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Chất không tan là Ag.
=> mAg= 6,25(g)
nH2=0,25(mol)
PTHH: Zn + H2SO4 -> ZnSO4 + H2
-> nZn=nH2= 0,25(mol)
=>mZn= 0,25 . 65=16,25(g)
=> \(\%mAg=\dfrac{6,25}{6,25+16,25}.100\approx27,778\%\\ \Rightarrow\%mZn\approx72,222\%\)
B : $CuO,Na_2O,Ag,BaO,Fe_3O_4$
$2Cu + O_2 \xrightarrow{t^o} 2CuO$
$4Na + O_2 \xrightarrow{t^o} 2Na_2O$
$2Ba + O_2 \xrightarrow{t^o} 2BaO$
$3Fe + 2O_2 \xrightarrow{t^o} Fe_3O_4$
C : $Cu,Na_2O,Ag,BaO,Fe$
$CuO + H_2 \xrightarrow{t^o} Cu + H_2O$
$Fe_3O_4 + 4H_2 \xrightarrow{t^o} 3Fe + 4H_2O$
D : $Cu,Ag,Fe$ ; E : $NaOH,Ba(OH)_2$
$Na_2O + H_2O \to 2NaOH$
$BaO + H_2O \to Ba(OH)_2$
F : Ag,Cu ; T : $HCl,FeCl_2$
$Fe + 2HCl \to FeCl_2 + H_2$
PTHH: Mg +2 HCl -> MgCl2 + H2
x_________2x_____x_______x(mol)
Zn + 2 HCl -> ZnCl2 + H2
y___2y_____y_______y(mol)
Ta có hpt: \(\left\{{}\begin{matrix}24x+65y=15,3\\x+y=0,3\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=\dfrac{21}{205}\\y=\dfrac{81}{410}\end{matrix}\right.\)
=>mMg=21/205 . 24 = 504/205(g)
mZn=81/410 . 65=1053/82(g)
Chất rắn D là Cu, chất rắn E là CuO
\(m_{tăng}=m_{O_2}=0,16\left(g\right)\)
=> \(n_{O_2}=\dfrac{0,16}{32}=0,005\left(mol\right)\)
PTHH: 2Cu + O2 --to--> 2CuO
0,01<-0,005
=> mCu = 0,01.64 = 0,64 (g)
Gọi số mol K, Ba là a, b (mol)
=> 39a + 137b = 3,18 - 0,64 = 2,54 (1)
PTHH: 2K + 2H2O --> 2KOH + H2
a--------------->a
Ba + 2H2O --> Ba(OH)2 + H2
b--------------->b
=> 56a + 171b = 3,39 (2)
(1)(2) => a = 0,03 (mol); b = 0,01 (mol)
=> \(\left\{{}\begin{matrix}\%m_{Cu}=\dfrac{0,64}{3,18}.100\%=20,126\%\\\%m_K=\dfrac{0,03.,39}{3,18}.100\%=36,792\%\\\%m_{Ba}=\dfrac{0,01.137}{3,18}.100\%=43,082\%\end{matrix}\right.\)
\(m_{O_2}=m+0,16-m=0,16\left(g\right)\\ \rightarrow n_{O_2}=\dfrac{0,16}{32}=0,005\left(mol\right)\)
PTHH: 2Cu + O2 --to--> 2CuO
0,01 0,005
Gọi \(\left\{{}\begin{matrix}n_K=a\left(mol\right)\\n_{Ba}=b\left(mol\right)\end{matrix}\right.\)
PTHH:
2K + 2H2O ---> 2KOH + H2
a a
Ba + 2H2O ---> Ba(OH)2 + H2
b b
Hệ pt \(\left\{{}\begin{matrix}39a+137b=3,18-0,01.64=2,54\\56a+171b=3,39\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,03\left(mol\right)\\b=0,01\left(mol\right)\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}\%m_{Cu}=\dfrac{0,01.64}{3,18}=20,13\%\\\%m_K=\dfrac{0,03.39}{3,18}=36,79\%\\\%m_{Ba}=100\%-20,13\%-36,79\%=43,08\%\end{matrix}\right.\)
m(rắn)= mAg=3,2(g)
Fe +2 HCl -> FeCl2 + H2
nH2= 0,3(mol) -> nFe=0,3(mol)
=> mFe=0,3. 56=16,8(g)
=> m(hỗn hợp)= mAg+ mFe= 3,2+16,8=20(g)
=> %mAg= (3,2/20).100=16%
=>%mFe=100% - 16%=84%