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a, Ta có: \(n_{CaCO_3}=\dfrac{300}{100}=3\left(mol\right)\)
\(m_{HCl}=400.7,3\%=29,2\left(g\right)\Rightarrow n_{HCl}=\dfrac{29,2}{36,5}=0,8\left(mol\right)\)
PT: \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
Xét tỉ lệ: \(\dfrac{3}{1}>\dfrac{0,8}{2}\), ta được CaCO3 dư.
Theo PT: \(n_{CO_2}=\dfrac{1}{2}n_{HCl}=0,4\left(mol\right)\Rightarrow V_{H_2}=0,4.22,4=8,96\left(l\right)\)
b, Theo PT: \(n_{CaCO_3\left(pư\right)}=n_{CaCl_2}=\dfrac{1}{2}n_{HCl}=0,4\left(mol\right)\)
Ta có: m dd sau pư = 0,4.100 + 400 - 0,4.44 = 422,4 (g)
\(\Rightarrow C\%_{CaCl_2}=\dfrac{0,4.111}{422,4}.100\%\approx10,51\%\)
a, \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Theo PT: \(n_{H_2}=n_{FeCl_2}=n_{Fe}=0,2\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
b, \(m_{FeCl_2}=0,2.127=25,4\left(g\right)\)
c, \(n_{HCl}=2n_{H_2}=0,4\left(mol\right)\Rightarrow C_{M_{HCl}}=\dfrac{0,4}{0,3}=\dfrac{4}{3}\left(M\right)\)
\(C_{M_{FeCl_2}}=\dfrac{0,2}{0,3}=\dfrac{2}{3}\left(M\right)\)
a, \(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)
\(m_{HCl}=200.14,6\%=29,2\left(g\right)\Rightarrow n_{HCl}=\dfrac{29,2}{36,5}=0,8\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Xét tỉ lệ: \(\dfrac{0,3}{1}< \dfrac{0,8}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,3\left(mol\right)\Rightarrow V_{H_2}=0,3.22,4=6,72\left(l\right)\)
b, \(n_{ZnCl_2}=n_{Zn}=0,3\left(mol\right)\Rightarrow m_{ZnCl_2}=0,3.136=40,8\left(g\right)\)
c, \(n_{HCl\left(pư\right)}=2n_{Zn}=0,6\left(mol\right)\Rightarrow n_{HCl\left(dư\right)}=0,2\left(mol\right)\)
Ta có: m dd sau pư = 19,5 + 200 - 0,3.2 = 218,9 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{HCl}=\dfrac{0,2.36,5}{218,9}.100\%\approx3,33\%\\C\%_{ZnCl_2}=\dfrac{40,8}{218,9}.100\%\approx18,64\%\end{matrix}\right.\)
\(a)n_{Zn}=\dfrac{19,5}{65}=0,3mol\\ n_{HCl}=\dfrac{200.14,6}{100.36,5}=0,8mol\\ Zn+2HCl\rightarrow ZnCl_2+H_2\\ \Rightarrow\dfrac{0,3}{1}< \dfrac{0,8}{2}\Rightarrow HCl.dư\\ n_{H_2}=n_{ZnCl_2}=n_{Zn}=0,3mol\\ V_{H_2}=0,3.22,4=6,72l\\ b)m_{ZnCl_2}=0,3.136=40,8g\\ c)n_{HCl.pư}=0,3.2=0,6mol\\ C_{\%ZnCl_2}=\dfrac{40,8}{200+19,5-0,3.2}\cdot100=18,64\%\\ C_{\%HCl.dư}=\dfrac{\left(0,8-0,6\right).36,5}{200+19,5-0,3.2}\cdot100=3,33\%\)
a) $n_{CaCO_3} = 0,15(mol)$
$CaCO_3 + 2HCl \to CaCl_2 + CO_2 + H_2O$
$n_{HCl} = 2n_{CaCO_3} = 0,3(mol)$
$m_{dd\ HCl} = \dfrac{0,3.36,5}{7,3\%} = 150(gam)$
b)
$n_{CaCl_2} = n_{CO_2} = n_{CaCO_3} =0,15(mol)$
$V_{CO_2} = 0,15.22,4 = 3,36(lít)$
c)
$m_{dd} = 15 + 150 - 0,15.44 = 158,4(gam)$
$C\%_{CaCl_2} = \dfrac{0,15.111}{158,4}.100\% = 10,51\%$
Ta có: \(n_{Na_2SO_3}=\dfrac{12,6}{126}=0,1\left(mol\right)\)
a. PTHH: Na2SO3 + 2HCl ---> 2NaCl + SO2 + H2O
Theo PT: \(n_{SO_2}=n_{Na_2CO_3}=0,1\left(mol\right)\)
=> \(V_{SO_2}=0,1.22,4=2,24\left(lít\right)\)
b. Theo PT: \(n_{HCl}=2.n_{SO_2}=2.0,1=0,2\left(mol\right)\)
=> \(m_{HCl}=0,2.36,5=7,3\left(g\right)\)
=> \(C_{\%_{HCl}}=\dfrac{7,3}{150}.100\%=4,87\%\)
c. Ta có: \(m_{dd_{NaCl}}=n_{Na_2SO_{3_{PỨ}}}=50\left(g\right)\)
Theo PT: \(n_{NaCl}=n_{HCl}=0,2\left(mol\right)\)
=> \(m_{NaCl}=0,2.58,5=11,7\left(g\right)\)
=> \(C_{\%_{NaCl}}=\dfrac{11,7}{50}.100\%=23,4\%\)
`n_[Na_2 CO_3]=[2,76]/106=0,03(mol)`
`Na_2 CO_3 +2CH_3 COOH->2CH_3 COONa+H_2 O+CO_2\uparrow`
`0,03` `0,06` `0,03` `(mol)`
`CO_2 +Ca(OH)_2 ->CaCO_3 \downarrow+H_2 O`
`0,03` `0,03`
`a)CH_3 COONa` là muối natri axetat.
`V_[dd CH_3 COOH]=[0,06]/[0,2]=0,3(l)`
`b)m_[CaCO_3]=0,03.100=3(g)`
a, CH3COONa: Natri axetat
PT: \(Na_2CO_3+2CH_3COOH\rightarrow2CH_3COONa+CO_2+H_2O\)
Ta có: \(n_{Na_2CO_3}=\dfrac{2,76}{106}=0,026\left(mol\right)\)
Theo PT: \(n_{CH_3COOH}=2n_{Na_2CO_3}=0,052\left(mol\right)\Rightarrow V_{CH_3COOH}=\dfrac{0,052}{0,2}=0,26\left(l\right)\)
b, \(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_{3\downarrow}+H_2O\)
Theo PT: \(n_{CaCO_3}=n_{CO_2}=n_{Na_2CO_3}=0,026\left(mol\right)\)
\(\Rightarrow m_{CaCO_3}=0,026.100=2,6\left(g\right)\)
a) \(n_{MgCO_3}=\dfrac{16,8}{84}=0,2\left(mol\right)\)
PTHH: MgCO3 + 2HCl ---> MgCl2 + CO2 + H2O
0,2--------------------->0,2----->0,2
=> \(m=m_{MgCl_2}=0,2.95=19\left(g\right)\)
\(m_{\text{dd}.sau.p\text{ư}}=150+16,8-0,2.44=158\left(g\right)\)
=> \(C\%_{MgCl_2}=\dfrac{19}{158}.100\%=12,025\%\)
b) CO2 + Ca(OH)2 ---> CaCO3 + H2O
0,2----->0,2------------>0,2
=> \(\left\{{}\begin{matrix}m_{kt}=m_{CaCO_3}=0,2.100=20\left(g\right)\\V_{\text{dd}Ca\left(OH\right)_2}=\dfrac{0,2}{3}=\dfrac{1}{15}\left(l\right)\end{matrix}\right.\)
\(a,n_{CaCO_3}=\dfrac{300}{100}=3mol\\ n_{HCl}=\dfrac{400.7,3}{100.36,5}=0,8mol\\ CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\\ \Rightarrow\dfrac{3}{1}>\dfrac{0,8}{2}\Rightarrow CaCO_3dư\\ n_{CaCl_2}=n_{CaCO_3}=n_{CO_2}=\dfrac{1}{2}\cdot0,8=0,4mol\\ m_{dd}=0,4.100+400-0,4.44=422,4g\\ C_{\%CaCl_2}=\dfrac{0,4.111}{422,4}\cdot100=10,51\%\)
\(c)n_{KOH}=\dfrac{200.11,2}{100.56}=0,4mol\\ T=\dfrac{0,4}{0,4}=1\\ \Rightarrow Tạo.KHCO_3\\ CO_2+KOH\rightarrow KHCO_3\\ n_{KHCO_3}=n_{CO_2}=0,4mol\\ m_{KHCO_3}=0,4.100=40g\)