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\(5.a.V_{rượu}=\dfrac{46.25}{100}=11,5\left(l\right)\\ m_{rượu}=11,5.0,8=9,2\left(g\right)\\ b.C_2H_5OH+CH_3COOH⇌CH_3COOC_2H_5+H_2O\\n_{C_2H_5OH}=\dfrac{9,2}{46}=0,2\left(mol\right)\\ n_{CH_3COOC_2H_5}=n_{C_2H_5OH}=0,2\left(mol\right)\\ \Rightarrow m_{CH_3COOC_2H_5}=0,2.88=17,6\left(g\right)\\ VìH=30\%\Rightarrow m_{CH_3COOC_2H_5}=17,6.30\%=5,28\left(g\right)\)
\(6.a.C_2H_5OH+CH_3COOH⇌CH_3COOC_2H_5+H_2O\\ n_{C_2H_5OH}=\dfrac{23}{46}=0,5\left(mol\right)\\ n_{CH_3COOH}=0,5.60=30\left(g\right)\\ b.n_{CH_3COOC_2H_5}=n_{C_2H_5OH}=0,5\left(mol\right)\\ \Rightarrow m_{CH_3COOC_2H_5}=0,5.88=44\left(g\right)\\ VìH=70\%\Rightarrow m_{CH_3COOC_2H_5}=44.70\%=30,8\left(g\right)\)
a)
$CH_3COOH + KOH \to CH_3COOK + H_2O$
n CH3COOH = n KOH = 0,1(mol)
$CH_3COOH + 2O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O$
$C_2H_5OH + 3O_2 \xrightarrow{t^o} 2CO_2 + 3H_2O$
$CO_2 +C a(OH)_2 \to CaCO_3 + H_2O$
2n C2H5OH + 2n CH3COOH = n CO2 = n CaCO3 = 60/100 = 0,6(mol)
=> n C2H5OH = (0,6 - 0,1.2)/2 = 0,2(mol)
=> n O2 = 2n CH3COOH + 3n C2H5OH = 0,1.2 + 0,2.3 = 0,8(mol)
=> V O2 = 0,8.22,4 = 17,92 lít
b) m = 0,1.60 + 0,2.46 = 15,2 gam
%m CH3COOH = 0,1.60/15,2 .100% = 39,47%
%m C2H5OH = 100%- 39,47% = 60,53%
C5:
nC2H5OH = 8,2 / 46 = 0,2 (mol)
C2H5OH + 3O2-- (t^o)-- > 2CO2 + 3H2O
VCO2 = 0,4 . 22,4 = 8,96 (l)
VO2 = 0,6.22,4=13,44 (l)
Câu 7:
a, \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
b, \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Theo PT: \(n_{Fe}=n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,1.56}{10}.100\%=56\%\\\%m_{CuO}=44\%\end{matrix}\right.\)
c, \(n_{CuO}=\dfrac{10-0,1.56}{80}=0,055\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{Fe}+n_{CuO}=0,155\left(mol\right)\)
\(\Rightarrow C\%_{H_2SO_4}=\dfrac{0,155.98}{100}.100\%=15,19\%\)
d, Theo PT: \(\left\{{}\begin{matrix}n_{FeSO_4}=n_{Fe}=0,1\left(mol\right)\\n_{CuSO_4}=n_{CuO}=0,055\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{FeSO_4}=0,1.152=15,2\left(g\right)\\m_{CuSO_4}=0,055.160=8,8\left(g\right)\end{matrix}\right.\)
Câu 8:
a, \(CuCO_3+2HCl\rightarrow CuCl_2+CO_2+H_2O\)
b, \(n_{CO_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
Theo PT: \(n_{CuCO_3}=n_{CO_2}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{CuCO_3}=\dfrac{0,15.124}{20}.100\%=93\%\\\%m_{CuCl_2}=7\%\end{matrix}\right.\)
c, \(n_{HCl}=2n_{CO_2}=0,3\left(mol\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\)