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a)
$BaCl_2 + Na_2SO_4 \to BaSO_4 + 2NaCl$
$n_{BaCl_2} = 0,01 = n_{Na_2SO_4} = 0,01 \Rightarrow $ Vừa đủ
$n_{BaSO_4} = n_{Na_2SO_4} = 0,01(mol)$
$m_{BaSO_4} = 0,01.233 = 0,233(gam)$
b)
$n_{NaCl} = 2n_{Na_2SO_4} = 0,02(mol)$
$V_{dd} = 0,1 + 0,2 = 0,3(lít)$
$C_{M_{NaCl}} = \dfrac{0,02}{0,3} = 0,067M$
c)
$[Na^+] = [Cl^-] = C_{M_{NaCl}} = 0,067M$
\(n_{BaCl_2}=0.1\cdot0.1=0.01\left(mol\right)\)
\(n_{Na_2SO_4}=0.2\cdot0.05=0.01\left(mol\right)\)
\(BaCl_2+Na_2SO_4\rightarrow BaSO_4+2NaCl\)
\(0.01..........0.01............0.01..............0.02\)
\(m_{BaSO_4}=0.01\cdot233=2.33\left(g\right)\)
\(C_{M_{NaCl}}=\dfrac{0.01}{0.1+0.2}=0.03\left(M\right)\)
\(\left[Na^+\right]=\left[Cl^-\right]=0.03\left(M\right)\)
$n_{BaCl_2} = \dfrac{41,6}{208} = 0,2(mol)$
$C_{M_{BaCl_2}} = 0,2 : 0,5 = 0,4M$
$BaCl_2 \to Ba^{2+} + 2Cl^-$
$[Ba^{2+}] = 0,4M ; [Cl^-] = 0,4.2 = 0,8M$
a) Ta có: \(n_{NaCl}=\dfrac{5,85}{58,5}=0,1\left(mol\right)\)
\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,1}{0,5}=0,2\left(M\right)=\left[Na^+\right]=\left[Cl^-\right]\)
b) Ta có: \(n_{Ba\left(OH\right)_2}=\dfrac{34,2}{171}=0,2\left(mol\right)\)
\(\Rightarrow C_{M_{Ba\left(OH\right)_2}}=\dfrac{0,2}{0,5}=0,4\left(M\right)\) \(\Rightarrow\left\{{}\begin{matrix}\left[Ba^{2+}\right]=0,4\left(M\right)\\\left[OH^-\right]=0,8\left(M\right)\end{matrix}\right.\)
c) Ta có: \(n_{H_2SO_4}=0,025\cdot2=0,05\left(mol\right)\)
\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,05}{0,125+0,025}\approx0,33\left(M\right)\) \(\Rightarrow\left\{{}\begin{matrix}\left[H^+\right]=0,66\left(M\right)\\\left[SO_4^{2-}\right]=0,33\left(M\right)\end{matrix}\right.\)
\(n_{K_2SO_4}=\dfrac{1,74}{174}=0,01\left(mol\right)\)
\(\Rightarrow C_{M\left(K_2SO_4\right)}=\dfrac{0,01}{0,4}=0,025M\)
Phương trình điện li: \(K_2SO_4\rightarrow2K^++SO_4^{2-}\)
\(\Rightarrow\left[K^+\right]=2C_{M\left(K_2SO_4\right)}=0,05M\)
\(\left[SO_4^{2+}\right]=C_{M\left(K_2SO_4\right)}=0,025M\)