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1)
a, \(n_{Al}=\dfrac{15,3}{102}=0,15\left(mol\right)\)
PTHH: Al2O3 + 6HCl → 2AlCl3 + 3H2O
Mol: 0,15 0,9 0,3
\(m_{ddHCl}=\dfrac{0,9.36,5.100}{20}=164,25\left(g\right)\)
b, mdd sau pứ = 15,3 + 164,25 = 179,55 (g)
c, \(C\%_{ddAlCl_3}=\dfrac{0,3.133,5.100\%}{179,55}=22,31\%\)
2)
a, \(m_{HCl}=54,75.20\%=10,95\left(g\right)\Rightarrow n_{HCl}=\dfrac{10,95}{36,5}=0,3\left(mol\right)\)
PTHH: Al2O3 + 6HCl → 2AlCl3 + 3H2O
Mol: 0,05 0,3 0,1
\(m_{Al_2O_3}=0,05.102=5,1\left(g\right)\)
b, mdd sau pứ = 5,1 + 54,75 = 59,85 (g)
\(C\%_{ddAlCl_3}=\dfrac{0,1.133,5.100\%}{59,85}=22,31\%\)
$a\big)$
$n_{CH_3COOH}=\dfrac{100}{1000}.1=0,1(mol)$
$CH_3COOH+NaOH\to CH_3COONa+H_2O$
Theo PT: $n_{NaOH}=n_{CH_3COOH}=0,1(mol)$
$\to C\%_{NaOH}=\dfrac{0,1.40}{50}.100\%=80\%$
$b\big)$
$n_{Na_2CO_3}=\dfrac{10,6}{106}=0,1(mol)$
$2CH_3COOH+Na_2CO_3\to 2CH_3COONa+CO_2+H_2O$
Theo PT: $\begin{cases} n_{CO_2}=n_{Na_2CO_3}=0,1(mol)\\ n_{CH_3COONa}=2n_{Na_2CO_3}=0,2(mol) \end{cases}$
$\to C\%_{CH_3COONa}=\dfrac{0,2.82}{60+10,6-0,1.44}.100\%\approx 24,77\%$
\(nHCl=0,2.0,3=0,06\\ 2Al+6HCl=>2AlCl3+3H2\\ =>nAl=0,02\left(mol\right)\\ =>mAl=0,02.27=0,54\left(g\right)\\ tacónAlCl3=0,02\left(mol\right)\\ =>Cm\left(AlCl3\right)=\dfrac{0,02}{0,2}=0,1\left(M\right)\)
a, \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
b, \(n_{HCl}=0,2.0,3=0,06\left(mol\right)\)
Theo PT: \(n_{Al}=\dfrac{1}{3}n_{HCl}=0,02\left(mol\right)\)
\(\Rightarrow m_{Al}=0,02.27=0,54\left(g\right)\)
c, \(n_{AlCl_3}=\dfrac{1}{3}n_{HCl}=0,02\left(mol\right)\)
\(\Rightarrow C_{M_{AlCl_3}}=\dfrac{0,02}{0,2}=0,1\left(M\right)\)
\(n_{Fe_2O_3}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: Fe2O3 + 3H2SO4 --> Fe2(SO4)3 + 3H2O
______0,05------>0,15--------->0,05
=> mH2SO4 = 0,15.98 = 14,7(g)
=> \(C\%\left(H_2SO_4\right)=\dfrac{14,7}{100}.100\%=14,7\%\)
\(C\%\left(Fe_2\left(SO_4\right)_3\right)=\dfrac{0,05.400}{8+100}.100\%=18,52\%\)
PTHH: Fe2(SO4)3 + 6NaOH --> 2Fe(OH)3\(\downarrow\) + 3Na2SO4
________0,05----------------------->0,1
=> mFe(OH)3 = 0,1.107=10,7(g)
Coi
\(m_{dd\ NaOH} = 100\ gam\\ \Rightarrow n_{NaOH} = \dfrac{100.10\%}{40} = 0,25(mol)\)
CH3COOH + NaOH → CH3COONa + H2O
0,25................0,25.................0,25......................(mol)
\(m_{CH_3COONa} = 0,25.82 = 20,5(gam)\\ \Rightarrow m_{dd\ sau\ pư} = \dfrac{20,5}{10,25\%} = 200(gam)\\ \Rightarrow m_{dd\ axit\ axetic} = 200 -100 = 100(gam)\)
Vậy :
\(C\%_{CH_3COOH} = \dfrac{0,25.60}{100}.100\% = 15\%\)
\(n_{Al\left(OH\right)_3}=\dfrac{7,8}{78}=0,1mol\\ 2Al\left(OH\right)_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+6H_2O\\ 0,1................0,15.............0,05............0,3\\ C_{\%H_2SO_4}=\dfrac{0,15.98}{300}\cdot100\%=4,9\%\\ C_{\%Al_2\left(SO_4\right)_3}=\dfrac{0,05.342}{7,8+300}\cdot100\%=5,56\%\)
250ml=0,25l
\(MgO+2HCl\rightarrow MgCl_2+H_2O\)
0.2.........0.4..........0,2............0,2 (mol)
a)
\(n_{MgO}=\dfrac{8}{40}=0,2\left(mol\right)\)
\(m_{MgCl_2}=0,2.95=19\left(g\right)\)
b)
\(C_{M_{HCl}}=\dfrac{0,4}{0,25}=1,6\left(M\right)\)
a/ \(n_{MgO}=\dfrac{8}{40}=0,2\left(mol\right)\)
PTHH: MgO + 2HCl → MgCl2 + H2O
Mol: 0,2 0,4 0,2
\(m_{MgCl_2}=0,2.95=19\left(g\right)\)
b/ \(C_{M_{ddHCl}}=\dfrac{0,4}{0,25}=1,6M\)
nAl2O3= 10,2/102= 0,1(mol)
a) PTHH: Al2O3 + 6 HCl -> 2 AlCl3 + 3 H2O
0,1_______0,6_______0,2_________0,3(mol)
mHCl=0,6.36,5= 21,9(g)
=>mddHCl= (21,9.100)/7,3=300(g)
b) mddsau= mAl2O3 + mddHCl= 10,2+300=310,2(g)
c) mAlCl3= 133,5.0,2=26,7(g)
=>C%ddAlCl3= (26,7/310,2).100=8,607%
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{Al_2\left(SO_4\right)_3}=0,1\left(mol\right)\\n_{H_2}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Al_2\left(SO_4\right)_3}=0,1\cdot342=34,2\left(g\right)\\m_{H_2}=0,3\cdot2=0,6\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd\left(sau.p/ứ\right)}=m_{Al}+m_{ddH_2SO_4}-m_{H_2}=164,8\left(g\right)\)
\(\Rightarrow C\%_{Al_2\left(SO_4\right)_3}=\dfrac{34,2}{164,8}\cdot100\%\approx20,75\%\)