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\(a,2NaOH+MgSO_4\rightarrow Mg\left(OH\right)_2+Na_2SO_4\\ n_{NaOH}=0,5.1=0,5\left(mol\right)\\ b,n_{Mg\left(OH\right)_2}=\dfrac{0,5}{2}=0,25\left(mol\right)=n_{Na_2SO_4}\\ m_{kt}=m_{Mg\left(OH\right)_2}=58.0,25=14,5\left(g\right)\\ c,V_{ddX}=V_{ddNaOH}+V_{ddMgSO_4}=0,5+0,5=1\left(l\right)\\ C_{MddNa_2SO_4}=\dfrac{0,25}{1}=0,25\left(M\right)\)
\(a,PTHH:Na_2O+H_2O\rightarrow2NaOH\\ \Rightarrow n_{NaOH}=2n_{Na_2O}=2\cdot\dfrac{37,2}{62}=0,6\cdot2=1,2\left(mol\right)\\ \Rightarrow C_{M_{NaOH}}=\dfrac{1,2}{0,5}=2,4M\\ b,PTHH:2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\\ \Rightarrow n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,6\left(mol\right)\\ \Rightarrow m_{H_2SO_4}=0,6\cdot98=58,8\left(g\right)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{58,8\cdot100\%}{20\%}=294\left(g\right)\\ \Rightarrow V_{dd}=\dfrac{294}{1,14}\approx257,9\left(ml\right)\)
a, \(n_{Na_2O}=\dfrac{7,75}{62}=0,125\left(mol\right)\)
PTHH: Na2O + H2O → 2NaOH
Mol: 0,125 0,25
b, \(C_{M_{ddNaOH}}=\dfrac{0,25}{0,25}=1M\)
c,
PTHH: 2NaOH + H2SO4 → Na2SO4 + 2H2O
Mol: 0,25 0,125
\(m_{ddH_2SO_4}=\dfrac{0,125.98.100}{20}=61,25\left(g\right)\)
\(\Rightarrow V_{ddH_2SO_4}=\dfrac{61,25}{1,14}=53,728\left(ml\right)\)
Lần sau bạn đăng tách từng bài ra nhé.
Câu 1:
a, \(Na_2O+H_2O\rightarrow2NaOH\)
\(n_{Na_2O}=\dfrac{15,5}{62}=0,25\left(mol\right)\)
Theo PT: \(n_{NaOH}=2n_{Na_2O}=0,5\left(mol\right)\Rightarrow C_{M_{NaOH}}=\dfrac{0,5}{0,5}=1\left(M\right)\)
b, \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
Theo PT: \(n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,25\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}=0,25.98=24,5\left(g\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{24,5}{20\%}=122,5\left(g\right)\)
\(\Rightarrow V_{ddH_2SO_4}=\dfrac{122,5}{1,14}\approx107,46\left(ml\right)\)
Câu 3: \(n_{CO_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
PT: \(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_{3\downarrow}+H_2O\)
\(n_{CaCO_3}=n_{CO_2}=0,4\left(mol\right)\Rightarrow m_{CaCO_3}=0,4.100=40\left(g\right)\)
Câu 4: \(n_{CuSO_4}=\dfrac{32}{160}=0,2\left(mol\right)\)
\(n_{BaCl_2}=\dfrac{20,8}{208}=0,1\left(mol\right)\)
PT: \(CuSO_4+BaCl_2\rightarrow BaSO_{4\downarrow}+CuCl_2\)
Xét tỉ lệ: \(\dfrac{0,2}{1}>\dfrac{0,1}{1}\), ta được CuSO4 dư.
Theo PT: \(n_{BaSO_4}=n_{BaCl_2}=0,1\left(mol\right)\Rightarrow m_{BaSO_4}=0,1.233=23,3\left(g\right)\)
\(n_{Na_2O}=\dfrac{15,5}{62}=0,25\left(mol\right)\\ PTHH:Na_2O+H_2O\rightarrow2NaOH\\ n_{NaOH}=2.0,25=0,5\left(mol\right)\\ a,C_{MddNaOH}=\dfrac{0,5}{0,5}=1\left(M\right)\\ b,2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\\ n_{H_2SO_4}=n_{Na_2SO_4}=\dfrac{0,5}{2}=0,25\left(mol\right)\\ m_{H_2SO_4}=0,25.98=24,5\left(g\right)\\ m_{ddH_2SO_4}=\dfrac{24,5.100}{20}=122,5\left(g\right)\\ V_{ddH_2SO_4}=\dfrac{122,5}{1,14}\approx107,456\left(ml\right)\\ c,V_{ddsau}=V_{ddNaOH}+V_{ddH_2SO_4}\approx0,5+0,107456=0,607456\left(l\right)\\C_{MddNa_2SO_4}\approx\dfrac{ 0,25}{0,607456}\approx0,411552\left(M\right)\)
a)\(n_{K_2O}=\dfrac{23,5}{94}=0,25mol\)
\(K_2O+H_2O\rightarrow2KOH\)
0,25 0,25 0,5
\(C_M=\dfrac{0,5}{0,5}=1M\)
b)Để trung hòa: \(n_{H^+}=n_{OH^-}=0,5\)
\(\Rightarrow n_{H_2SO_4}=\dfrac{1}{2}n_{H^+}=0,25mol\)
\(m_{H_2SO_4}=0,25\cdot98=24,5g\)
\(\Rightarrow m_{ddHCl}=\dfrac{24,5\cdot100\%}{60\%}=\dfrac{245}{6}g\)
Thể tích dung dịch:
\(V=\dfrac{m}{D}=\dfrac{\dfrac{245}{6}}{1,5}\approx27,22ml\)
\(n_{K_2O}=\dfrac{23,5}{94}=0,25\left(mol\right)\\ K_2O+H_2O\rightarrow2KOH\\ n_{KOH}=2.0,25=0,5\left(mol\right)\\ a,C_{M\text{dd}A}=C_{M\text{dd}KOH}=\dfrac{0,5}{0,5}=1\left(M\right)\\ b,2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\\ n_{H_2SO_4}=\dfrac{0,5}{2}=0,25\left(mol\right)\\ m_{H_2SO_4}=0,25.98=24,5\left(g\right)\\ m_{\text{dd}H_2SO_4}=\dfrac{24,5.100}{60}=\dfrac{245}{6}\left(g\right)\\ V_{\text{dd}H_2SO_4}=\dfrac{\dfrac{245}{6}}{1,5}=\dfrac{245}{9}\left(ml\right)\approx27,222\left(ml\right)\)
a, \(n_{KOH}=0,3.1=0,3\left(mol\right)\)
PT: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
Theo PT: \(n_{K_2SO_4}=\dfrac{1}{2}n_{KOH}=0,15\left(mol\right)\)
\(\Rightarrow m_{K_2SO_4}=0,15.174=26,1\left(g\right)\)
b, \(C_{M_{K_2SO_4}}=\dfrac{0,3}{0,3+0,2}=0,6\left(M\right)\)
Anh bổ sung câu c)
\(C_{MddNa_2SO_4}=\dfrac{0,25}{0,09879+0,5}=0,4175\left(M\right)\)
a, \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
Chất X là MgCl2, Y là khí H2
PTHH: Mg + 2HCl → MgCl2 + H2
Mol: 0,2 0,4 0,2 0,2
b, \(V=\dfrac{0,4}{2}=0,2\left(l\right)=200\left(ml\right)\)
\(V_1=0,2.22,4=4,48\left(l\right)\)
c, \(C_{M_{ddMgCl_2}}=\dfrac{0,2}{0,2}=1M\)
d,
PTHH: M2Ox + 2xHCl → 2MClx + xH2O
Mol: \(\dfrac{0,2}{x}\) 0,4
\(\Rightarrow M_{M_2O_x}=\dfrac{16,2}{\dfrac{0,2}{x}}=81x\left(g/mol\right)\)
Vì M là kim loại nên có hóa trị l,ll,lll
| x | l | ll | lll |
| \(M_{M_2O_x}\) | 81 | 162 | 243 |
| MM | 32,5 | 65 | 97,5 |
| Kết luận | loại | thỏa mãn | loại |
⇒ M là kẽm (Zn)
\(n_{Na_2O}=\dfrac{12,4}{62}=0,2\left(mol\right)\)
PTHH:
\(Na_2O+H_2O\rightarrow2NaOH\)
0,2 0,2 0,4
\(C_{M\left(NaOH\right)}=\dfrac{0,4}{0,5}=0,8\left(M\right)\)
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
0,4 0,2
\(V_{H_2SO_4}=\dfrac{0,2}{1}=0,2\left(l\right)=200\left(ml\right)\)
\(a)Na_2O+H_2O\rightarrow2NaOH\\ n_{Na_2O}=\dfrac{12,4}{62}=0,2mol\\ n_{NaOH}=0,2.2=0,4mol\\ C_{M_{NaOH}}=\dfrac{0,4}{0,5}=0,8M\\ b)2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\\ n_{H_2SO_4}=0,4:2=0,2mol\\ V_{ddH_2SO_4}=\dfrac{0,2}{1}=0,2l=200ml\)