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\(n_{FeCl_3}=\dfrac{48,75}{162,5}=0,3(mol)\\ 3NaOH+FeCl_3\to Fe(OH)_3\downarrow+3NaCl\\ \Rightarrow n_{Fe(OH)_3}=0,3(mol);n_{NaOH}=n_{NaCl}=0,9(mol)\\ a,m_{Fe(OH)_3}=0,3.107=32,1(g)\\ b,m_{dd_{NaOH}}=\dfrac{0,9.40}{10\%}=360(g)\\ c,C\%_{NaCl}=\dfrac{0,9.58,5}{360+48,75-32,1}.100\%=13,98\%\\ \)
\(d,2Fe(OH)_3+3H_2SO_4\to Fe_2(SO_4)_3+6H_2O\\ \Rightarrow n_{H_2SO_4}=0,45(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,45.98}{20\%}=220,5(g)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{220,5}{1,14}=193,42(ml)\)
a, PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_{2\downarrow}\)
\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)
b, Ta có: \(n_{Mg}=\dfrac{9,6}{24}=0,4\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Mg}=0,8\left(mol\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{0,8}{0,2}=4\left(M\right)\)
c, Theo PT: \(n_{MgO}=n_{Mg}=0,4\left(mol\right)\)
\(\Rightarrow m_{MgO}=0,4.40=16\left(g\right)\)
\(3NaOH+FeCl_3\rightarrow Fe\left(OH\right)_3+3NaCl\)
\(n_{NaCl}=n_{NaOH}=0,2.3=0,6\left(mol\right)\)
=> \(C_{M\left(NaCl\right)}=\dfrac{0,6}{0,2}=3M\)
\(n_{Fe\left(ỌH\right)_3}=\dfrac{1}{3}n_{NaOH}=0,2\left(mol\right)\)
\(2Fe\left(OH\right)_3-^{t^o}\rightarrow Fe_2O_3+3H_2O\)
Ta có \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=0,1\left(mol\right)\)
=> m Fe2O3 = 0,1 . 160=16(g)
PTHH: \(BaCl_2+H_2SO_4\rightarrow2HCl+BaSO_4\downarrow\)
Ta có: \(n_{BaCl_2}=\dfrac{208\cdot10\%}{208}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,2\left(mol\right)\\n_{BaSO_4}=0,1\left(mol\right)=n_{H_2SO_4}\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{ddH_2SO_4}=\dfrac{0,1\cdot98}{8\%}=122,5\left(g\right)\\m_{BaSO_4}=0,1\cdot233=23,3\left(g\right)\\m_{HCl}=0,2\cdot36,5=7,3\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{ddBaCl_2}+m_{ddH_2SO_4}-m_{BaSO_4}=307,2\left(g\right)\)
\(\Rightarrow C\%_{HCl}=\dfrac{7,3}{307,2}\cdot100\%\approx2,38\%\)
\(n_{BaCl_2}=\dfrac{150.16,64\%}{137+35.2}=0,12\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{100.14,7\%}{98}=0,15\left(mol\right)\)
Phương trình hóa học :
BaCl2 + H2SO4 -----> BaSO4 + 2HCl
Dễ thấy \(\dfrac{n_{BaCl_2}}{1}< \dfrac{n_{H_2SO_4}}{1}\Rightarrow H_2SO_4\text{ dư }0,15-0,12=0,03\left(mol\right)\)
c) Khối lượng kết tủa :
\(m_{BaSO_4}=0,12.233=27,96\) (g)
Khối lượng chất tan : \(m_{HCl}=0,24.36,5=8,76\left(g\right)\) ;
\(m_{H_2SO_4\left(\text{dư}\right)}=0,03.98=2,94\left(g\right)\)
c) \(C\%_{H_2SO_4}\)= \(\dfrac{2,94}{150+100}.100\%=1,176\%\)
\(C\%_{HCl}=\dfrac{8,76}{150+100}.100\%=3.504\%\)
d) NaOH + HCl ---> NaCl + H2O
0,24 <-- 0,24
mol mol
2NaOH + H2SO4 ---> Na2SO4 + 2H2O
0,06 mol <-- 0,03 mol
\(\Rightarrow n_{NaOH}=0,24+0,06=0,3\left(mol\right)\)
\(V_{NaOH}=0,3.2=0,6\left(l\right)\)
a) Na2O +H2O-->2NaOH (1)
2NaOH +CuSO4 -->Na2SO4+ Cu(OH)2 (2)
Cu(OH)2 -to-> CuO +H2O (3)
b) mNa2O=8.100/100=8(g)
=>nNa2O=8/62=0,13(mol)
theo(2) :nCu(OH)2=1/2nNaOH=0,065(mol)
theo(3):nCuO=nCu(OH)2=0,065(mol)
=>mCuO=0,065.80=5,2(g)
c) CuO +2HCl-->CuCl2+H2O (4)
theo (4) : nHCl=2nCuO=0,13(mol)
mddHCl 25%=0,13.36,5.100250,13.36,5.10025=18,98(g)
\(n_{MgCl_2}=0,15.0,2=0,03(mol)\\ PTHH:MgCl_2+2NaOH\to Mg(OH)_2\downarrow +2NaCl\\ a,n_{Mg(OH)_2}=n_{MgCl_2}=0,03(mol)\\ \Rightarrow m_{\downarrow}=m_{Mg(OH)_2}=0,03.58=1,74(g)\\ b,n_{NaOH}=2n_{MgCl_2}=0,06(mol)\\ \Rightarrow C_{M_{NaOH}}=\dfrac{0,06}{0,3}=0,2M\\ c,PTHH:Mg(OH)_2\xrightarrow{t^o}MgO+H_2O\\ \Rightarrow n_{MgO}=n_{Mg(OH)_2}=0,03(mol)\\ \Rightarrow m_{A}=m_{MgO}=0,03.40=1,2(g)\)
\(\begin{cases} m_{NaOH}=\dfrac{150.20\%}{100\%}=30(g)\\ m_{MgCl_2}=\dfrac{80.59,375\%}{100\%}=47,5(g) \end{cases} \Rightarrow \begin{cases} n_{NaOH}=\dfrac{30}{40}=0,75(mol)\\ n_{MgCl_2}=\dfrac{47,5}{95}=0,5(mol) \end{cases}\\ PTHH:2NaOH+MgCl_2\to Mg(OH)_2\downarrow+2NaCl\\ \text {Vì }\dfrac{n_{NaOH}}{2}<\dfrac{n_{MgCl_2}}{1} \text {nên }MgCl_2 \text { dư}\\ a,n_{Mg(OH)_2}=\dfrac{1}{2}n_{NaOH}=0,375(mol)\\ \Rightarrow m_{Mg(OH)_2}=0,375.58=21,75(g)\\ b,n_{NaCl}=m_{NaOH}=0,75(mol)\\ \Rightarrow m_{CT_{NaCl}}=0,75.58,5=43,875(g)\\ m_{dd_{NaCl}}=150+80-21,75=208,25(g)\\ \Rightarrow C\%_{NaCl}=\dfrac{43,875}{208,25}.100\%\approx 21,07\%\)