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a, \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
____0,1_____0,2______0,1_____0,1 (mol)
\(V_{H_2}=0,1.24,79=2,479\left(l\right)\)
\(m_{ZnCl_2}=0,1.136=13,6\left(g\right)\)
b, \(C_{M_{HCl}}=\dfrac{0,2}{0,1}=1\left(M\right)\)
c, \(n_{CuO}=\dfrac{12}{80}=0,15\left(mol\right)\)
PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Xét tỉ lệ: \(\dfrac{0,15}{1}>\dfrac{0,1}{1}\), ta được CuO dư.
Theo PT: \(n_{CuO\left(pư\right)}=n_{Cu}=n_{H_2}=0,1\left(mol\right)\Rightarrow n_{CuO\left(dư\right)}=0,05\left(mol\right)\)
⇒ m chất rắn = mCuO (dư) + mCu = 0,05.80 + 0,1.64 = 10,4 (g)
a)\(m_{ddHCl}=\dfrac{4,8}{10\%}.100\%=48\left(g\right)\)
b)\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
\(PTHH:Mg+2HCl\xrightarrow[]{}MgCl_2+H_2\)
\(n_{MgCl_2}=n_{Mg}=n_{H_2}=0,2\)
\(m_{MgCl_2}=0,2.95=19\left(g\right)\)
\(V_{H_2}=0,2.22,4=4.48\left(l\right)\)
c)\(m_{H_2}=0,2.2=0,4\left(g\right)\)
\(m_{ddMgCl_2}=4,8+48-0,4=52,4\left(g\right)\)
\(C\%_{MgCl_2}=\dfrac{19}{52,4}.100\%=36\%\)
=)) Cái chất tan của dd HCl ấy nó là HCl , khí hidro clorua ấy còn dm là nước trong đấy khí HCl + nước mới tạo thành dd axit HCl . Cái Mg nó là cái chất tác dụng thêm chứ có phải trong dd HCl đâu , khi tạo ra sp là MgCl2 thì MgCl2 + Nước ở dd HCl thì nó mới là dd chứ . Trong 1 dd chính chất đấy là chất tan còn dung môi chỉ là nước th
\(nFe=\dfrac{5,6}{56}=0,1\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
1 2 1 1 (mol)
0,1 0,2 0,1 0,1 (mol)
m muối là mFeCl2
=> \(mFeCl_2=0,1.127=12,7\left(g\right)\)
\(VH_2=0,1.22,4=2,24\left(l\right)\)
\(VHCl=100ml=0,1\left(l\right)\)
\(CM_{HCl}=\dfrac{nHCl}{VHCl}=\dfrac{0,2}{0,1}=2M\)
\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\ n_{H_2SO_4}=0,16.5=0,8\left(mol\right)\)
PTHH: 2Al + 3H2SO4 ---> Al2(SO4)3 + 3H2
LTL: \(\dfrac{0,2}{2}< \dfrac{0,8}{3}\rightarrow\)H2SO4 dư
Theo pt: \(\left\{{}\begin{matrix}n_{H_2SO_4\left(pư\right)}=n_{H_2}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}.0,2=0,3\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=\dfrac{1}{2}.0,2=0,1\left(mol\right)\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}m_{Al_2\left(SO_4\right)_3}=0,1.342=34,2\left(g\right)\\V_{H_2}=0,3.22,4=6,72\left(l\right)\end{matrix}\right.\\ \rightarrow\left\{{}\begin{matrix}C_{M\left(Al_2\left(SO_4\right)_3\right)}=\dfrac{0,2}{5}=0,04M\\C_{M\left(H_2SO_4.dư\right)}=\dfrac{0,8-0,3}{5}=0,1M\end{matrix}\right.\)
\(n_{Zn}=\dfrac{13}{65}=0.2\left(mol\right)\)
\(n_{HCl}=\dfrac{182.5\cdot10}{100\cdot36.5}=0.5\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(0.2......0.4..........0.2........0.2\)
\(n_{HCl\left(dư\right)}=0.5-0.4=0.1\left(mol\right)\)
\(m_{HCl\left(dư\right)}=0.1\cdot36.5=3.65\left(g\right)\)
\(V_{H_2}=0.2\cdot22.4=4.48\left(l\right)\)
\(m_{\text{dung dịch sau phản ứng}}=13+182.5-0.2\cdot2=195.1\left(g\right)\)
\(C\%_{HCl\left(dư\right)}=\dfrac{3.65}{195.1}\cdot100\%=1.87\%\)
\(C\%_{ZnCl_2}=\dfrac{0.2\cdot136}{195.1}\cdot100\%=13.94\%\)
`a)PTHH:`
`Zn + 2HCl -> ZnCl_2 + H_2`
`0,1` `0,2` `0,1` `0,1` `(mol)`
`n_[HCl]=0,2.1=0,2(mol)`
`=>m_[Zn]=0,1.65=6,5(g)`
`b)m_[dd HCl]=1,1.200=220(g)`
`=>C%_[ZnCl_2]=[0,1.136]/[6,5+220-0,1.2].100~~6%`
\(a,n_{HCl}=0,2.1=0,2\left(mol\right)\)
PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,1<--0,2------>0,1------->0,1
\(\rightarrow m_{Zn}=0,1.65=6,5\left(g\right)\)
\(b,m_{ddHCl}=200.1,1=220\left(g\right)\)
\(\rightarrow m_{dd}=220+6,5-0,1.2=226,3\left(g\right)\\ \rightarrow C\%_{ZnCl_2}=\dfrac{0,1.136}{226,3}.100\%=6\%\)
\(n_{NaOH}=0.2\cdot0.5=0.1\left(mol\right)\)
\(n_{CuSO_4}=0.1\cdot2=0.2\left(mol\right)\)
\(2NaOH+CuSO_4\rightarrow Na_2SO_4+Cu\left(OH\right)_2\)
\(0.1.............0.05...............0.05...........0.05\)
\(m_{Cu\left(OH\right)_2}=0.05\cdot98=4.9\left(g\right)\)
\(C_{M_{Na_2SO_4}}=\dfrac{0.05}{0.2+0.1}=0.167\left(M\right)\)
\(C_{M_{CuSO_4\left(dư\right)}}=\dfrac{0.2-0.05}{0.1}=1.5\left(M\right)\)
\(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\\ m_{HCl}=\dfrac{100.18,25}{100}=18,25\left(g\right)\\
n_{HCl}=\dfrac{18,25}{36,5}=0,5\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,125 0,125 (mol )
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(l\right)\\
\)
\(C\%=\dfrac{8,125}{8,125+18,25}.100\%=30,8\%\)
Bài 18:
Ta có: \(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\)
\(m_{HCl}=100.18,25\%=18,25\left(g\right)\Rightarrow n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, Xét tỉ lệ: \(\dfrac{0,125}{1}< \dfrac{0,5}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,125\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(g\right)\)
\(m_{H_2}=0,125.2=0,25\left(g\right)\)
c, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,125\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Zn}=0,25\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{HCl\left(dư\right)}=0,25\left(mol\right)\)
Có: m dd sau pư = 8,125 + 100 - 0,25 = 107,875 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,125.136}{107,875}.100\%\approx15,76\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,25.36,5}{107,875}.100\%\approx8,46\%\end{matrix}\right.\)
Bạn tham khảo nhé!
\(a,Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right);n_{HCl}=2.0,2=0,4\left(mol\right)\\ m_{ZnCl_2}=136.0,2=27,2\left(g\right);C_{MddHCl}=\dfrac{0,4}{0,1}=4\left(M\right)\\ b,Zn+CuSO_4\rightarrow ZnSO_4+Cu\\ n_{CuSO_4}=\dfrac{20.10\%}{160}=0,0125\left(mol\right);n_{Zn}=0,2\left(mol\right)\\ Vì:\dfrac{0,0125}{1}< \dfrac{0,2}{1}\Rightarrow Zn.dư\\ n_{Zn\left(p.ứ\right)}=n_{ZnSO_4}=n_{CuSO_4}=0,0125\left(mol\right)\\m_{Zn\left(p.ứ\right)}=0,0125.65=0,8125\left(g\right)\\ m_{ddsau}=m_{Zn\left(p.ứ\right)}+m_{ddCuSO_4}=0,8125+20=20,8125\left(g\right)\\ C\%_{ddZnSO_4}=\dfrac{0,0125.161}{20,8125}.100\approx9,67\%\)