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\(a,n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\\ n_{O_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
PTHH: 4Al + 3O2 --to--> 2Al2O3
b, LTL: \(\dfrac{0,4}{4}>\dfrac{0,6}{3}\) => O2 dư
Theo pthh: \(\left\{{}\begin{matrix}n_{O_2\left(pư\right)}=\dfrac{3}{4}n_{Al}=\dfrac{3}{4}.0,4=0,3\left(mol\right)\\n_{Al_2O_3}=\dfrac{1}{2}n_{Al}=\dfrac{1}{2}.0,4=0,2\left(mol\right)\end{matrix}\right.\)
=> VO2 (dư) = (0,6 - 0,3).22,4 = 6,72 (l)
c, mAl2O3 = 0,2.102 = 20,4 (g)
\(n_{Al}=\dfrac{10,8}{27}=0,4mol\)
\(n_{O_2}=\dfrac{13,44}{22,4}=0,6mol\)
\(4Al+3O_2\rightarrow\left(t^o\right)2Al_2O_3\)
Xét: \(\dfrac{0,4}{4}\) < \(\dfrac{0,6}{3}\) ( mol )
0,4 0,3 0,2 ( mol )
Chất dư là O2
\(m_{O_2\left(dư\right)}=\left(0,6-0,3\right).32=9,6g\)
\(m_{Al_2O_3}=0,2.102=20,4g\)
Nếu có thể thì lần sau bạn nên đăng tách từng bài ra nhé!
Bài 1:
PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
Ta có: \(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\)
\(n_{HCl}=\dfrac{3,65}{36,5}=0,1\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,1}{2}\) , ta được Mg dư.
Theo PT: \(n_{Mg\left(pư\right)}=n_{MgCl_2}=n_{H_2}=\dfrac{1}{2}n_{HCl}=0,05\left(mol\right)\)
\(\Rightarrow n_{Mg\left(dư\right)}=0,1-0,05=0,05\left(mol\right)\)
\(\Rightarrow m_{Mg\left(dư\right)}=0,05.24=1,2\left(g\right)\)
\(m_{MgCl_2}=0,05.95=4,75\left(g\right)\)
\(V_{H_2}=0,05.22,4=1,12\left(l\right)\)
Bài 2:
PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{14,7}{98}=0,15\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,2}{2}>\dfrac{0,15}{3}\) , ta được Al dư.
Theo PT: \(\left\{{}\begin{matrix}n_{Al\left(pư\right)}=\dfrac{2}{3}n_{H_2SO_4}=0,1\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{3}n_{H_2SO_4}=0,05\left(mol\right)\\n_{H_2}=n_{H_2SO_4}=0,15\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{Al\left(dư\right)}=0,2-0,1=0,1\left(mol\right)\)
\(\Rightarrow m_{Al\left(dư\right)}=0,1.27=2,7\left(g\right)\)
\(m_{Al_2\left(SO_4\right)_3}=0,05.342=17,1\left(g\right)\)
\(V_{H_2}=0,15.22,4=3,36\left(l\right)\)
Bài 3:
PT: \(2M+6HCl\rightarrow2MCl_3+3H_2\)
Ta có: \(n_{H_2}=\dfrac{4,704}{22,4}=0,21\left(mol\right)\)
Theo PT: \(n_M=\dfrac{2}{3}n_{H_2}=0,14\left(mol\right)\)
\(\Rightarrow M_M=\dfrac{3,78}{0,14}=27\left(g/mol\right)\)
Vậy: M là nhôm (Al).
Bài 4:
PT: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{KMnO_4}=0,2\left(mol\right)\)
PT: \(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
Ta có: \(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,2}{4}>\dfrac{0,2}{5}\) , ta được P dư.
Theo PT: \(n_{P_2O_5}=\dfrac{2}{5}n_{O_2}=0,08\left(mol\right)\)
\(\Rightarrow m_{P_2O_5}=0,08.142=11,36\left(g\right)\)
Bạn tham khảo nhé!
Câu 8:
Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PT: \(2H_2+O_2\underrightarrow{t^o}2H_2O\)
Xét tỉ lệ: \(\dfrac{0,1}{2}< \dfrac{0,2}{1}\), ta được O2 dư.
Theo PT: \(\left\{{}\begin{matrix}n_{O_2\left(pư\right)}=\dfrac{1}{2}n_{H_2}=0,05\left(mol\right)\\n_{H_2O}=n_{H_2}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{O_2\left(dư\right)}=0,15\left(mol\right)\)
\(\Rightarrow V_{O_2\left(dư\right)}=0,15.22,4=3,36\left(l\right)\)
\(m_{H_2O}=0,1.18=1,8\left(g\right)\)
Bạn tham khảo nhé!
Câu 9:
a, PT: \(2R+O_2\underrightarrow{t^o}2RO\)
Theo ĐLBT KL, có: mR + mO2 = mRO
⇒ mO2 = 4,8 (g)
\(\Rightarrow n_{O_2}=\dfrac{4,8}{32}=0,15\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,15.22,4=3,36\left(l\right)\)
b, Theo PT: \(n_R=2n_{O_2}=0,3\left(mol\right)\)
\(\Rightarrow M_R=\dfrac{19,2}{0,3}=64\left(g/mol\right)\)
Vậy: M là đồng (Cu).
Câu 10:
Ta có: mBaCl2 = 200.15% = 30 (g)
a, m dd = 200 + 100 = 300 (g)
\(\Rightarrow C\%_{BaCl_2}=\dfrac{30}{300}.100\%=10\%\)
⇒ Nồng độ dung dịch giảm 5%
b, Ta có: \(C\%_{BaCl_2}=\dfrac{30}{150}.100\%=20\%\)
⇒ Nồng độ dung dịch tăng 5%.
Bạn tham khảo nhé!
a. \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
\(n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH : 2Mg + O2 -> 2MgO
0,2 0,1 0,2
Xét tỉ lệ : \(\dfrac{0,2}{2}< \dfrac{0,3}{1}\) => Mg đủ , O2 dư
\(m_{O_2\left(dư\right)}=\left(0,3-0,1\right).32=6,4\left(g\right)\)
b) \(m_{MgO}=0,2.40=8\left(g\right)\)
PTHH: \(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
a) Ta có: \(n_P=\dfrac{3,1}{31}=0,1\left(mol\right)\)
\(\Rightarrow n_{P_2O_5}=0,05\left(mol\right)\) \(\Rightarrow m_{P_2O_5}=0,05\cdot142=7,1\left(g\right)\)
b) Ta có: \(n_{O_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,1}{4}< \dfrac{0,25}{5}\) \(\Rightarrow\) Photpho p/ứ hết, Oxi còn dư
\(\Rightarrow n_{O_2\left(dư\right)}=0,25-0,125=0,125\left(mol\right)\)
\(\Rightarrow m_{O_2\left(dư\right)}=0,125\cdot32=4\left(g\right)\)
\(a) n_P = \dfrac{3,1}{31} = 0,1(mol)\\ 4P + 5O_2 \xrightarrow{t^o} 2P_2O_5\\ n_{P_2O_5} = \dfrac{1}{2}n_P = 0,05(mol)\\ m_{P_2O_5} = 0,05.142 = 7,1(gam)\\ b) n_{O_2} = \dfrac{5,6}{22,4} = 0,25(mol)\\ \dfrac{n_P}{4} = 0,025<\dfrac{n_{O_2}}{5} = 0,05 \to O_2\ dư\\ n_{O_2\ pư} = \dfrac{5}{4}n_P = 0,125(mol) \Rightarrow m_{O_2\ dư} = (0,25 - 0,125).32 = 4(gam)\)
Bài 2:
\(n_{Zn}=\dfrac{15,6}{65}=0,24\left(mol\right);n_{H_2SO_4}=\dfrac{39,2}{98}=0,4\left(mol\right)\\ Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ a,Vì:\dfrac{0,4}{1}>\dfrac{0,24}{1}\Rightarrow H_2SO_4dư\\ n_{H_2\left(LT\right)}=n_{H_2SO_4\left(p.ứ\right)}=n_{Zn}=0,24\left(mol\right)\\ a,n_{H_2\left(TT\right)}=50\%.0,24=0,12\left(mol\right)\\ \Rightarrow V_{H_2\left(đktc,thực.tế\right)}=0,12.22,4=2,688\left(l\right)\\ b,n_{H_2SO_4\left(dư\right)}=0,4-0,24=0,16\left(mol\right)\\ \Rightarrow m_{H_2SO_4\left(dư\right)}=0,16.98=15,68\left(g\right)\)
Bài trên
\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right);n_{O_2}=\dfrac{22,4}{22,4}=1\left(mol\right)\\ a,PTHH:2H_2+O_2\rightarrow\left(t^o\right)2H_2O\\ Vì:\dfrac{1}{1}>\dfrac{0,5}{2}\Rightarrow O_2thừa\\ n_{O_2\left(thừa\right)}=1-\dfrac{0,5}{2}=0,75\left(mol\right)\\ \Rightarrow m_{O_2\left(thừa\right)}=0,75.32=24\left(g\right)\\ b,n_{H_2O}=n_{H_2}=0,5\left(mol\right)\Rightarrow m_{H_2O}=0,5.18=9\left(g\right)\)
\(a.Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right);n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\\ LTL:\dfrac{0,2}{1}< \dfrac{0,5}{2}\Rightarrow HCldư\\ n_{HCl\left(pứ\right)}=2n_{Zn}=0,4\left(mol\right)\\\Rightarrow m_{HCl\left(dư\right)}=\left(0,5-0,4\right).36,5=3,65\left(g\right)\\ b.n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\\ \Rightarrow m_{ZnCl_2}=0,2.136=27,2\left(g\right)\\ c.n_{H_2}=n_{Zn}=0,2\left(mol\right)\\ \Rightarrow V_{H_2}=0,2.22,4,=4,48\left(l\right)\\ d.3H_2+Fe_2O_3-^{t^o}\rightarrow2Fe+3H_2O \\ n_{Fe_2O_3}=\dfrac{19,2}{160}=0,12\left(mol\right)\\ LTL:\dfrac{0,2}{3}< \dfrac{0,12}{1}\Rightarrow Fe_2O_3dưsauphảnứng\\ \Rightarrow n_{Fe}=\dfrac{2}{3}n_{H_2}=\dfrac{2}{15}\left(mol\right)\\ \Rightarrow m_{Fe}=\dfrac{2}{15}.56=7,467\left(g\right)\)
a) n\(Zn\)=\(\dfrac{m}{M}\)=\(\dfrac{13}{65}\)=0,2(mol)
n\(HCl\)=\(\dfrac{m}{M}\)=\(\dfrac{18,25}{36,5}=\)0,5(mol)
PTHH : Zn + 2HCl->ZnCl\(2\) + H\(2\)
0,2 0,5
Lập tỉ lệ mol : \(^{\dfrac{0,2}{1}}\)<\(\dfrac{0,5}{2}\)
n\(Zn\) hết , n\(HCl\) dư
-->Tính theo số mol hết
Zn + 2HCl->ZnCl\(2\) + H\(2\)
0,2 -> 0,4 0,2 0,2
n\(HCl\) dư= n\(HCl\)(đề) - n\(HCl\)(pt)= 0,5 - 0,4 = 0,1(mol)
m\(HCl\) dư= 0,1.36,5 = 3,65(g)
b) m\(ZnCl2\) = n.M= 0,2.136= 27,2 (g)
c)V\(H2\)=n.22,4=0,2.22,4=4,48(l)
d) n\(Fe\)\(2\)O\(3\)=\(\dfrac{m}{M}\)=\(\dfrac{19,2}{160}\)=0,12 (mol)
3H2 +Fe2O3 → 2Fe + 3H2O
0,2 0,12
Lập tỉ lệ mol: \(\dfrac{0,2}{3}\)<\(\dfrac{0,12}{1}\)
nH2 hết .Tính theo số mol hết
\(HCl\)
3H2 +Fe2O3 → 2Fe + 3H2O
0,2-> 0,2
m\(Fe\)=n.M= 0,2.56= 11,2(g)
a) Fe + 2HCl --> FeCl2 + H2
b) \(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
\(n_{HCl\left(bđ\right)}=\dfrac{36,5}{36,5}=1\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
0,4<--0,8<----0,4<----0,4
=> mHCl(dư) = (1-0,8).36,5 = 7,3 (g)
c) mFe = 0,4.56 = 22,4 (g)
mFeCl2 = 0,4.127 = 50,8 (g)
\(Mg+Cl_2\rightarrow MgCl_2\)
0,1 0,4
Vì \(n_{Mg}< n_{Cl_2}\) nên tính theo Mg
=>\(n_{MgCl_2}=0.1\left(mol\right)\)
\(m_{MgCl_2}=0.1\left(64+35.5\cdot2\right)=13.5\left(g\right)\)
\(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\\ n_{Cl_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ Mg+Cl_2\rightarrow MgCl_2\)
0,1--------->0,1
Xét tỉ lệ có: \(\dfrac{0,1}{1}< \dfrac{0,4}{1}\Rightarrow Cl_2.dư\)
\(m_{MgCl_2}=0,1.95=9,5\left(g\right)\)