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a) \(n_{Al}=\dfrac{0,54}{27}=0,02\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
_____0,02->0,06---->0,02--->0,03
=> VH2 = 0,03.22,4 = 0,672 (l)
b) mHCl = 0,06.36,5 = 2,19 (g)
=> \(C\%_{ddHCl}=\dfrac{2,19}{100}.100\%=2,19\%\)
`a)`
`2Al+6HCl->2AlCl_3+3H_2`
`n_{Al}={0,54}/{27}=0,02(mol)`
`n_{H_2}=3/{2}n_{Al}=0,03(mol)`
`V_{H_2}=0,03.22,4=0,672(l)`
`b)`
`n_{HCl}=2n_{H_2}=0,06(mol)`
`C%_{HCl}={0,06.36,5}/{100}.100%=2,19%`
a, PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
b, Ta có: \(n_{Fe}=\dfrac{19,6}{56}=0,35\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Fe}=0,35\left(mol\right)\Rightarrow V_{H_2}=0,35.22,4=7,84\left(l\right)\)
c, \(n_{H_2SO_4}=n_{Fe}=0,35\left(mol\right)\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,35}{0,2}=1,75\left(M\right)\)
d, \(n_{FeSO_4}=n_{Fe}=0,35\left(mol\right)\Rightarrow m_{FeSO_4}=0,35.152=53,2\left(g\right)\)
e, \(C_{M_{FeSO_4}}=\dfrac{0,35}{0,2}=1,75\left(M\right)\)
d, \(n_{H_2SO_4}=0,25.1,6=0,4\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{n_{Fe}}{1}< \dfrac{n_{H_2SO_4}}{1}\), ta được H2SO4 dư.
Theo PT: \(n_{H_2SO_4\left(pư\right)}=n_{Fe}=0,35\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4\left(dư\right)}=0,4-0,35=0,05\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4\left(dư\right)}=0,05.98=4,9\left(g\right)\)
nFe=0,1 mol
Fe +2HCl=>FeCl2+H2
0,1 mol=>0,2 mol =>0,1 mol
VH2=0,1.22,4=2,24 lít
nHCl=0,2 mol=>mHCl=0,2.36,5=7,3g
=>C% dd HCl=7,3/200.100%=3,65%
a ,\(Zn+2HCl=>ZnCl_2+H_2\) (1)
b, \(n_{Zn}=\frac{6,5}{65}=0,1\left(mol\right)\)
theo (1) \(n_{H_2}=n_{Zn}=0,1\left(mol\right)\)
=> \(V_{H_2}=0,1.22,4=2,24\left(l\right)\)
c, Theo (1) \(n_{HCl}=2n_{Zn}=0,2\left(mol\right)\)
=> \(m_{HCl}=0,2.36,5=7,3 \left(g\right)\)
nồng độ % dung dịch axit đã dùng là
\(\frac{7,3}{200}.100\%=36,5\%\)
\(n_{Mg}=\dfrac{12}{24}=0,5\left(mol\right)\)
PT: \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
a, \(n_{H_2}=n_{Mg}=0,5\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,5.22,4=11,2\left(l\right)\)
b, \(n_{H_2SO_4}=n_{Mg}=0,5\left(mol\right)\)\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,5}{0,2}=2,5\left(M\right)\)
nAl = 5.4/27 = 0.2 (mol)
2Al + 3H2SO4 => Al2(SO4)3 + 3H2
0.2____0.3_________________0.3
VH2 = 0.3*22.4 = 6.72(l)
CM H2SO4 = 0.3/0.1 = 3 M
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(\Rightarrow n_{H_2}=0,3mol=n_{H_2SO_4}\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\\C_{M_{H_2SO_4}}=\dfrac{0,3}{0,1}=3\left(M\right)\end{matrix}\right.\)
PTHH: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
\(H_2+\dfrac{1}{2}O_2\xrightarrow[]{t^o}H_2O\)
Ta có: \(n_{H_2}=\dfrac{0,896}{22,4}=0,04\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{Fe}=0,04\left(mol\right)=n_{H_2SO_4}\\n_{O_2}=0,02\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,04\cdot56=2,24\left(g\right)\\C_{M_{H_2SO_4}}=\dfrac{0,04}{0,5}=0,08\left(M\right)\\V_{O_2}=0,02\cdot22,4=0,448\left(l\right)\end{matrix}\right.\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PT: \(Fe+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Fe+H_2\)
a, Theo PT: \(n_{CH_3COOH}=2n_{Fe}=0,2\left(mol\right)\Rightarrow m_{CH_3COOH}=0,2.60=12\left(g\right)\)
\(\Rightarrow m_{ddCH_3COOH}=\dfrac{12}{10\%}=120\left(g\right)\)
\(n_{H_2}=n_{Fe}=0,1\left(mol\right)\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, Theo PT: \(n_{\left(CH_3COO\right)_2Fe}=n_{Fe}=0,1\left(mol\right)\)
Ta có: m dd sau pư = 5,6 + 120 - 0,1.2 = 125,4 (g)
\(\Rightarrow C\%_{\left(CH_3COO\right)_2Fe}=\dfrac{0,1.174}{125,4}.100\%\approx13,88\%\)
a)
$n_{Al} = 0,3(mol)$
$2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$
Theo PTHH :
$n_{H_2SO_4} = \dfrac{3}{2}n_{Al} = 0,45(mol)$
$m_{dd\ H_2SO_4} = \dfrac{0,45.98}{12,25\%} = 360(gam)$
b)
$n_{H_2} = n_{H_2SO_4} = 0,45(mol)$
$V_{H_2} = 0,45.22,4 = 10,08(lít)$
c)
$n_{Al_2(SO_4)_3} = 0,15(mol)$
$m_{dd\ sau\ pư} = 8,1 + 360 - 0,45.2 = 367,2(gam)$
$C\%_{Al_2(SO_4)_3} = \dfrac{0,15.342}{367,2}.100\% = 14\%$
hình như sai đề