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\(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
PTHH: Fe + H2SO4 ---> FeSO4 + H2
0,3-->0,3----------->0,3
=> \(\left\{{}\begin{matrix}C_{M\left(H_2SO_4\right)}=\dfrac{0,3}{0,15}=2M\\m_{muối}=0,3.152=45,6\left(g\right)\end{matrix}\right.\)
Sửa đề : 11.2 g sắt
\(n_{Fe}=\dfrac{11.2}{56}=0.2\left(mol\right)\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(0.2....0.2.................0.2\)
\(m_{FeSO_4}=0.2\cdot152=30.4\left(g\right)\)
\(C_{M_{H_2SO_4}}=\dfrac{0.2}{0.05}=4\left(M\right)\)
`a)`
`Fe + H_2 SO_4 -> FeSO_4 + H_2`
`0,4` `0,4` `0,4` `(mol)`
`n_[Fe]=[22,4]/56=0,4(mol)`
`b)m_[FeSO_4]=0,4.152=60,8(g)`
`c)V_[H_2]=0,4.22,4=8,96(l)`
\(n_{Al}=\dfrac{2.7}{27}=0.1\left(mol\right)\)
\(n_{CuSO_4}=0.6\cdot0.1=0.06\left(mol\right)\)
\(2Al+3CuSO_4\rightarrow Al_2\left(SO_4\right)_3+3Cu\)
\(2............3\)
\(0.1.........0.06\)
\(LTL:\dfrac{0.1}{2}>\dfrac{0.06}{3}\Rightarrow Aldư\)
\(m_{Al\left(dư\right)}=\left(0.1-0.04\right)\cdot27=1.62\left(g\right)\)
\(C_{M_{Al_2\left(SO_4\right)_3}}=\dfrac{0.02}{0.1}=0.2\left(M\right)\)
\(n_{FeO}=\dfrac{10.8}{72}=0.15\left(mol\right)\)
\(FeO+2HCl\rightarrow FeCl_2+H_2O\)
\(0.15.......0.3.............0.15\)
\(m_{HCl}=0.3\cdot36.5=10.95\left(g\right)\)
\(C\%HCl=\dfrac{10.95}{100}\cdot100\%=10.95\%\)
\(m_{dd}=10.8+100=110.8\left(g\right)\)
\(m_{FeCl_2}=0.15\cdot127=19.05\left(g\right)\)
\(C\%FeCl_2=\dfrac{19.05}{110.8}\cdot100\%=17.19\%\)
nFeO=10.872=0.15(mol)nFeO=10.872=0.15(mol)
FeO+2HCl→FeCl2+H2OFeO+2HCl→FeCl2+H2O
0.15.......0.3.............0.150.15.......0.3.............0.15
mHCl=0.3⋅36.5=10.95(g)mHCl=0.3⋅36.5=10.95(g)
C%HCl=10.95100⋅100%=10.95%C%HCl=10.95100⋅100%=10.95%
mdd=10.8+100=110.8(g)mdd=10.8+100=110.8(g)
mFeCl2=0.15⋅127=19.05(g)mFeCl2=0.15⋅127=19.05(g)
C%FeCl2=19.05110.8⋅100%=17.19%C%FeCl2=19.05110.8⋅100%=17.19%
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\
n_{H_2SO_4}=\dfrac{24,5}{98}=0,25\left(mol\right)\\
pthh:Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
\(LTL:\dfrac{0,2}{1}< \dfrac{0,25}{1}\)
=> H2SO4 dư
\(n_{H_2}=n_{H_2SO_4\left(p\text{ư}\right)}=n_{Fe}=0,2\left(mol\right)\\
V_{H_2}=0,2.22,4=4,48l\\
m_{H_2SO_4\left(d\right)}=\left(0,25-0,2\right).98=4,9g\)
Fe+H2SO4->FeSO4+H2
0,3--------0,3---0,3----0,3
nFe=16,8\56=0,3 mol
=>Cm=2M
=>mFeSO4=0,3.152=45,6g