Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
\(n_{Zn}=\dfrac{13}{65}=0.2\left(mol\right)\)
\(n_{HCl}=\dfrac{182.5\cdot10}{100\cdot36.5}=0.5\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(0.2......0.4..........0.2........0.2\)
\(n_{HCl\left(dư\right)}=0.5-0.4=0.1\left(mol\right)\)
\(m_{HCl\left(dư\right)}=0.1\cdot36.5=3.65\left(g\right)\)
\(V_{H_2}=0.2\cdot22.4=4.48\left(l\right)\)
\(m_{\text{dung dịch sau phản ứng}}=13+182.5-0.2\cdot2=195.1\left(g\right)\)
\(C\%_{HCl\left(dư\right)}=\dfrac{3.65}{195.1}\cdot100\%=1.87\%\)
\(C\%_{ZnCl_2}=\dfrac{0.2\cdot136}{195.1}\cdot100\%=13.94\%\)
a)
Gọi $n_{NaOH} = a(mol) ; n_{KOH} = b(mol) \Rightarrow 40a + 56b = 3,04(1)$
$NaOH + HCl \to NaCl + H_2O$
$KOH + HCl \to KCl + H_2O$
$m_{muối} = 58,5a + 74,5b = 4,15(2)$
Từ (1)(2) suy ra a = 0,02 ; b = 0,04
$n_{HCl} = a + b = 0,06(mol)$
$C\%_{HCl} = \dfrac{0,06.36,5}{200}.100\% = 1,095\%$
b)
$m_{dd} = 3,04 + 200 = 203,4(gam)$
$C\%_{NaCl} = \dfrac{0,02.58,5}{203,4}.100\% = 0,58\%$
$C\%_{KCl} =\dfrac{0,04.74,5}{203,4}.100\% = 1,47\%$
mNaOH=25.4%=1g
=>nNaOH=1/40=0,025 mol
nH2SO4=0,2.52/1000=0,0104 mol
2NaOH +H2SO4=>Na2SO4 +2H2O
Bđ:0,025 mol
Pứ:0,0208 mol<=0,0104 mol=>0,0104 mol
Dư:4,2.10^(-3) mol
mNaOH dư=4,2.10^(-3).40=0,168g
mNa2SO4=0,0104.142=1,4768g
mdd sau pứ=25+51=76g
C%dd NaOH dư=0,168/76.100%=0,22%
C%dd Na2SO4=1,4768/76.100%=1,943%
Bài 14 :
\(a) n_{CuO} = \dfrac{8}{80} = 0,1(mol)\\ CuO + 2HCl \to CuCl_2 + H_2O\\ n_{HCl} = 2n_{CuO} = 0,2(mol)\\ m_{dd\ HCl} = \dfrac{0,2.36,5}{7,3\%} = 100(gam)\\ b) \text{Chất tan : } CuCl_2\\ n_{CuCl_2} = n_{CuO} = 0,1(mol)\\ m_{CuCl_2} = 0,1.135 = 13,5(gam)\)
Bài 15 :
\(a) n_{Fe_2O_3} =\dfrac{4,8}{160} = 0,03(mol)\\ Fe_2O_3 + 3H_2SO_4 \to Fe_2(SO_4)_3 + 3H_2O\\ n_{H_2SO_4} = 3n_{Fe_2O_3} = 0,09(mol)\\ m_{dd\ H_2SO_4} = \dfrac{0,09.98}{9,8\%} = 90(gam)\\ b) \text{Chất tan : } Fe_2(SO_4)_3\\ n_{Fe_2(SO_4)_3} = n_{Fe_2O_3} = 0,03(mol)\\ m_{Fe_2(SO_4)_3} = 0,03.400 = 12(gam)\)
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ n_{HCl}=\dfrac{109,5.20\%}{36,5}=0,6\left(mol\right)\\ PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ Vì:\dfrac{0,2}{1}< \dfrac{0,6}{2}\Rightarrow HCldư\\ n_{H_2}=n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\\ n_{HCl\left(dư\right)}=0,6-0,2.2=0,2\left(mol\right)\\ a,V_{H_2\left(đktc\right)}=0,2.22,4=4,48\left(l\right)\\ b,m_{ZnCl_2}=136.0,2=27,2\left(g\right)\\ c,m_{ddsau}=13+109,5-0,2.2=122,1\left(g\right)\\ C\%_{ddZnCl_2}=\dfrac{27,2}{122,1}.100\approx22,277\%\\ C\%_{ddHCl\left(dư\right)}=\dfrac{0,2.36,5}{122,1}.100\approx5,979\%\)
Zn + 2HCl -> ZnCl2 + H2
a, nZn = 13/65= 0,2(mol)
mHCl= 109,5.20%/100%=21.9(g)
nHCl=21,9/36,5=0,6(mol)
Theo PT nHCl = 2nZn= 2.0,2= 0,4(mol)<0,6(mol)
=> HCl pư dư, Zn pư hết
Theo PT: nH2= nZn =0,2(mol)
VH2=0,2.22,4=4,48(l)
b, Theo PT: nZnCl2=nZn=0,2(mol)
mZnCl2= 0,2.136=27,2(g)
c, mdd sau pư= 13+109,5-0,2.2=122,1(g)
C%dd ZnCl2=27,2.100%/122,1=22,28%
nHCl dư= 0,6-0,4=0,2(mol)
mHcl
\(n_{HCl}=\dfrac{100.14,6\%}{36,5}=0,4\left(mol\right)\\ n_{MgCO_3}=\dfrac{50}{84}=\dfrac{25}{42}\left(mol\right)\\ PTHH:MgCO_3+2HCl\rightarrow MgCl_2+CO_2+H_2O\\ Vì:0,4:2< \dfrac{25}{42}:1\\ \Rightarrow MgCO_3dư\\ \Rightarrow ddsau:MgCl_2\\n_{MgCO_3\left(p.ứ\right)}=n_{CO_2}= n_{MgCl_2}=\dfrac{n_{HCl}}{2}=\dfrac{0,4}{2}=0,2\left(mol\right)\\ m_{ddsau}=m_{MgCO_3\left(p.ứ\right)}+m_{ddHCl}-m_{CO_2}=0,2.84+100-0,2.44=108\left(g\right)\\ C\%_{ddMgCl_2}=\dfrac{0,2.95}{108}.100\approx17,593\%\%\)
\(\text{1)}m_{KOH}=40.35\%=14\left(g\right)\\ \rightarrow n_{KOH}=\dfrac{14}{56}=0,25\left(mol\right)\\ PTHH:KOH+HCl\rightarrow KCl+H_2O\\ \text{Theo pthh}:n_{HCl}=n_{KOH}=0,25\left(mol\right)\\ \rightarrow V_{ddHCl}=0,25.0,5=0,125\left(l\right)\)
\(\text{2)}n_{Al}=\dfrac{4,05}{27}=0,15\left(mol\right)\\ n_{H_2SO_4}=200.14,7\%=29,4\left(g\right)\\ \rightarrow n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\\ \text{PTHH}:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\\ \text{LTL}:\dfrac{0,15}{2}< \dfrac{0,3}{3}\rightarrow H_2SO_4\text{ dư}\)
\(\text{Theo pthh}:\left\{{}\begin{matrix}n_{H_2SO_4\left(pư\right)}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}.0,15=0,225\left(mol\right)\\n_{H_2}=n_{H_2SO_4\left(pư\right)}=0,225\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=\dfrac{1}{2}.0,15=0,075\left(mol\right)\end{matrix}\right.\\ \rightarrow m_{dd\left(\text{sau phản ứng}\right)}=200+4,05-0,3.2=203,45\left(g\right)\)
\(\rightarrow\left\{{}\begin{matrix}C\%_{H_2SO_4\text{ dư}}=\dfrac{\left(0,3-0,225\right).98}{203,45}=3,61\%\\C\%_{Al_2\left(SO_4\right)_3}=\dfrac{342.0,075}{203,45}=12,61\%\end{matrix}\right.\)
`1)PTHH:`
`NaOH + HNO_3 -> NaNO_3 + H_2 O`
`0,05` `0,05` `0,05` `(mol)`
`n_[NaOH]=[4/100 .50]/40=0,05(mol)`
`n_[HNO_3]=[[12,6]/100 .50]/63=0,1(mol)`
Ta có:`[0,05]/1 < [0,1]/1`
`=>HNO_3` dư
`m_\text{dd sau p/ư}=50+50=100(g)`
`@C%_[NaNO_3]=[0,05.85]/100 .100=4,25%`
`@C%_[HNO_3(dư)]=[(0,1-0,05).63]/100 .100=3,15%`
\(n_{Fe_3O_4}=\dfrac{4,64}{232}=0,02\left(mol\right)\)
\(m_{HCl}=\dfrac{210,24.25}{100}=52,56\left(g\right)\)
\(n_{HCl}=\dfrac{52,56}{36,5}=1,44\left(mol\right)\)
PTHH :
\(Fe_3O_4+8HCl\rightarrow2FeCl_3+FeCl_2+4H_2O\)
trc p/u : 0,02 1,44
p/u : 0,02 0,16 0,04 0,02 0,08
sau : 0 1,28 0,04 0,02 0,08
HCl dư sau p/ư
\(m_{ddsaupu}=210,24+4,64=214,88\left(g\right)\)
\(C\%_{FeCl_3}=\dfrac{0,04.162,5}{214,88}\approx3,02\%\)
\(C\%_{FeCl_2}=\dfrac{0,02.127}{214,88}\approx1,18\%\)
Giúp tôi với các bạn 😫😫😫😫😭😭😭😭😭😭😭😭😥