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a.\(n_{hh}=\dfrac{13,44}{22,4}=0,6mol\)
\(n_{C_2H_2Br_4}=\dfrac{6,72}{22,4}=0,3mol\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
0,3 0,3 ( mol )
\(\%C_2H_2=\dfrac{0,3}{0,6}.100=50\%\)
\(\%CH_4=100\%-50\%=50\%\)
b.
\(CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\)
0,3 0,6 ( mol )
\(2C_2H_2+5O_2\rightarrow\left(t^o\right)4CO_2+2H_2O\)
0,3 0,75 ( mol )
\(V_{O_2}=\left(0,6+0,75\right).22,4=1,35.22,4=30,24l\)
PTHH: \(CH_4+2O_2\xrightarrow[]{t^o}CO_2+2H_2O\)
Ta có: \(n_{CO_2}=\dfrac{1,68}{22,4}=0,075\left(mol\right)=n_{CH_4}\)
Đặt \(\left\{{}\begin{matrix}n_{C_2H_4}=a\left(mol\right)\\n_{C_2H_2}=b\left(mol\right)\end{matrix}\right.\) \(\Rightarrow a+b=\dfrac{5,04}{22,4}-0,075=0,15\) (1)
PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
Theo PTHH: \(28a+26b=4,1\) (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}a=n_{C_2H_4}=0,1\left(mol\right)\\b=n_{C_2H_2}=0,05\left(mol\right)\end{matrix}\right.\)
Mặt khác: \(n_{hh}=\dfrac{5,04}{22,4}=0,225\left(mol\right)\) \(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,075}{0,225}\cdot100\%\approx33,33\%\\\%V_{C_2H_4}=\dfrac{0,1}{0,225}\cdot100\%\approx44,44\%\\\%V_{C_2H_2}=22,23\%\end{matrix}\right.\)
\(n_{Br_2}=\dfrac{8}{160}=0,05mol\)
\(n_{hh}=\dfrac{5,6}{22,4}=0,25mol\)
\(C_2H_4+Br_2\rightarrow C_2H_2Br_4\)
0,05 0,05 ( mol )
\(\%V_{C_2H_4}=\dfrac{0,05}{0,25}.100=20\%\)
\(\%V_{CH_4}=100\%-20\%=80\%\)
\(CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\)
0,2 0,4 ( mol )
\(C_2H_4+5O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\)
0,05 0,25 ( mol )
\(V_{kk}=V_{O_2}.5=\left(0,4+0,25\right).22,4.5=14,56.5=72,8l\)
a) \(n_{Br_2\left(p\text{ư}\right)}=\dfrac{6,4}{160}=0,04\left(mol\right);n_{hh}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,04<--0,04
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,04}{0,6}.100\%=6,67\%\\\%V_{CH_4}=100\%-6,67\%=93,33\%\end{matrix}\right.\)
b) \(n_{CH_4}=0,6-0,04=0,56\left(mol\right)\)
PTHH: \(CH_4+2O_2\xrightarrow[]{t^o}CO_2+2H_2O\)
0,56----------->0,56
\(C_2H_4+3O_2\xrightarrow[]{t^o}2CO_2+2H_2O\)
0,04----------->0,08
\(\Rightarrow V_{CO_2}=\left(0,08+0,56\right).22,4=14,336\left(l\right)\)
a)
$CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O$
$C_2H_4 + 3O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O$
$CO_2 + Ba(OH)_2 \to BaCO_3 + H_2O$
b)
Gọi $n_{CH_4} = a(mol) ; n_{C_2H_4} = b(mol)$
$\Rightarorw a + b = \dfrac{1,68}{22,4} = 0,075(1)$
Theo PTHH : $n_{BaCO_3} = n_{CO_2} = a + 2b = \dfrac{19,7}{197} = 0,1(2)$
Từ (1)(2) suy ra : a = 0,05 ; b = 0,025
$\%V_{CH_4} = \dfrac{0,05}{0,075}.100\% = 66,67\%$
$\%V_{C_2H_4} = 100\% - 66,67\% = 33,33\%$
c) $n_{O_2} = 2n_{CH_4} + 3n_{C_2H_4} = 0,175(mol)$
$\Rightarrow V_{O_2} = 0,175.22,4 = 3,92(lít)$
$\Rightarrow V_{kk} = 5V_{O_2} = 19,6(lít)$
C2H4+Br2->C2H4Br2
0,05----0,05
n Br2=\(\dfrac{8}{160}\)=0,05 mol
=>%VC2H4=\(\dfrac{0,05.22,4}{5,6}.100=20\%\)
=>%VCH4=80%
c)CH4+2O2-to>CO2+2H2O
1.10-3----2.10-3 mol
C2H4+3O2-to>2CO2+2H2O
2,5.10-4-7,5.10-4 mol
n hh=\(\dfrac{0,028}{22,4}\)=1,25.10-3 mol
=>n C2H4=2,5.10-4 mol
=>n CH4=1.10-3 mol
=>VO2=(2.10-3+7,5.10-4).22,4=0,0616l
\(n_{Br_2}=\dfrac{8}{160}=0,05mol\)
\(\Rightarrow n_{etilen}=n_{Br_2}=0,05mol\)
\(n_{hh}=\dfrac{5,6}{22,4}=0,25mol\)
\(\Rightarrow n_{metan}=n_{hh}-n_{etilen}=0,25-0,05=0,2mol\)
a)\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
b)\(\%V_{metan}=\dfrac{0,2}{0,25}\cdot100\%=80\%\)
\(\%V_{etilen}=100\%-80\%=20\%\)
\(a) C_2H_4 + Br_2 \to C_2H_4Br_2\\ n_{C_2H_4} = n_{Br_2} = \dfrac{48}{160} = 0,3(mol)\\ \%V_{C_2H_4} = \dfrac{0,3.22,4}{8,96}.100\% = 75\%\\ \%V_{CH_4} = 100\% -75\% = 25\%\\ b)\)
Khí còn lại : CH4
\(CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + H_2O\\ n_{CO_2} = n_{CH_4} = \dfrac{8,96.25\%}{22,4} = 0,1(mol)\\ m_{CO_2} = 0,1.44 = 4,4(gam)\)
a) PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
Ta có: \(n_{C_2H_4}=\dfrac{5,6}{28}=0,2\left(mol\right)=n_{C_2H_4Br_2}\) \(\Rightarrow m_{C_2H_4Br_2}=0,2\cdot188=37,6\left(g\right)\)
b) Ta có: \(n_{CH_4}=\dfrac{11,2}{22,4}-0,2=0,3\left(mol\right)\)
Bảo toàn nguyên tố: \(n_{CO_2}=n_{CH_4}+2n_{C_2H_4}=0,7\left(mol\right)\)
\(\Rightarrow V_{CO_2}=0,7\cdot22,4=15,68\left(l\right)\)
a, PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
Khí thoát ra khỏi bình là CH4 (metan).
b, Ta có: \(\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{1,12}{5,6}.100\%=20\%\\\%V_{C_2H_4}=100-20=80\%\end{matrix}\right.\)
c, Ta có: \(V_{C_2H_4}=5,6.80\%=4,48\left(l\right)\)
\(\Rightarrow n_{C_2H_4}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Theo PT: \(n_{Br_2}=n_{C_2H_4}=0,2\left(mol\right)\)
\(\Rightarrow m_{Br_2}=0,2.160=32\left(g\right)\)
Bạn tham khảo nhé!
\(CH_2=CH_2+Br_2\rightarrow CH_2Br-CH_2Br\)
\(n_{hh}=\dfrac{3.36}{22.4}=0.15\left(mol\right)\)
\(V_{CH_4}=2.24\left(l\right)\)
\(n_{CH_4}=\dfrac{2.24}{22.4}=0.1\left(mol\right)\)
\(\Rightarrow n_{C_2H_4}=0.15-0.1=0.05\left(mol\right)\)
\(\%CH_4=\dfrac{0.1}{0.15}\cdot100\%=66.67\%\)
\(\%C_2H_4=33.33\%\)
\(CH_4+2O_2\underrightarrow{^{t^0}}CO_2+2H_2O\)
\(C_2H_4+3O_2\underrightarrow{^{t^0}}2CO_2+2H_2O\)
\(n_{O_2}=0.1\cdot2+0.05\cdot3=0.35\left(mol\right)\)
\(V_{kk}=5V_{O_2}=5\cdot0.35\cdot22.4=39.2\left(l\right)\)