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\(n_{FeO}=\dfrac{7,2}{72}=0,1mol\\ n_{H_2SO_4}=0,4.1,5=0,6mol\\ FeO+H_2SO_4\rightarrow FeSO_4+H_2O\\ \Rightarrow\dfrac{0,1}{1}< \dfrac{0,6}{1}\Rightarrow H_2SO_4.dư\\ n_{FeO}=n_{FeSO_4}=n_{H_2SO_4,pư}=0,1mol\\ C_{M_{FeSO_4}}=\dfrac{0,1}{0,4}=0,25M\\ C_{M_{H_2SO_4}}=\dfrac{0,6-0,1}{0,4}=1,25M\)
nHCl=0,6 mol
FeO+2HCl-->FeCl2+ H2O
x mol x mol
Fe2O3+6HCl-->2FeCl3+3H2O
x mol 2x mol
72x+160x=11,6
=>x=0,05 mol
a) CMFeCl2=0,05/0,3=1/6 M
CM FeCl3=0,1/0,3=1/3 M
CM HCl du=(0,6-0,4)/0,3=2/3 M
b/
NaOH+ HCl-->NaCl+H2O
0,2 0,2
2NaOH+FeCl2-->2NaCl+Fe(OH)2
0,1 0,05
3NaOH+FeCl3-->3NaCl+Fe(OH)3
0,3 0,1
nNaOH=0,6
VNaOH=0,6/1,5=0,4l=400ml
a)
$K_2SO_4 + BaCl_2 \to BaSO_4 + 2KCl$
b)
$n_{K_2SO_4} = 0,2.2 = 0,4(mol)$
$n_{BaCl_2} = 0,3.1 = 0,3(mol)$
Ta thấy :
$n_{K_2SO_4} : 1 > n_{BaCl_2} : 1$ nên $K_2SO_4$ dư
$n_{BaSO_4} = n_{BaCl_2} = 0,3(mol)$
$m_{BaSO_4} = 0,3.233 = 69,9(gam)$
c) $n_{K_2SO_4} = 0,4 - 0,3 = 0,1(mol)$
$V_{dd\ sau\ pư} = 0,2 + 0,3 = 0,5(lít)$
$C_{M_{K_2SO_4} } = \dfrac{0,1}{0,5} = 0,2M$
$C_{M_{KCl}} = \dfrac{0,6}{0,5} = 1,2M$
2Al+ 3H2SO4→ Al2(SO4)3+ 3H2
(mol) 0,1 0,15 0,05 0,15
đổi: 300ml=0,3 lít
a) nAl=\(\dfrac{m}{M}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(n_{H_2SO_4}=C_M.V=0,5.0,3=0,15\left(mol\right)\)
tỉ lệ:
Al H2SO4
\(\dfrac{0,2}{2}\) > \(\dfrac{0,15}{3}\)
→ Al dư, H2SO4 phản ứng hết sau phản ứng
→ \(V_{H_2}=n.22,4=0,15.22,4=3,36\left(lít\right)\)
b) \(n_{Al\left(dư\right)}=n_{Al\left(bđ\right)}-n_{Al\left(ph.ứ\right)}=0,2-0,1=0,1\left(mol\right)\)
\(C_{M_{Al\left(dư\right)}}=\dfrac{n}{V}=\dfrac{0,1}{0,3}=\dfrac{1}{3}M\)
\(C_{M_{Al_2\left(SO_4\right)_3}}=\dfrac{n}{V}=\dfrac{0,05}{0,3}=\dfrac{1}{6}M\)
\(C_{M_{H_2}}=\dfrac{n}{V}=\dfrac{0,15}{0,3}=0,05M\)
a) \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
_____0,2-->0,6----->0,2---->0,3
=> \(C_{M\left(HCl\right)}=\dfrac{0,6}{0,2}=3M\)
b) VH2 = 0,3.24,79 = 7,437 (l)
c) \(C_{M\left(AlCl_3\right)}=\dfrac{0,2}{0,2}=1M\)
\(n_{Fe}=\dfrac{11.2}{56}=0.2\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(0.2.......0.4........0.2.......0.2\)
\(V_{H_2}=0.2\cdot22.4=4.48\left(l\right)\)
\(V_{dd_{HCl}}=\dfrac{0.4}{0.2}=2\left(l\right)\)
\(C_{M_{FeCl_2}}=\dfrac{0.2}{2}=0.1\left(M\right)\)
a)
$Fe + 2HCl \to FeCl_2 + H_2$
$n_{H_2} = n_{Fe} = \dfrac{11,2}{56} = 0,2(mol)$
$V_{H_2} = 0,2.22,4 = 4,48(lít)$
b)
$n_{HCl} = 2n_{Fe} = 0,4(mol)$
$V_{dd\ HCl} = \dfrac{0,4}{0,2} = 2(lít) = 2000(ml)$
c)
$n_{FeCl_2} = n_{Fe} = 0,2(mol)$
$\Rightarrow C_{M_{FeCl_2}} = \dfrac{0,2}{2} = 0,1M$
\(a,n_{H_2SO_4}=0,5\cdot0,1=0,05\left(mol\right)\\ PTHH:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ \Rightarrow n_{H_2}=n_{H_2SO_4}=0,05\left(mol\right)\\ \Rightarrow V_{H_2\left(đktc\right)}=0,05\cdot22,4=1,12\left(l\right)\\ b,n_{Al}=\dfrac{2}{3}n_{H_2SO_4}=\dfrac{1}{30}\left(mol\right)\\ \Rightarrow m_{Al}=\dfrac{1}{30}\cdot27=0,9\left(g\right)\\ c,n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{3}n_{H_2SO_4}\approx0,017\left(mol\right)\\ \Rightarrow C_{M_{Al_2\left(SO_4\right)_3}}=\dfrac{0,017}{0,1}\approx0,17M\)