Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
Câu 1:
Đặt \(n_{Al}=x(mol);n_{Fe}=y(mol)\Rightarrow 27x+56y=0,83(1)\)
\(n_{H_2}=\dfrac{0,56}{22,4}=0,025(mol)\\ 2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\\ Fe+H_2SO_4\to FeSO_4+H_2\\ \Rightarrow 1,5x+y=0,025(2)\\ (1)(2)\Rightarrow x=y=0,01(mol)\\ \Rightarrow \%_{Al}=\dfrac{0,01.27}{0,83}.100\%=32,53\%\\ \Rightarrow \%_{Fe}=100\%-32,53\%=67,47\%\)
Câu 2:
Đặt \(n_{Al}=x(mol);n_{Mg}=y(mol)\Rightarrow 27x+24y=4,5(1)\)
\(n_{H_2}=\dfrac{5,04}{22,4}=0,225(mol)\\ 2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\\ Mg+H_2SO_4\to MgSO_4+H_2\\ \Rightarrow 1,5x+y=0,225(2)\\ (1)(2)\Rightarrow x=0,1(mol);y=0,075(mol)\\ \Rightarrow \%_{Al}=\dfrac{0,1.27}{4,5}.100\%=60\%\\ \Rightarrow \%_{Mg}=100\%-60\%=40\%\)
Dạng PP hai dòng:
\(PTHH:2A+Cl_2\to 2ACl\\ \Rightarrow n_A=n_{ACl}\\ \Rightarrow \dfrac{9,2}{M_A}=\dfrac{23,4}{M_A+35,5}\\ \Rightarrow M_A=23(g/mol)\)
Vậy A là natri
a, Ta có: 27nAl + 56nFe = 0,83 (1)
PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}+n_{Fe}=\dfrac{0,56}{22,4}=0,025\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow n_{Al}=n_{Fe}=0,01\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,01.27}{0,83}.100\%\approx32,53\%\\\%m_{Fe}\approx67,47\%\end{matrix}\right.\)
b, nH2SO4 = nH2 = 0,025 (mol)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,025.98}{20\%}=12,25\left(g\right)\)
Gọi x,y là số mol của AI và Fe
2Al + 3H2SO4 -> Al2(SO4)3 + 3H2
x --------------------... \(\frac{3x}{2}\)
Fe + H2SO4 -> FeSO4 + H2
y ----------------------> y
n H2 = 0,56 / 22,4 = 0,025 mol
Ta có hệ \(\begin{cases}27x+56y=0,83\\x+\frac{3x}{2}=0,025\end{cases}\)
\(\begin{cases}x=0,01mol\\y=0,01mol\end{cases}\)
=> m Al = 0,01 x 27 = 0,27 g
=> m Fe = 0,01 x 56 = 0,56 g
=> % Al = 0,27 / 0,83 x 100% = 32,53 %
=> % Fe = 0,56 / 0,83 x 100% = 67,47 %
a/ \(n_{CO_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
\(MgCO_3+H_2SO_4\rightarrow MgSO_4+H_2O+CO_2\)
\(0,5---0,5----0,5---0,5-0,5\)
\(MgO+H_2SO_4\rightarrow MgSO_4+H_2O\)
\(b---b----b-----b\)
\(\Rightarrow m_{MgCO_3}=0,5.\left(24+12+16.3\right)=42\left(g\right)\)
\(\dfrac{m_{MgCO_3}}{m_{MgO}}=\dfrac{7}{3}\Rightarrow m_{MgO}=42.\dfrac{3}{7}=18\left(g\right)\Rightarrow n_{MgO}=b=0,45\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4}=0,45+0,5=0,95\left(mol\right)\) \(\Rightarrow m_{dd}=\dfrac{0,95.98}{0,05}=1862\left(g\right)\)
nH2=0,025(mol)
gọi a,b lần lượt là sô mol của Al và Fe
PT1: 2Al + 6HCl -> 2AlCl3 + 3H2
vậy: a---------->3a----->a-------->1,5a(mol)
pt2: Fe + 2HCl -> FeCl2 + H2
vậy: b------->2b------->b----->b (mol)
Ta có HPT:
27a+56b=0,83
1,5a+b=0,025
Giải ra :a=b=0,01 mol
=> mAl=n.M=0,01.27=0,27(g)
=> mfe=n.M=0,01.56=0,56(g)
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
x x
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
y 3/2y
\(nH_2=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
ta có hệ pt:
\(\left\{{}\begin{matrix}x+\dfrac{3}{2}y=0,4\\24x+27y=7,8\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)
\(mMg=0,1.24=2,4\left(g\right)\)
\(mAl=0,2.27=5,4\left(g\right)\)
Trong \(20,4g\) hỗn hợp có: \(\left\{{}\begin{matrix}n_{Zn}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\\n_{Al}=c\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow65a+56b+27c=20,4\left(1\right)\)
\(n_{H_2}=\dfrac{10,08}{22,4}=0,45mol\)
\(BTe:2n_{Zn}+2n_{Fe}+3n_{Al}=2n_{H_2}\)
\(\Rightarrow2a+2b+3c=2\cdot0,45\left(2\right)\)
Trong \(0,2mol\) hhX có \(\left\{{}\begin{matrix}Zn:ka\left(mol\right)\\Fe:kb\left(mol\right)\\Al:kc\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow ka+kb+kc=0,2\)
\(n_{Cl_2}=\dfrac{6,16}{22,4}=0,275mol\)
\(BTe:2n_{Zn}+3n_{Fe}+3n_{Al}=2n_{Cl_2}\)
\(\Rightarrow2ka+3kb+3kc=2\cdot0,275\)
Xét thương:
\(\dfrac{ka+kb+kc}{2ka+3kb+3kc}=\dfrac{0,2}{2\cdot0,275}\Rightarrow\dfrac{a+b+c}{2a+3b+3c}=\dfrac{4}{11}\)
\(\Rightarrow3a-b-c=0\left(3\right)\)
Từ (1), (2), (3)\(\Rightarrow\left\{{}\begin{matrix}a=0,1mol\\b=0,2mol\\c=0,1mol\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}m_{Zn}=6,5g\\m_{Fe}=11,2g\\m_{Al}=2,7g\end{matrix}\right.\)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1mol\)
a)\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,1 0,1 0,1
\(m_{Fe}=0,1\cdot56=5,6\left(g\right)\)
b)\(\Rightarrow\%m_{Fe}=\dfrac{5,6}{12}\cdot100\%=46,67\%\) \(\Rightarrow\%m_{Cu}=100\%-46,67\%=53,33\%\)
c)\(n_{NaOH}=0,1\cdot1=0,1mol\)
\(2NaOH+FeCl_2\rightarrow Fe\left(OH\right)_2+2NaCl\)
0,1 0,1 0,1
\(m_{Fe\left(OH\right)_2}=0,1\cdot90=9\left(g\right)\)
a)2Al +3H2SO4---->Al2(SO4)3 +3H2
x(27x)---------------------------------1,5x
Fe+ H2SO4---->FeSO4+H2
y(56y)-------------------------y
b) n\(_{H2}=\frac{0,56}{22,4}=0,025\left(mol\right)\)
Gọi n Al=x
n Fe =y
Theo bài ta có hệ pt
\(\left\{{}\begin{matrix}27x+56y=0,83\\1,5x+y=0,025\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,01\\y=0,01\end{matrix}\right.\)
m\(_{Al}=0,01.27=0,27\left(g\right)\)
m\(_{Fe}=0,01.56=0,56\left(g\right)\)