182.5-0.2\cdot2=195.1\left(g\right)\)
\(C\%_{HCl\left(dư\right)}=\dfrac{3.65}{195.1}\cdot100\%=1.87\%\)
\(C\%_{ZnCl_2}=\dfrac{0.2\cdot136}{195.1}\cdot100\%=13.94\%\)
\(n_{Zn}=\dfrac{6,5}{65}=0,1mol\)
\(m_{HCl}=\dfrac{200\cdot14,6\%}{100\%}=29,2g\Rightarrow n_{HCl}=0,8mol\)
a)\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,1 0,8 0 0
0,1 0,2 0,1 0,1
0 0,6 0,1 0,1
b)Chất HCl dư và dư \(m=0,6\cdot36,5=21,9g\)
c)\(V_{H_2}=0,1\cdot22,4=2,24l\)
d)\(m_{H_2}=0,1\cdot2=0,2g\)
\(m_{ZnCl_2}=0,1\cdot136=13,6g\)
\(m_{ddZnCl_2}=6,5+200-0,2=206,3g\)
\(C\%=\dfrac{13,6}{206,3}\cdot100\%=6,59\%\)
a, ta có pt sau : Zn + 2HCl >ZnCl2 + H2 (1)
b, nHCl=\(\dfrac{200\times14,6}{100}=29,2\left(g\right)\)\(\Rightarrow n_{HCl}=\dfrac{29,2}{36,5}=0,8\left(mol\right)\)
Ta có : nZn=\(\dfrac{6,5}{65}=0,1\left(mol\right)\)
Ta có tỉ lệ số mol là : \(\dfrac{n_{Zn}}{1}< \dfrac{n_{HCl}}{2}\left(\dfrac{0,1}{1}< \dfrac{0,8}{2}\right)\)
\(\Rightarrow\) HCl dư , Zn pứ hết
Theo pt : nHClpứ = 2.nZn=2.0,1=0,2(mol)
\(\Rightarrow\)nHCl dư = nHCl bđ - nHCl pứ = 0,8 - 0,2 = 0,6 (mol)
\(\Rightarrow\)mHCl dư=0,6.36,6=21,9 (g)
c,theo pt :nH2=nZn=0,1(mol)
\(\Rightarrow\)VH2=0,1.22,4=2,24(l)
d,Các chất có trong dung dịch sau pứ là: ZnCl2 , HCl dư
mk chịu câu này
\(n_{Zn}=\dfrac{6.5}{65}=0.1\left(mol\right)\)
\(n_{HCl}=\dfrac{100\cdot14.6\%}{36.5}=0.4\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(1........2\)
\(0.1......0.4\)
\(LTL:\dfrac{0.1}{1}< \dfrac{0.4}{2}\Rightarrow HCldư\)
\(V_{H_2}=0.1\cdot22.4=2.24\left(l\right)\)
\(m_{\text{dung dịch sau phản ứng}}=6.5+100-0.1\cdot2=106.3\left(g\right)\)
\(C\%ZnCl_2=\dfrac{0.1\cdot136}{106.3}\cdot100\%=12.79\%\)
\(C\%HCl\left(dư\right)=\dfrac{\left(0.4-0.2\right)\cdot36.5}{106.3}\cdot100\%=6.87\%\%\)
a, \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
\(n_{HCl}=0,1.1=0,1\left(mol\right)\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,1}{2}\), ta được Fe dư.
Theo PT: \(n_{H_2}=\dfrac{1}{2}n_{HCl}=0,05\left(mol\right)\Rightarrow V_{H_2}=0,05.22,4=1,12\left(l\right)\)
b, Fe dư.
Theo PT: \(n_{Fe\left(pư\right)}=\dfrac{1}{2}n_{HCl}=0,05\left(mol\right)\Rightarrow n_{Fe\left(dư\right)}=0,1-0,05=0,05\left(mol\right)\)
\(\Rightarrow m_{Fe\left(dư\right)}=0,05.56=2,8\left(g\right)\)
c, \(n_{FeCl_2}=\dfrac{1}{2}n_{HCl}=0,05\left(mol\right)\Rightarrow C_{M_{HCl}}=\dfrac{0,05}{0,1}=0,5\left(M\right)\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
\(n_{HCl}=0,1.1=0,1\left(mol\right)\)
PTHH :
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
trc p/u : 0,1 0,1
p/u : 0,05 0,1 0,05 0,05
sau p/u: 0,05 0 0,05 0,05
---> sau p/ư : Fe dư
\(a,V_{H_2}=0,05.22,4=1,12\left(l\right)\)
b, \(m_{Fedư}=0,05.56=2,8\left(g\right)\)
\(c,_{FeCl_2}=0,05.127=6,35\left(g\right)\)
\(m_{ddFeCl_2}=5,6+\left(0,1.36,5\right)-\left(0,05.1\right)=9,2\left(g\right)\)
\(C\%_{FeCl_2}=\dfrac{6,35}{9,2}.100\%\approx69\%\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right);n_{HCl}=1.0,1=0,1\left(mol\right)\\ PTHH:Fe+2HCl\rightarrow FeCl_2+H_2\\ Vì:\dfrac{0,1}{2}< \dfrac{0,1}{1}\Rightarrow Fe.dư\\ n_{H_2}=n_{FeCl_2}=n_{Fe\left(p.ứ\right)}=\dfrac{0,1}{2}=0,05\left(mol\right)\\ a,V_{H_2\left(đktc\right)}=0,05.22,4=1,12\left(l\right)\\ b,n_{Fe\left(dư\right)}=0,1-0,05=0,05\left(mol\right)\\ m_{Fe\left(dư\right)}=0,05.56=2,8\left(g\right)\\ c,V_{ddFeCl_2}=V_{ddHCl}=0,1\left(l\right)\\ C_{MddFeCl_2}=\dfrac{0,05}{0,1}=0,5\left(M\right)\)
PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\n_{H_2SO_4}=\dfrac{49}{98}=0,5\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Axit còn dư
\(\Rightarrow\left\{{}\begin{matrix}n_{H_2}=0,2\left(mol\right)\\n_{H_2SO_4\left(dư\right)}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,2\cdot22,4=4,48\left(l\right)\\m_{H_2SO_4\left(dư\right)}=0,3\cdot98=29,4\left(g\right)\end{matrix}\right.\)
nH2SO4=0,5(mol)
nZn=0,2(mol)
a) PTHH: Zn + H2SO4 -> ZnSO4 + H2
ta có: 0,5/1 > 0,2/1
=> Zn hết, H2SO4 dư, tính theo nZn
b) m(H2SO4 dư)= (0,5-0,2).98=29,4(g)
c) nH2= nZn=0,2(mol)
=>V(H2,đktc)=0,2.22,4=4,48(l)
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\
n_{H_2SO_4}=\dfrac{24,5}{98}=0,25\left(mol\right)\\
pthh:Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
\(LTL:\dfrac{0,2}{1}< \dfrac{0,25}{1}\)
=> H2SO4 dư
\(n_{H_2}=n_{H_2SO_4\left(p\text{ư}\right)}=n_{Fe}=0,2\left(mol\right)\\
V_{H_2}=0,2.22,4=4,48l\\
m_{H_2SO_4\left(d\right)}=\left(0,25-0,2\right).98=4,9g\)
a, \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH: Fe + H2SO4 -----> FeSO4 + H2
b, ko tính đc do thiếu khối lượng ddH2SO4
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
nFe = 5,6 : 56 = 0,1 (mol)
nH2SO4 (đủ) = 0,1 (mol)
mH2SO4 = 0,1 . 98 = 9,8 (g)
\(mH_2SO_{\text{4(thamgiapứ) }}=\dfrac{9,8.100}{49}=20\left(g\right)\)
H2SO4 dư , Fe đủ
mH2SO4 dư = 20 - 9,8 = 10,2(g)
mFeSO4 = 0,1 . 152 = 15,2(g)
VH2 = 0,1 .22,4 = 2,24(l)
mH2 = 0,1 . 2 = 0,2 (g)
\(C\%H_2SO_4=\dfrac{10,2.100}{5,6+20+15,2-0,2}=25\%\)
\(C\%_{FeSO_4}=\dfrac{15,2.100}{5,6+20+15,2-0,2}=37\%\)