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\(n_{H_2}= \dfrac{8,96}{22,4} = 0,4(mol)\\ 2Al + 6HCl \to 2AlCl_3 + 3H_2\\ Fe + 2HCl \to FeCl_2 + H_2\\ m_{tăng} = m_{kim\ loại} - m_{H_2} = 11 - 0,4.2 = 10,2(gam)\)
PTHH: 2Al+6HCl→2AlCl3+3H2↑2Al+6HCl→2AlCl3+3H2↑
Fe+2HCl→FeCl2+H2↑Fe+2HCl→FeCl2+H2↑
Ta có: mH2=8,9622,4⋅2=0,8(g)<mhh=11(g)mH2=8,9622,4⋅2=0,8(g)<mhh=11(g)
⇒⇒ Sau p/ứ dd tăng 11−0,8=10,2(g)
a, \(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
PTHH: 2Al + 6HCl → 2AlCl3 + 3H2
Mol: x 1,5x
PTHH: Fe + 2HCl → FeCl2 + H2
Mol: y y
b, Ta có hpt: \(\left\{{}\begin{matrix}27x+56y=11\\1,5x+y=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)
\(\Rightarrow\%m_{Al}=\dfrac{0,2.27.100\%}{11}=49,09\%\Rightarrow\%m_{Fe}=100\%-49,09\%=50,91\%\)
c, \(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)
Ta có: \(\dfrac{0,2}{1}< \dfrac{0,4}{1}\) ⇒ CuO hết, H2 dư
PTHH: CuO + H2 → Cu + H2O
Mol: 0,2 0,2
\(m_{Cu}=0,2.64=12,8\left(g\right)\)
Gọi \(m_{Al}=a\left(g\right)\left(0< a< 11\right)\)
\(\rightarrow m_{Fe}=11-a\left(g\right)\)
\(\rightarrow\left\{{}\begin{matrix}n_{Al}=\dfrac{a}{27}\left(mol\right)\\n_{Fe}=\dfrac{11-a}{56}\left(mol\right)\end{matrix}\right.\)
PTHH:
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(\dfrac{a}{27}\) \(\dfrac{a}{18}\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(\dfrac{11-a}{56}\) \(\dfrac{11-a}{56}\)
\(\rightarrow pt:\dfrac{a}{18}+\dfrac{11-a}{56}=0,4\\ \Leftrightarrow m_{Al}=a=5,4\left(g\right)\left(TM\right)\)
\(\rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{5,4}{11}=49,1\%\\\%m_{Fe}=100\%-49,1\%=50,9\%\end{matrix}\right.\)
\(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)
PTHH: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
LTL: \(0,2< 0,4\rightarrow\) H2 dư
\(n_{Cu}=n_{CuO}=0,2\left(mol\right)\rightarrow m_{CuO}=0,2.64=12,8\left(g\right)\)
a) \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(Đặt:n_{Zn}=x\left(mol\right);n_{Fe}=y\left(mol\right)\)
\(n_{H_2}=0,4\left(mol\right)\)
Theo đề ta có hệ \(\left\{{}\begin{matrix}65x+56y=24,2\\x+y=0,4\end{matrix}\right.\)
=> x=0,2 ; y=0,2
\(\%m_{Zn}=\dfrac{0,2.65}{24,2}.100=53,72\%;\%m_{Fe}=46,28\%\)
b)Bảo toàn nguyên tố H: \(n_{HCl}=2n_{H_2}=0,8\left(mol\right)\)
=> \(V_{HCl}=\dfrac{0,8}{2,5}=0,32\left(l\right)\)
c) \(n_{FeCl_2}=0,2\left(mol\right);n_{ZnCl_2}=0,2\left(mol\right)\)
=> \(CM_{FeCl_2}=\dfrac{0,2}{0,32}=0,625\left(mol\right)\)
\(CM_{ZnCl_2}=\dfrac{0,2}{0,32}=0,625\left(mol\right)\)
a) n H2 = 15,68/22,4 = 0,7(mol)
$Zn + 2HCl \to ZnCl_2 + H_2$
$Fe + 2HCl \to FeCl_2 + H_2$
Theo PTHH : nHCl = 2n H2 = 1,4(mol)
=> CM HCl = 1,4/2 = 0,7M
b) n Zn = a(mol) ; n Fe = b(mol) => 65a + 56b = 43,7(1)
n H2 = a + b = 0,7(2)
Từ (1)(2) suy ra a = 0,5 ; b = 0,2
Suy ra:
m Zn = 0,5.65 = 32,5 gam
m Fe = 0,2.56 = 11,2 gam
a) n H2 = 15,68/22,4 = 0,7(mol)
Zn+2HCl→ZnCl2+H2Zn+2HCl→ZnCl2+H2
Fe+2HCl→FeCl2+H2Fe+2HCl→FeCl2+H2
Theo PTHH : nHCl = 2n H2 = 1,4(mol)
=> CM HCl = 1,4/2 = 0,7M
b) n Zn = a(mol) ; n Fe = b(mol) => 65a + 56b = 43,7(1)
n H2 = a + b = 0,7(2)
Từ (1)(2) suy ra a = 0,5 ; b = 0,2
Suy ra:
m Zn = 0,5.65 = 32,5 gam
m Fe = 0,2.56 = 11,2 gam
\(Zn+2HCl->ZnCl_2+H_2\\ Mg+2HCl->MgCl_2+H_2\\ n_{Zn}=a\\ n_{Mg}=b\\ 65a+24b=11,3g\\ n_{H_2}=a+b=\dfrac{6,72}{22,4}=0,3\\ a=0,1\\ m_{Zn}=65.0,1=6,5g\)
\(\left\{{}\begin{matrix}m_{Mg}=\dfrac{40.9}{100}=3,6\left(g\right)\\m_{Al}=9-3,6=5,4\left(g\right)\end{matrix}\right.\\ \rightarrow\left\{{}\begin{matrix}n_{Mg}=\dfrac{3,6}{24}=0,15\left(mol\right)\\n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\end{matrix}\right.\)
PTHH:
Mg + 2HCl ---> MgCl2 + H2
0,15 ------------------------> 0,15
2Al + 6HCl ---> 2AlCl3 + 3H2
0,2 ---------------------------> 0,3
\(\rightarrow V_{H_2}=\left(0,15+0,3\right).22,4=10,08\left(l\right)\)
\(n_{H_2O}=\dfrac{6,48}{18}=0,36\left(mol\right)\)
PTHH: FexOy + yH2 --to--> xFe + yH2O
Theo pthh: \(n_{O\left(oxit\right)}=n_{H_2\left(pư\right)}=n_{H_2O}=0,36\left(mol\right)\)
\(\rightarrow m_{oxit}=15,12+16.0,36=20,88\left(g\right)\)
\(n_{Fe}=\dfrac{15,12}{56}=0,27\left(mol\right)\)
CTHH: FexOy
=> x : y = 0,27 : 0,36 = 3 : 4
=> CTHH: Fe3O4 (oxit sắt từ)
mMg = 40%x9 = 3,6(g) =>nMg=3,6:24 = 0,15 (mol)
=> mAl = 9-3,6 = 5,4(g) => nAl = 5,4:27 = 0,2 (mol)
pthh : 2Al+6HCl -> 2AlCl3+3H2
0,2 0,3
Mg+2HCl -> MgCl2 +H2
0,15 0,15
=> nH2 = 0,15 + 0,3 = 0,45 (mol)
=> VH2 = 0,45.22,4 = 10,08 (L)
mH2 = 0,45 . 2 = 0,9 (mol)
áp dụng BLBTKL ta có :
mH2 + moxit sắt = mFe + mH2O
=> moxit sắt = 20,7 (g)
a) 2Al + 6HCl \(\rightarrow\) 2AlCl3 + 3H2
Fe + 2HCl \(\rightarrow\) FeCl2 + H2
b) Gọi nAl = x, nFe = y
=> 27x + 56y = 11 (1)
Theo pt: \(\Sigma\)nH2 = 1,5x + y = \(\dfrac{8,96}{22,4}=0,4mol\)(2)
Từ 1 + 2 => x = 0,2 , y = 0,1
=> mAl = 0,2.27 = 5,4 => %mAl = \(\dfrac{5,4}{11}.100\%\approx49,09\%\)
%mFe = 100 - 49,09 = 50,91%
c) Theo pt: nHCl = 2nH2 = 0,8 mol
=> mHCl = 0,8 . 36,5 = 29,2g
=> \(m_{dd}\)HCl = 29,2 : 10% = 292g
d) mdd sau phản ứng = m A + mHCl = 11 + 292 = 303g
Theo pt: nAlCl3 = nAl = 0,2 mol => m AlCl3 = 26,7g
=> C%AlCl3 = \(\dfrac{26,7}{303}.100\%\) = 8,81%
tương tự nFeCl2 = 0,1 mol => C%FeCl2 = 4,19%