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\(\begin{array}{l} n_{H_2}=\dfrac{6,72}{22,4}=0,3\ (mol)\\ PTHH:\\ 2Al+6HCl\to 2AlCl_3+3H_2\uparrow\ (1)\\ Al_2O_3+6HCl\to 2AlCl_3+3H_2O\ (2)\\ Theo\ pt\ (1):\ n_{Al}=\dfrac{2}{3}n_{H_2}=0,2\ (mol)\\ \Rightarrow m_{Al}=0,2\times 27=5,4\ (g).\\ \Rightarrow m_{Al_2O_3}=15,6-5,4=10,2\ (g)\\ \Rightarrow n_{Al_2O_3}=\dfrac{10,2}{102}=0,1\ (mol)\\ \Rightarrow \sum n_{AlCl_3}=n_{Al}+2n_{Al_2O_3}=0,2+2\times 0,1=0,4\ (mol)\\ \Rightarrow m_{AlCl_3}=0,4\times 133,5=53,4\ (g)\end{array}\)
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH: Mg + 2HCl --> MgCl2 + H2
___________________0,3<----0,3____(mol)
=> mMgCl2 = 0,3.95 = 28,5 (g)
Ta có: \(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
a, \(n_{Al}=\dfrac{2}{3}n_{H_2}=\dfrac{1}{6}\left(mol\right)\Rightarrow m_{Al}=\dfrac{1}{6}.27=4,5\left(g\right)\)
b, \(n_{H_2SO_4}=n_{H_2}=0,25\left(mol\right)\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,25}{0,2}=1,25\left(M\right)\)
c, \(n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{3}n_{H_2}=\dfrac{1}{12}\left(mol\right)\)
\(\Rightarrow m_{Al_2\left(SO_4\right)_3}=\dfrac{1}{12}.342=28,5\left(g\right)\)
Sửa đề: 3,785 (l) → 3,7185 (l)
a, \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)
b, Ta có: \(n_{H_2}=\dfrac{3,7185}{24,79}=0,15\left(mol\right)\)
Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,1.27}{40}.100\%=6,75\%\\\%m_{Al_2O_3}=93,25\%\end{matrix}\right.\)
c, \(n_{Al_2O_3}=\dfrac{40.93,25\%}{102}=\dfrac{373}{1020}\left(mol\right)\)
Theo PT: \(n_{HCl}=3n_{Al}+6n_{Al_2O_3}=\dfrac{212}{85}\left(mol\right)\)
\(\Rightarrow V_{HCl}=\dfrac{\dfrac{212}{85}}{2}=\dfrac{106}{85}\left(l\right)\approx1247,06\left(ml\right)\)
d, \(n_{AlCl_3}=n_{Al}+2n_{Al_2O_3}=\dfrac{212}{255}\left(mol\right)\)
\(\Rightarrow m_{AlCl_3}=\dfrac{212}{255}.133,5=\dfrac{9434}{85}\left(g\right)\)
e, \(C_{M_{AlCl_3}}=\dfrac{\dfrac{212}{255}}{\dfrac{106}{85}}=\dfrac{2}{3}\left(M\right)\)
a, \(Na_2SO_3+H_2SO_4\rightarrow Na_2SO_4+SO_2+H_2O\)
\(K_2SO_3+H_2SO_4\rightarrow K_2SO_4+SO_2+H_2O\)
Ta có: \(n_{SO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{SO_2}=0,3\left(mol\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,3.98}{20\%}=147\left(g\right)\)
b, Ta có: 126nNa2SO3 + 158nK2SO3 = 44,2 (1)
Theo PT: \(n_{SO_2}=n_{Na_2SO_3}+n_{K_2SO_3}=0,3\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Na_2SO_3}=0,1\left(mol\right)\\n_{K_2SO_3}=0,2\left(mol\right)\end{matrix}\right.\)
Có: m dd sau pư = 44,2 + 147 - 0,3.64 = 172 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{Na_2SO_3}=\dfrac{0,1.126}{172}.100\%\approx7,33\%\\C\%_{K_2SO_3}=\dfrac{0,2.158}{172}.100\%\approx18,37\%\end{matrix}\right.\)
c, \(n_{Ba\left(OH\right)_2}=0,5.1=0,5\left(mol\right)\)
\(\Rightarrow\dfrac{n_{SO_2}}{n_{Ba\left(OH\right)_2}}=0,6< 1\) → Pư tạo BaSO3.
PT: \(SO_2+Ba\left(OH\right)_2\rightarrow BaSO_3+H_2O\)
\(n_{BaSO_3}=n_{SO_2}=0,3\left(mol\right)\Rightarrow m_{BaSO_3}=0,3.217=65,1\left(g\right)\)
\(n_{H2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Pt : \(2Al+6HCl\rightarrow2AlCl_3+3H_2|\)
2 6 2 3
0,2 0,2 0,3
\(Al_2O_2+6HCl\rightarrow2AlCl_3+3H_2|\)
1 6 2 3
0,2 0,4
a) \(n_{Al}=\dfrac{0,3.2}{3}=0,2\left(mol\right)\)
\(m_{Al}=0,2.27=5,4\left(g\right)\)
\(m_{Al2O3}=25,8-5,4=20,4\left(g\right)\)
b) Có : \(m_{Al2O3}=20,4\left(g\right)\)
\(n_{Al2O3}=\dfrac{20,4}{102}=0,2\left(mol\right)\)
\(n_{AlCl3\left(tổng\right)}=0,2+0,4=0,6\left(mol\right)\)
⇒ \(m_{AlCl3}=0,6.133,5=80,1\left(g\right)\)
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