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a) \(n_{NaOH}=0,2.1=0,2\left(mol\right);n_{H_2SO_4}=0,15.2=0,3\left(mol\right)\)
PTHH: 2NaOH + H2SO4 → Na2SO4 + 2H2O
Mol: 0,2 0,1
Ta có: \(\dfrac{0,2}{2}< \dfrac{0,3}{1}\) ⇒ NaOH hết, H2SO4 dư
\(m_{Na_2SO_4}=0,1.142=14,2\left(g\right)\)
b) Vdd sau pứ = 0,2 + 0,15 = 0,35 (l)
\(C_{M_{ddNa_2SO_4}}=\dfrac{0,1}{0,35}=\dfrac{2}{7}\approx0,2857M\)
\(C_{M_{ddH_2SO_4dư}}=\dfrac{0,3-0,1}{0,35}=\dfrac{4}{7}\approx0,57M\)
\(H_2SO_4+2NaOH->Na_2SO_4+2H_2O\\ H_2SO_4+Na_2CO_3->Na_2SO_4+CO_2+H_2O\\ n_{Na_2CO_3}=0,1mol=n_{H_2SO_4dư}\\ n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=\dfrac{1}{2}.0,15.2=0,15mol\\ C_{M\left(H_2SO_4\right)}=\dfrac{0,15+0,1}{0,25}=1\left(M\right)\\ m_{Na_2SO_4}=142\left(0,15+0,1\right)=35,5g\)
\(a)n_{NaOH}=0,5.0,2=0,1mol\\ n_{H_2SO_4}=0,3.1=0,3mol\\2 NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\\ \Rightarrow\dfrac{0,1}{2}< \dfrac{0,3}{1}\Rightarrow H_2SO_4.dư\\ 2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
0,1 0,05 0,05 0,1
\(C_M\) \(_{Na_2SO_4}=\dfrac{0,05}{0,2+0,3}=0,1M\)
\(C_M\) \(_{H_2SO_4}=\dfrac{0,3-0,05}{0,2+0,3}=0,5M\)
b) Vì H2SO4 dư nên quỳ tím hoá đỏ.
a, PT: \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
\(FeO+H_2SO_4\rightarrow FeSO_4+H_2O\)
Gọi: \(\left\{{}\begin{matrix}n_{CuO}=x\left(mol\right)\\n_{FeO}=y\left(mol\right)\end{matrix}\right.\) ⇒ 80x + 72y = 11,2 (1)
Ta có: \(n_{H_2SO_4}=0,15.1=0,15\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{CuO}+n_{FeO}=x+y=0,15\left(2\right)\)
Từ (1) và (2) ⇒ x = 0,05 (mol), y = 0,1 (mol)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{CuO}=\dfrac{0,05.80}{11,2}.100\%\approx35,71\%\\\%m_{FeO}\approx64,28\%\end{matrix}\right.\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{CuSO_4}=n_{Cu}=0,05\left(mol\right)\\n_{FeSO_4}=n_{FeO}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}C_{M_{CuSO_4}}=\dfrac{0,05}{0,15}=\dfrac{1}{3}\left(M\right)\\C_{M_{FeSO_4}}=\dfrac{0,1}{0,15}=\dfrac{2}{3}\left(M\right)\end{matrix}\right.\)
PTHH: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
Ta có: \(n_{KOH}=0,2\cdot0,5=0,1\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4}=n_{K_2SO_4}=0,05\left(mol\right)\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{H_2SO_4}}=\dfrac{0,05}{0,1}=0,5\left(M\right)\\C_{M_{K_2SO_4}}=\dfrac{0,05}{0,2+0,1}\approx0,17\left(M\right)\end{matrix}\right.\)
Bài 1 :
200ml = 0,2l
100ml = 0,1l
\(n_{KOH}=0,5.0,2=0,1\left(mol\right)\)
a) Pt : \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O|\)
2 1 1 2
0,1 0,05 0,05
b) \(n_{H2SO4}=\dfrac{0,1.1}{2}=0,05\left(mol\right)\)
\(C_{M_{ddH2SO4}}=\dfrac{0,05}{0,1}=0,5\left(M\right)\)
c) \(n_{K2SO4}=\dfrac{0,05.1}{1}=0,05\left(mol\right)\)
\(V_{ddspu}=0,2+0,1=0,3\left(l\right)\)
\(C_{M_{K2SO4}}=\dfrac{0,05}{0,3}=\dfrac{1}{6}\left(M\right)\)
Chúc bạn học tốt
\(n_{CuSO_4}=\dfrac{15,2}{160}=0,095mol\\ CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
0,095 0,19 0,095 0,095
\(m_{rắn}=m_{Cu\left(OH\right)_2}=0,095.98=9,31g\\ V_{ddNaOH}=\dfrac{0,19}{2}=0,095l\\ b)C_{M_{Na_2SO_4}}=\dfrac{0,095}{0,04+0,095}\approx0,7M\\ c)Cu\left(OH\right)_2\xrightarrow[t^0]{}CuO+H_2O\)
0,095 0,095
\(m_{rắn}=m_{CuO}=0,095.80=7,6g\)
a) 2NaOH + H2SO4 -- Na2SO4 + 2H2O
b) \(n_{NaOH}=\dfrac{100.20}{100.40}=0,5\left(mol\right)\)
PTHH: 2NaOH + H2SO4 -- Na2SO4 + 2H2O
______0,5----->0,25------>0,25
=> mH2SO4 = 0,25.98 = 24,5 (g)
=> \(m_{ddH_2SO_4}=\dfrac{24,5.100}{19,6}=125\left(g\right)\)
c) mNa2SO4 = 0,25.142 = 35,5 (g)
mdd sau pư = 100 + 125 = 225 (g)
=> \(C\%\left(Na_2SO_4\right)=\dfrac{35,5}{225}.100\%=15,778\%\)
a)
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
_____0,2----------------------->0,2
Xét mZn -mH2 = 13-0,2.2=12,6(g)
=> khối lượng dd sau phản ứng tăng 12,6g
b)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH: 2Fe + 6H2SO4 --> Fe2(SO4)3 + 3SO2 + 6H2O
_____0,1--------------------------------->0,15
Xét mFe - mSO2 = 5,6 - 0,15.64 = -4
=> Khối lượng dung dịch sau phản ứng giảm đi 4g